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1. Complete the following equations and write the accepted mechanism for
the reaction in each case.
CH3CH2O-/CH3CH2OH
a. CH3CHCHCH3
Heat
Br Br
Cl
NaOH
b. (CH3)2CCH2CH3
Heat
H+/H2O
c. CH3HC=CH2
Conc.H2SO4
d. CH3CH2CH2OH
180°C
CH3
H+
e. + CH3C=CH2
HBr
f.
CH3CH2O-Na+/CH3CH2OH
g. CH2CH2Br
Heat
Br
h. EtO-/EtOH
CHCH2Br
Heat
Lig.NH3
i. CH3CH2Cl + HC C-Na+
CCl4
j. H2C=CH2 + Cl2
25°C
OH-(aq)
k. (CH3)3CBr
Heat
H+/H2O
l. CH3HC=CHCH3
CH3OH
m. (CH3)3CBr + CH3O-Na+ Heat
1
mechanism in organic chemistry 02/18/2019
KOH(aq)
n. CH3CH2I Heat
COCH3
o. + NaHSO3
p. AlCl3
+ CH3COCl
q. AlBr3
+ CH3CH2Br
OH
C(CH3)2
r. Conc.H3PO4
Heat
Conc.H2SO4
s. CH3CH2OH
140°C
Cl
EtO-/EtOH
t. CH3CHCH2CH3 Heat
CH3CH2OH
u. (CH3)3CBr + CH3CH2O-Na+ Heat
v. CH3CH2CHO + HSO3-Na+
H+
x. CH3COCH3 + H2NNHCONH2
CH3
Cl2/U.V
w.
Light
CH2CH2Br
y. NaOH(aq)
Heat
H+
z. + CH3HC=CH2
FeCl3
z. + CH3COBr
2
mechanism in organic chemistry 02/18/2019
OH
Conc.H2SO4
1. CH3CHCH3 Heat
Conc.H2SO4
2. CH3CH2OH
140°C
C2H5O-K+/C2H5OH
3. (CH3)3CBr
Heat
Conc.H2SO4/H2O
4. CH3HC=CHCH3
5. CH3CHO + NaHSO3
CH3CH2OH
6. CH3CH2CH2Br + CH3CH2O-Na+
Heat
7. Fe(s)/Heat
+ Br2
H2SO4
8. + CH3HC=CH2
NHNH2
9. (CH3)3C=O + H+
NHNH2
H+
10. CH3CH2CHO +
CH2Br
OH-(aq)
11. Heat
H+
12. CH3CH2CHO + NH2NH2
OH
Conc.H2SO4
13. CH3CHCH3
Heat
Cl2/H2O
14. CH3HC=CHCH3
3
mechanism in organic chemistry 02/18/2019
CCl4
15. (CH3)2C=CH2 + I2
25°C
CH2CH2I
16. OH-(aq)
HC=CH2
CCl4
17. + Br2
25°C
AlCl3
18. + CH3COCl
OH
Conc.H3PO4
19.
Heat
NHNH2
H+
20. CH3COCH2CH3 +
Cl2/Fe
21.
Br2/FeBr3
22.
CH3
H2O
23. CH3C=CHCH3 + Conc.H2SO4
Warm
Br2/H2O
24. HC=CH2
Excess KOH(aq)/EtOH
25. CH3BrCH2Br
Heat
CCl4
26. CH3HC=CH2 + Cl2 25°C
H2O
27. CH3HC=CH2 + Br2
H+
28. + H2C=CH2
4
mechanism in organic chemistry 02/18/2019
I
NaOH(aq)
29. (CH3)2CCH2CH3 Heat
MnO4-/H2O
30. (CH3)2C=CH2
NaOH(aq)
31. CH3CH2CH2Cl Reflux
KOH(aq)
32. (CH3)3CBr + CH3OH Heat
EtOH
33. CH3CH2CH2Br + NaOH(aq)
Heat
EtO-/EtOH
34. CH3CHCH2CH3
Heat
H+
35. CH3COCH3 + NH2OH
36. CH3COCH3 + NaHSO3
37. 2CH3CHO + NaOH(aq)
38. CH3C CH + Excess HCl
FeBr3
39. C6H5NH2 + CH3COCl
CH3
AlCl3
40. + CH3COCl
Conc.H2SO4
41. CH3CH2OH
O °C
OH
CH3COCl/NaOH(aq)
42.
43. CH3CH2COOH + CH3COCl
H+
44. CH3CH2COOH + CH3OH
Dil. NaOH
45. 2CH3COCH3
Warm
5
mechanism in organic chemistry 02/18/2019
Conc.H2SO4
46. + Conc.HNO3
55°C
Conc.H3PO4
47. CH3CH2CH2OH
Heat
OH-(aq)
48. CH3COOCH3 + H2O
KCN/CH3COOH
49. O
2. Show how the following conversion can be effected and in each case,
indicate the reagents and conditions for the reactions.
1. (CH3)3CHOH from ethene
2. (CH3)3CHOH from CH3CH2Br
3. CH3CH2CH2NH2 from pentene
4. Phenol from 2-phenylpropane
5.Benzene from phenylmethanol
6.CH3CH2CH2COOH from propan-1-ol
7.Ethanoylchloride from ethane
8.Phenylbenzoate from phenylamine
9.Phenol from nitrobenzene
10.CH3CH2NH2 from CH3CH2CH2Cl
11.CH3CH2OH from CH3CH2COCl
12.CH3CH2COOH from CH3CH2OH
13.CH3COCH3 from CH3CH2CH2OH
14.But-2-yne from propene
15.Ethene from propan-2-ol
16.CH3CH2OCH2CH3 from ethane
17.Propene from acetic acid
18.CH3CONHCH2CH3 from CH3Br
19.Cyclohexene from aminobenzene
20.CH3CH2NH2 from CH3CH2COOH
21.Phenylamine from benzoic acid
22.Phenylmethanol from benzene
23.(CH3)2C=NOH from ethanol
6
mechanism in organic chemistry 02/18/2019
COCH3 CH2CH2Cl
29. from
NH2
30. from
CHO
31. from
Br
32. from Benzaldehyde
NH2
33. from Cyclohexene
3. Name the reagents used to distinguish between each of the followings and
in each case, state what would be observed and write equations of
reactions where possible.
Part A Inorganic branch of chemistry:
1. Ni2+ and Cr3+ 8. SO42- and SO32-
2. Ca2+ and Ba2+ 9. CO32- and Cl-
3. Ca2+ and Mg2+ 10. HCO3- and CO32-
4. Al3+ and Pb2+ 11. Cl- and F-
5. Sn4+ and Sn2+ 12. NO3- and NO2-
6. Pb2+ and Ag+ 13. SO32- and S2O32-
7. Mn2+ and Pb2+ 14. C2O42- and HCO3- 15. Br- and Cl-
7
mechanism in organic chemistry 02/18/2019
OH CH2OH
34. and
COOH OH
35. and
NH2
CH3 CH2NH2
36. and
8
mechanism in organic chemistry 02/18/2019
Cl
38. and
CHCH3 CH2CH2O
39. OH H
and
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mechanism in organic chemistry 02/18/2019
10