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1. The pressure of a gas is the force that gas particles exert on the walls of a container. The pressure
depends on the temperature, the number of molecules of the gas and the volume of the container.
2. The air pressure inside the balloon is greater than the air pressure outside the balloon. The pressure
inside must equal the sum of the outside air pressure plus the pressure exerted by the stretched rubber of
the balloon.
4. 1 torr ¼ 1 mm Hg
5. The molecules of H2 at 100 C are moving faster. Temperature is a measure of average kinetic energy.
At higher temperatures, the molecules will have more kinetic energy.
6. 1 atm corresponds to 4 L.
7. The pressure times the volume at any point on the curve is equal to the same value. This is an inverse
relationship as is Boyle’s law. (PV ¼ k)
8. If T2 < T1, the volume of the cylinder would decrease (the piston would move downward).
9. N2 ðgÞ þ O2 ðgÞ
! 2 NOðgÞ
1 vol þ 1 vol ! 2 vol
According to Avogadro’s law, equal volumes of nitrogen and oxygen at the same temperature and
pressure contain the same number of molecules. In the reaction, nitrogen and oxygen molecules react in
a 1:1 ratio. Since two volumes of nitrogen monoxide are produced, one molecule of nitrogen and one
molecule of oxygen must produce two molecules of nitrogen monoxide. Therefore each nitrogen and
oxygen molecule must be made up of two atoms (diatomic).
10. We refer gases to STP because some reference point is needed to relate volume to moles. A temperature
and pressure must be specified to determine the moles of gas in a given volume, and 0 C and 760 torr
are convenient reference points.
12. An ideal gas is one which follows the described gas laws at all P, V, and T and whose behavior is
described exactly by the Kinetic Molecular Theory.
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- Chapter 12 -
16. The order of increasing molecular velocities is the order of decreasing molar masses.
increasing molecular velocity
!
Rn; F2 ; N2 CH4 ; He; H2
!
decreasing molar mass
At the same temperature the kinetic energies of the gases are the same and equal to ½ mv2 . For the
kinetic energies to be the same, the velocities must increase as the molar masses decrease.
17. Average kinetic energies of all these gases are the same, since the gases are all at the same temperature.
18. A gas is least likely to behave ideally at low temperatures. Under this condition, the velocities of the
molecules decrease and attractive forces between the molecules begin to play a significant role.
19. A gas is least likely to behave ideally at high pressures. Under this condition, the molecules are forced
close enough to each other so that their volume is no longer small compared to the volume of the
container. Attractive forces may also occur here and sooner or later, the gas will liquefy.
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- Chapter 12 -
21. Conversion of oxygen to ozone is an endothermic reaction. Evidence for this statement is that energy
(286 kJ=3 mol O2) is required to convert O2 to O3.
23. The pressure inside the bottle is less than atmospheric pressure. We come to this conclusion because the
water inside the bottle is higher than the water in the trough (outside the bottle).
24. The density of air is 1.29 g/L. Any gas listed below air in Table 12.4 has a density greater than air. For
example: O2, H2S, HCl, F2, CO2.
volume O2 ¼ volume H2
mass O2 mass H2 mass O2
density O2 ¼ ðdensity H2 Þ
density O2 density H2 mass H2
32
density O2 ¼ ðdensity H2 Þ ¼ 16 ðdensity H2 Þ
2
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- Chapter 12 -
26. Heating a mole of N2 gas at constant pressure has the following effects:
(a) Density will decrease. Heating the gas at constant pressure will increase its volume. The mass
does not change, so the increased volume results in a lower density.
(b) Mass does not change. Heating a substance does not change its mass.
(c) Average kinetic energy of the molecules increases. This is a basic assumption of the Kinetic
Molecular Theory.
(d) Average velocity of the molecules will increase. Increasing the temperature increases the average
kinetic energies of the molecules; hence, the average velocity of the molecules will increase also.
(e) Number of N2 molecules remains unchanged. Heating does not alter the number of molecules
present, except if extremely high temperatures were attained. Then, the N2 molecules might
dissociate into N atoms resulting in fewer N2 molecules.
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- Chapter 12 -
SOLUTIONS TO EXERCISES
1. Pressure conversions:
2. Pressure conversions:
mm Hg lb/in.2 atmospheres
a. 789 15.3 1.04
b. 1700 32 2.2
c. 1100 21 1.4
14:7 lb=in:2
(a) mm Hg ! lb=in: ð789 mm HgÞ
2
¼ 15:3 lb=in:2
760 mm Hg
1 atm
mm Hg ! atm ð789 mm HgÞ ¼ 1:04 atm
760 mm Hg
760 mm Hg
(b) lb=in: ! mm Hg ð32 lb=in: Þ
2 2
¼ 1700 mm Hg
14:7 lb=in:2
1 atm
lb=in:2 ! atm ð32 lb=in:2 Þ ¼ 2:2 atm
14:7 lb=in:2
760 mm Hg
(c) atm ! mm Hg ð1:4 atmÞ ¼ 1100 mm Hg
1 atm
14:7 lb=in:2
atm ! lb=in: ð1:4 atmÞ
2
¼ 21 lb=in:2
1 atm
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- Chapter 12 -
101:3 kPa
3. (a) torr ! kPa ð953 torrÞ ¼ 127 kPa
760 torr
1 atm
(b) kPa ! atm ð2:98 kPaÞ ¼ 0:0294 atm
101:3 kPa
760 mm Hg
(c) atm ! mm Hg ð2:77 atmÞ ¼ 2110 mm Hg
1 atm
1 atm
(d) torr ! atm ð372 torrÞ ¼ 0:489 atm
760 torr
76:0 cm Hg
(e) atm ! cm Hg ð2:81 atmÞ ¼ 214 cm Hg
1 atm
101:3 kPa
4. (a) torr ! kPa ð649 torrÞ ¼ 86:5 kPa
760 torr
1 atm
(b) kPa ! atm ð5:07 kPaÞ ¼ 0:0500 atm
101:3 kPa
760 mm Hg
(c) atm ! mm Hg ð3:64 atmÞ ¼ 2770 mm Hg
1 atm
1 atm
(d) torr ! atm ð803 torrÞ ¼ 1:06 atm
760 torr
76:0 cm Hg
(e) atm ! cm Hg ð1:08 atmÞ ¼ 82:1 cm Hg
1 atm
1 atm
5. (a) lb=in: ! atm ð1920 lb=in: Þ
2 2
¼ 131 atm
14:7 lb=in:2
760 torr
(b) lb=in: ! torr ð1920 lb=in: Þ
2 2
¼ 9:93 104 torr
14:7 lb=in:2
101:3 kPa
(c) lb=in: ! kPa ð1920 lb=in: Þ
2 2
¼ 1:32 104 kPa
14:7 lb=in:2
1 atm
6. (a) lb=in: ! atm ð31 lb=in: Þ
2 2
¼ 2:1 atm
14:7 lb=in:2
760 torr
(b) lb=in: ! torr ð31 lb=in: Þ
2 2
¼ 1600 torr
14:7 lb=in:2
101:3 kPa
(c) lb=in: ! kPa ð31 lb=in: Þ
2 2
¼ 210 kPa
14:7 lb=in:2
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- Chapter 12 -
P 1 V1
7. P1 V1 ¼ P2 V2 or P2 ¼
V2
ð825 torrÞð725 mLÞ
(a) ¼ 2110 torr
ð283 mLÞ
ð825 torrÞð725 mLÞ
(b) Change 2:87 L to mL ¼ 208 torr
ð2:87 LÞð1000 mL=1 LÞ
P 1 V1
8. P1 V1 ¼ P2 V2 or P2 ¼
V2
ð508 torrÞð486 mLÞ
(a) ¼ 1330 torr
ð185 mLÞ
ð508 torrÞð486 mLÞ
(b) Change 6:17 L to mL ¼ 40:0 torr
ð6:17 LÞð1000 mL=1 LÞ
P 1 V1
9. P1 V1 ¼ P2 V2 or V2 ¼
P2
ð58:2 LÞð7:25 atmÞ
¼ 208 L
ð2:03 atmÞ
P 1 V1
10. P1 V1 ¼ P2 V2 or V2 ¼
P2
ð832 LÞð0:204 atmÞ
¼ 21:2 L
ð8:02 atmÞ
V1 V2 V1 T 2
11. ¼ or V2 ¼ ; temperatures must be in Kelvin ( C þ 273)
T1 T2 T1
(a) ð125 mLÞð268 KÞ
¼ 114 mL
294 K
ð125 mLÞð308 KÞ
(b) ¼ 131 mL
294 K
ð125 mLÞð1095 KÞ
(c) ¼ 466 mL
294 K
V1 V2 V1 T 2
12. ¼ or V2 ¼ ; temperatures must be in Kelvin ( C þ 273)
T1 T2 T1
(a) ð575 mLÞð298 KÞ
¼ 691 mL
248 K
ð575 mLÞð273 KÞ
(b) ¼ 633 mL ð32 F ¼ 0 C ¼ 273 KÞ
248 K
ð575 mLÞð318 KÞ
(c) ¼ 737 mL
248 K
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- Chapter 12 -
P1 V1 P2 V2 P1 V1 T2
13. Use the combined gas laws ¼ or V2 ¼
T1 T2 P2 T1
P1 V1 P2 V2 P1 V1 T2
14. Use the combined gas laws ¼ or V2 ¼
T1 T2 P2 T1
P 1 V1 P 2 V2 P 1 V1 T 2
15. Use the combined gas law ¼ or V2 ¼
T1 T2 P2 T1
P 1 V1 P 2 V2 P 1 V1 T 2
16. Use the combined gas law ¼ or V2 ¼
T1 T2 P2 T1
P 1 V1 P 2 V2 P 1 V1 T 2
17. Use the combined gas law ¼ or P2 ¼
T1 T2 V2 T1
ð1:0 atmÞð775 mLÞð298 KÞ
¼ 1:4 atm
ð615 mLÞð273 KÞ
P 1 V1 P 2 V2 P 2 V2 T 1
18. Use the combined gas law ¼ or T2 ¼
T1 T2 P1 V1
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- Chapter 12 -
To calculate the volume of dry propane, note that the temperature is constant, so P1 V1 ¼ P2 V2
can be used.
P1 V1 ð725 torrÞð1:25 L C3 H8 Þ
V2 ¼ ¼ ¼ 1:19 L C3 H8
P2 ð760: torrÞ
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- Chapter 12 -
1L 1 mol 17:03 g
29. ð725 mL NH3 Þ ¼ 0:551 g NH3
1000 mL 22:4 L mol
1L 1 mol 42:08 g
30. ð945 mL C3 H6 Þ ¼ 1:78 g C3 H6
1000 mL 22:4 L mol
1 mol 22:4 L
31. ð1025 molecules CO2 Þ ¼ 3:813 1020 L CO2
6:022 1023 molecules mol
1 mol 6:022 1023 molecules
32. ð10:5 L CO2 Þ ¼ 2:82 1023 molecules CO2
22:4 L mol
PV ð1:2 atmÞð5:25 L O2 Þ
37. PV ¼ nRT n ¼ n¼ ¼ 0:26 mol O2
RT ð0:0821 L atm=mol KÞð299 KÞ
0 1
B752 torrC
@ torr Að9:55 L CO2 Þ
PV 760
38. PV ¼ nRT n ¼ n¼ atm ¼ 0:362 mol CO2
RT ð0:0821 L atm=mol KÞð318 KÞ
0 1
B732 torrC
@ torr Að645 L XeÞ
PV 760
39. PV ¼ nRT T ¼ T¼ atm ¼ 300: K
nR ð25:2 mol XeÞð0:0821 L atm=mol KÞ
0 1
B675 torrC
@ torr Að725 L ArÞ
PV 760
40. PV ¼ nRT T ¼ T¼ atm ¼ 209 K
nR ð37:5 mol ArÞð0:0821 L atm=mol KÞ
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- Chapter 12 -
- 146 -
- Chapter 12 -
45. The balanced equation is CaCO3(s) ! CaO(s) + CO2(g); 1 mol of a gas occupies 22.4 L at STP.
1 mol 1 mol CO2 22:4 L CO2
(a) ð6:24 g CaCO3 Þ ¼ 1:40 L CO2
100:1 g 1 mol CaCO3 1 mol CO2
1 mol CO2 1 mol CaCO3 100:1 g
(b) ð52:6 L CO2 Þ ¼ 235 g CaCO3
22:4 L CO2 1 mol CO2 1 mol
46. The balanced equation is Mg(s) + 2 HCl(aq) ! MgCl2(aq) + H2(g); 1 mol of a gas occupies 22.4 L
at STP.
1 mol 1 mol H2 22:4 L 1000 mL
(a) ð42:9 g MgÞ ¼ 3:95 104 mL H2
24:31 g 1 mol Mg 1
mol 1
L
1L 1 mol H2 2 mol HCl
(b) ð825 mL H2 Þ ¼ 0:0737 mol HCl
1000 mL 22:4 L H2 1 mol H2
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- Chapter 12 -
50. The balanced equation is C6 H12 O6 ðsÞ þ 6 O2 ðgÞ ! 6 CO2 ðgÞ þ 6 H2 Oðl Þ
1000 g 1 mol 6 mol CO2 22:4 L
ð1:50 kg C6 H12 O6 Þ ¼ 1:12 103 L CO2
1 kg 180:2 g 1 mol C6 H12 O6 1 mol
51. Like any other gas, water in the gaseous state occupies a much larger volume than in the liquid state.
52. During the winter the air in a car’s tires is colder, the molecules move slower and the pressure
decreases. In order to keep the pressure at the manufacturer’s recommended psi air needs to be added to
the tire. The opposite is true during the summer.
53. Sample (b) has the greatest pressure because it has more molecules. Pressure is proportional to number
of moles when temperature and volume remain constant.
54. Image (a) best represents the balloon because lowering the temperature of the gas will decrease its
volume. The size of the balloon will also decrease, but the gas molecules will still be distributed
throughout the volume of the balloon.
P n
V V
(b)
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- Chapter 12 -
57.
Graph showing
Factors that Factors that the relationship
Law are constant are variable of variable factors
Boyle’s law Temperature and number Pressure and volume (c)
of moles
Charles’ law Pressure and number of moles Volume and temperature (b)
Avogadro’s law Pressure and temperature Volume and number of moles (b)
58. The can is a sealed unit and very likely still contains some of the aerosol. As the can is heated, pressure
builds up in it eventually causing the can to explode and rupture with possible harm from flying debris.
59. One mole of an ideal gas occupies 22.4 liters at standard conditions. (0 C and 1 atm pressure)
PV ¼ nRT
ð1:00 atmÞðVÞ ¼ ð1:00 molÞð0:0821 L atm=mol KÞð273 KÞ
V ¼ 22:4 L
60. Solve for volume using PV ¼ nRT
- 149 -
- Chapter 12 -
- 150 -
- Chapter 12 -
2:01 g 22:4 L
(b) Molecular formula: ¼ 30: g=molðmolar massÞ
1:5 L mol
30: g=mol
¼ 2; Molecular formula is C2 H6
15:03 g=mol
(c) Valence electrons ¼ 2ð4Þ þ 6 ¼ 14
H H
H C C H
H H
65. PV ¼ nRT
(a) ð790 torrÞð1 atmÞ
ð2:0 LÞ ¼ ðnÞð0:0821 L atm=mol KÞð298 KÞ
760 torr
n ¼ 0:085 molðtotal molesÞ
66. 2 CO þ O2 ! 2 CO2
Calculate the moles of O2 and CO to find the limiting reactant.
PV ¼ nRT
O2 : ð1:8 atmÞð0:500 L O2 Þ ¼ ðnÞð0:0821 L atm=mol KÞð288 KÞ
mol O2 ¼ 0:038 mol
800 mm Hg 1 atm
CO : ð0:500 LÞ ¼ ðnÞð0:0821 L atm=mol KÞð333 KÞ
760 mm Hg
mol CO ¼ 0:019 mol Limiting reactant is CO
0:0095 mol O2 will react with 0:019 mol CO:
2 mol CO2 22:4 L
ð0:019 mol COÞ ¼ 0:43 L CO2 ¼ 430 mL CO2
2 mol CO mol
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- Chapter 12 -
g
67. PV ¼ nRT or PV ¼ RT
molar mass
1:4 g 1000 cm3
¼ 1:4 103 g=L
cm3 L
1:4 103 g
1:3 10 atm ð1:0 LÞ ¼
9
ð0:0821 L atm=mol KÞðTÞ
2:0 g=mol
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- Chapter 12 -
70. To double the volume of a gas, at constant pressure, the temperature (K) must be doubled.
V1 V2
¼ V2 ¼ 2 V1
T1 T2
V1 2 V1 2 V1 T 1
¼ T2 ¼ T2 ¼ 2 T1
T1 T2 V1
ðT1 ÞðP2 Þ
Since the volume stays constant, V1 = V2 and the equation reduces to T2 ¼
ðP1 Þ
ð500: torrÞð295 KÞ
T2 ¼ ¼ 211 K ¼ 62 C
700: torr
73. Use the combined gas laws
The volume of the tires remains constant (until they burst) so V1 = V2 and the equation reduces to
ðT1 ÞðP2 Þ
T2 ¼
ðP1 Þ
71:0 F ¼ 21:7 C ¼ 295 K
ð44 psiÞð295 KÞ
T2 ¼ ¼ 433 K ¼ 160 C ¼ 320 F
30: psi
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- Chapter 12 -
P1 V1 P2 V2 P1 V1 T2
76. Use the combined gas law ¼ or V2 ¼
T1 T2 P2 T1
First calculate the volume at STP.
78. A column of mercury at 1 atm pressure is 760 mm Hg high. The density of mercury is 13.6 times that of
water, so a column of water at 1 atm pressure should be 13.6 times as high as that for mercury.
ð760 mmÞð13:6Þ ¼ 1:03 104 mmð33:8 ftÞ
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- Chapter 12 -
81. First calculate the moles of gas and then convert moles to molar mass.
1 mol
ð0:560 LÞ ¼ 0:0250 mol
22:4 L
1:08 g
¼ 43:2 g=molðmolar massÞ
0:0250 mol
82. The conversion is: g=L
! g=mol
1:78 g 22:4 L
¼ 39:9 g=molðmolar massÞ
L mol
83. PV ¼ nRT
nRT ð0:510 mol H2 Þð0:0821 L atm=mol KÞð320: KÞ
(a) V ¼ ¼ ¼ 8:4 L H2
P 1:6 atm
PV ð600 torrÞð1 atm=760 torrÞð16:0 L CH4 Þ
(b) n¼ ¼ ¼ 0:513 mol CH4
RT ð0:0821 L atm=mol KÞð300: KÞ
The molar mass for CH4 is 16.04 g=mol
ð16:04 g=molÞð0:513 molÞ ¼ 8:23 g CH4
g
(c) PV ¼ nRT, but n ¼ where M is the molar mass and g is the grams of the gas.
M
gRT
Thus, PV ¼ . To determine density, d ¼ g=V.
M
gRT g g PM
Solving PV ¼ for produces ¼ .
M V V RT
g ð4:00 atmÞð44:01 g=mol CO2 Þ
d¼ ¼ ¼ 8:48 g=L CO2
V ð0:0821 L atm=mol KÞð253 KÞ
- 155 -
- Chapter 12 -
g PM
(d) Since d ¼ ¼ from part (c), solve for M (molar mass)
V RT
dRT ð2:58 g=LÞð0:0821 L atm=mol KÞð300: KÞ
M¼ ¼ ¼ 63:5 g=mol ðmolar massÞ
P 1:00 atm
86. Assume 100. g of material to start with. Calculate the empirical formula.
1 mol 7:14
C ð85:7 gÞ ¼ 7:14 mol ¼ 1:00 mol
12:01 g 7:14
1 mol 14:2
H ð14:3 gÞ ¼ 14:2 mol ¼ 1:99 mol
1:008 g 7:14
The empirical formula is CH2. To determine the molecular formula, the molar mass
must be known.
2:50 g 22:4 L
¼ 56:0 g=molðmolar massÞ
L mol
56:0
The empirical formula mass is 14:0 ¼4
14:0
Therefore, the molecular formula is ðCH2 Þ4 ¼ C4 H8
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- Chapter 12 -
P 1 V1 P 2 V2
¼
T1 T2
P1 V1 T2 ð760 torrÞð1:00 LÞð290 KÞ
V2 ¼ ¼ ¼ 1:8 L
P2 T1 ð450 torrÞð273 KÞ
m 1:29 g
d¼ ¼ ¼ 0:72 g=L
V 1:8 L
90. Each gas behaves as though it were alone in a 4.0 L system.
(a) After expansion: P1 V1 ¼ P2 V2
P1 V1 ð150: torrÞð3:0 LÞ
For CO2 P2 ¼ ¼ ¼ 1:1 102 torr
V2 4:0 L
P1 V1 ð50: torrÞð1:0 LÞ
For H2 P2 ¼ ¼ ¼ 13 torr
V2 4:0 L
(b) Ptotal ¼ PH2 þ PCO2 ¼ 110 torr þ 13 torr ¼ 120 torr ð2 sig: figuresÞ
- 157 -
- Chapter 12 -
93. 1st step: find the volume of CO2 that must be produced
55:0 L CO2
volume CO2 ¼ ðvolume of batterÞð55:0%Þ ¼ ð1:32 L batterÞ ¼ 0:726 L CO2
100 L batter
2nd step: find the moles of CO2 needed to produce the necessary rise in the cupcakes
PV
PV ¼ nRT or n ¼
RT
1 atm
P ¼ ð738 torrÞ ¼ 0:971 atm
760 torr
V ¼ 0:726 L
T ¼ 325 F ¼ 163 C ¼ 436 K
ð0:971 atmÞð0:726 LÞ
n ¼ ¼ 0:0197 mol CO2
ð0:0821 L atm=mol KÞð436 KÞ
3rd step: Calculate the mass of sodium bicarbonate which will produce the CO2 needed
3 mol NaHCO3 84:02 g
ð0:0197 mol CO2 Þ ¼ 1:66 g NaHCO3
3 mol CO2 1 mol
4th step: calculate mass of sodium bicarbonate needed to add since only 63.7% will decompose to form
carbon dioxide
100 g NaHCO3 added
ð1:66 g NaHCO3 reactedÞ ¼ 2:61 g NaHCO3 added
63:7 g NaHCO3 reacted
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