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Petroleum
Petroleum, or crude oil, is a fossil fuel and nonrenewable source of energy.
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P H OTO G R A P H
Petroleum
Petroleum, also called crude oil, is a fossil fuel. Like coal and natural gas,
petroleum was formed from the remains of ancient marine organisms, such
as plants, algae, and bacteria. Over millions of years of intense heat and
pressure, these organic remains (fossils) transformed into carbon-rich
substances we rely on as raw materials for fuel and a wide variety of
products.
P H OTO G R A P H BY R E B E C C A H A L E
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A RT I C L E VO C A B U L A RY
Millions of years ago, algae and plants lived in shallow seas. After dying and
sinking to the seafloor, the organic material mixed with other sediments
and was buried. Over millions of years under high pressure and high
temperature, the remains of these organisms transformed into what we
know today as fossil fuels. Coal, natural gas, and petroleum are all fossil fuels
that formed under similar conditions.
Print
Crude oil is usually black or dark brown, but can also be yellowish, reddish,
tan, or even greenish. Variations in color indicate the distinct chemical
compositions of different supplies of crude oil. Petroleum that has few
metals or sulfur, for instance, tends to be lighter (sometimes nearly clear).
When petroleum products such as gasoline are burned for energy, they
release toxic gases and high amounts of carbon dioxide, a greenhouse gas.
Carbon helps regulate Earth’s atmospheric temperature, and adding to the
natural balance by burning fossil fuels adversely affects our climate.
There are huge quantities of petroleum found under Earth’s surface and
in tar pits that bubble to the surface. Petroleum even exists far below the
deepest wells that are developed to extract it.
Oil supplies will run out. Eventually, the world will reach “peak oil,” or its
highest production level. Some experts predict peak oil could come as soon
as 2050. Finding alternatives to petroleum is crucial to global energy use,
and is the focus of many industries.
Formation of Petroleum
The geological conditions that would eventually create petroleum formed
millions of years ago, when plants, algae, and plankton drifted in oceans and
shallow seas. These organisms sank to the seafloor at the end of their life
cycle. Over time, they were buried and crushed under millions of tons of
sediment and even more layers of plant debris.
With more heat, time, and pressure, the kerogen underwent a process
called catagenesis, and transformed into hydrocarbons. Hydrocarbons are
simply chemicals made up of hydrogen and carbon. Different combinations
of heat and pressure can create different forms of hydrocarbons. Some
other examples are coal, peat, and natural gas.
Sedimentary basins, where ancient seabeds used to lie, are key sources of
petroleum. In Africa, the Niger Delta sedimentary basin covers land in
Nigeria, Cameroon, and Equatorial Guinea. More than 500 oil deposits have
been discovered in the massive Niger Delta basin, and they comprise one of
the most productive oil fields in Africa.
The gasoline we use to fuel our cars, the synthetic fabrics of our backpacks
and shoes, and the thousands of different useful products made from
petroleum come in forms that are consistent and reliable. However, the
crude oil from which these items are produced is neither consistent nor
uniform.
Chemistry
Crude oil is composed of hydrocarbons, which are mainly hydrogen (about
13 percent by weight) and carbon (about 85 percent). Other elements such
as nitrogen (about 0.5 percent), sulfur (0.5 percent), oxygen (1 percent), and
metals such as iron, nickel, and copper (less than 0.1 percent) can also be
mixed in with the hydrocarbons in small amounts.
The way molecules are organized in the hydrocarbon is a result of the
original composition of the algae, plants, or plankton from millions of years
ago. The amount of heat and pressure the plants were exposed to also
contributes to variations that are found in hydrocarbons and crude oil.
Due to this variation, crude oil that is pumped from the ground can consist
of hundreds of different petroleum compounds. Light oils can contain up to
97 percent hydrocarbons, while heavier oils and bitumens might contain
only 50 percent hydrocarbons and larger quantities of other elements. It is
almost always necessary to refine crude oil in order to make useful products.
Classification
Oil is classified according to three main categories: the geographic location
where it was drilled, its sulfur content, and its API gravity (a measure of
density).
Classification: Geography
Oil is drilled all over the world. However, there are three primary sources of
crude oil that set reference points for ranking and pricing other oil supplies:
Brent Crude, West Texas Intermediate, and Dubai and Oman.
Brent Crude is a mixture that comes from 15 different oil fields between
Scotland and Norway in the North Sea. These fields supply oil to most of
Europe.
West Texas Intermediate (WTI) is a lighter oil that is produced mostly in the
U.S. state of Texas. It is “sweet” and “light”—considered very high quality.
WTI supplies much of North America with oil.
Dubai crude, also known as Fateh or Dubai-Oman crude, is a light, sour oil
that is produced in Dubai, part of the United Arab Emirates. The nearby
country of Oman has recently begun producing oil. Dubai and Oman crudes
are used as a reference point for pricing Persian Gulf oils that are mostly
exported to Asia.
The OPEC Reference Basket is another important oil source. OPEC is the
Organization of Petroleum Exporting Countries. The OPEC Reference
Basket is the average price of petroleum from OPEC’s 12 member countries:
Algeria, Angola, Ecuador, Iran, Iraq, Kuwait, Libya, Nigeria, Qatar, Saudi
Arabia, the United Arab Emirates, and Venezuela.
Sweet oil is usually much more valuable than sour because it does not
require as much refining and is less harmful to the environment.
Light oils are preferred because they have a higher yield of hydrocarbons.
Heavier oils have greater concentrations of metals and sulfur, and require
more refining.
Petroleum Reservoirs
Crude oil is frequently found in reservoirs along with natural gas. In the
past, natural gas was either burned or allowed to escape into the
atmosphere. Now, technology has been developed to capture the natural
gas and either reinject it into the well or compress it into liquid natural gas
(LNG). LNG is easily transportable and has versatile uses.
Extracting Petroleum
Oil Rigs
On land, oil can be drilled with an apparatus called an oil rig or drilling rig.
Offshore, oil is drilled from an oil platform.
Primary Production
Most modern wells use an air rotary drilling rig, which can operate 24 hours
a day. In this process, engines power a drill bit. A drill bit is a cutting tool
used to create a circular hole. The drill bits used in air rotary drilling rigs are
hollow steel, with tungsten rods used to cut the rock. Petroleum drill bits
can be 36 centimeters (14 inches) in diameter.
As the drill bit rotates and cuts through the earth, small pieces of rock are
chipped off. A powerful flow of air is pumped down the center of the hollow
drill, and comes out through the bottom of the drill bit. The air then rushes
back toward the surface, carrying with it tiny chunks of rock. Geologists on
site can study these pieces of pulverized rock to determine the different
rock strata the drill encounters.
When the drill hits oil, some of the oil naturally rises from the ground,
moving from an area of high pressure to low pressure. This immediate
release of oil can be a “gusher,” shooting dozens of meters into the air, one
of the most dramatic extraction activities. It is also one of the most
dangerous, and a piece of equipment called a blowout preventer
redistributes pressure to stop such a gusher.
Pumps are used to extract oil. Most oil rigs have two sets of
pumps: mud pumps and extraction pumps. “Mud” is the drilling fluid used
to create boreholes for extracting oil and natural gas. Mud pumps circulate
drilling fluid.
One of the most familiar types of extraction pumps is the pumpjack, the
upper part of a piston pump. Pumpjacks are nicknamed “thirsty birds” or
“nodding donkeys” for their controlled, regular dipping motion. A crank
moves the large, hammer-shaped pumpjack up and down. Far below the
surface, the motion of the pumpjack moves a hollow piston up and down,
constantly carrying petroleum back to the surface or well.
Successful drilling sites can produce oil for about 30 years, although some
produce for many more decades.
Secondary Recovery
Even after pumping, the vast majority (up to 90 percent) of the oil can
remain tightly trapped in the underground reservoir. Other methods are
necessary to extract this petroleum, a process called secondary recovery.
Vacuuming the extra oil out was a method used in the 1800s and early 20th
century, but it captured only thinner oil components, and left behind great
stores of heavy oil.
The most prevalent secondary recovery method today is gas drive. During
this process, a well is intentionally drilled deeper than the oil reservoir. The
deeper well hits a natural gas reservoir, and the high-pressure gas rises,
forcing the oil out of its reservoir.
Oil Platforms
Drilling offshore is much more expensive than drilling onshore. It usually
uses the same drilling techniques as onshore, but requires a massive
structure that can sustain the tremendous strength of ocean waves in
stormy seas.
The platform can either be tethered to the ocean floor and float, or can be a
rigid structure that is fixed to the bottom of the ocean, sea, or lake with
concrete or steel legs.
The Hibernia platform, 315 kilometers (196 miles) off Canada’s eastern shore
in the North Atlantic, is one of the world’s largest oil platforms. More than
70 people work on the platform, in three-week shifts. The platform is 111
meters (364 feet) tall and is anchored to the ocean floor. About 450,000
tons of solid ballast were added to give it additional stability. The platform
can store up to 1.3 million barrels of oil. In total, Hibernia weighs 1.2 million
tons! However, the platform is still vulnerable to the crushing weight and
strength of icebergs. Its edges are serrated and sharp to withstand the
impact of sea ice or icebergs.
When oil spills in the ocean, it floats on the water and wreaks havoc on the
animal population. One of its most devastating effects is on birds. Oil
destroys the waterproofing abilities of feathers, and birds are not insulated
against the cold ocean water. Thousands can die of hypothermia. Fish and
marine mammals, too, are threatened by oil spills. The dark shadows cast by
oil spills can look like food. Oil can damage animals’ internal organs and be
even more toxic to animals higher up in the food chain, a process
called bioaccumulation.
Rigs to Reefs
Offshore oil platforms can also act as artificial reefs. They provide a surface
(substrate) for algae, coral, oysters, and barnacles. This artificial reef can
attract fish and marine mammals, and create a thriving ecosystem.
Until the 1980s, oil platforms were deconstructed and removed from the
oceans, and the metal was sold as scrap. In 1986, the National Marine
Fisheries Association developed the Rigs-to-Reefs Program. Now, oil
platforms are either toppled (by underwater explosion), removed and
towed to a new location, or partially deconstructed. This allows the marine
life to continue flourishing on the artificial reef that had provided habitats
for decades.
Crude oil does not always have to be extracted through deep drilling. If it
does not encounter rocky obstacles underground, it can seep all the way to
the surface and bubble above ground. Bitumen is a form of petroleum that
is black, extremely sticky, and sometimes rises to Earth’s surface.
In its natural state, bitumen is typically mixed with “oil sands” or “tar sands,”
which makes it extremely difficult to extract and an unconventional source
of oil. Only about 20 percent of the world’s reserves of bitumen are above
ground and can be surface mined.
Unfortunately, because bitumen contains high amounts of sulfur and heavy
metals, extracting and refining it is both costly and harmful to the
environment. Producing bitumen into useful products releases 12 percent
more carbon emissions than processing conventional oil.
Bitumen is about the consistency of cold molasses, and powerful hot steam
has to be pumped into the well in order to melt the bitumen to extract it.
Large quantities of water are then used to separate the bitumen from sand
and clay. This process depletes nearby water supplies. Releasing the treated
water back into the environment can further contaminate the remaining
water supply.
Bitumen Reserves
Most of the world’s tar sands are in the eastern part of Alberta, Canada, in
the Athabasca Oil Sands. Other major reserves are in the North Caspian
Basin of Kazahkstan and Siberia, Russia.
The Athabasca Oil Sands are the fourth-largest reserves of oil in the world.
Unfortunately, the bitumen reserves are located beneath part of the boreal
forest, also called the taiga. This makes extraction both difficult and
environmentally dangerous.
The taiga circles the Northern Hemisphere just below the frozen tundra,
spanning more than 5 million square kilometers (two million square miles),
mostly in Canada, Russia, and Scandinavia. It accounts for almost one-third
of all of the forested land on the planet.
The taiga is sometimes called the “lungs of the planet” because it filters
tons of water and oxygen through the leaves and needles of its trees every
day. Every spring, the boreal forest releases immense amounts of oxygen
into the atmosphere and keeps our air clean. It is home to a mosaic of plant
and animal life, all of which depend on the mature trees, mosses, and lichen
of the boreal biome.
Surface mines are estimated to only take up 0.2 percent of Canada’s boreal
forest. About 80 percent of Canada’s oil sands can be accessed through
drilling, and 20 percent by surface mining.
Refining Petroleum
Crude oil comes out of the ground with impurities, from sulfur to sand.
These components have to be separated. This is done by heating the crude
oil in a distillation tower that has trays and temperatures set at different
levels. Oil’s hydrocarbons and metals have different boiling temperatures,
and when the oil is heated, vapors from the different elements rise to
different levels of the tower before condensing back into a liquid on the
tiered trays.
Petroleum Industry
Oil was not always extracted, refined, and used by millions of people as it is
today. However, it has always been an important part of many cultures.
The earliest known oil wells were drilled in China as early as 350 C.E. The
wells were drilled almost 244 meters (800 feet) deep using strong bamboo
bits. The oil was extracted and transported through bamboo pipelines. It
was burned as a heating fuel and industrial component. Chinese engineers
burned petroleum to evaporate brine and produce salt.
The modern oil industry was established in the 1850s. The first well was
drilled in Poland in 1853, and the technology spread to other countries and
was improved.
The Industrial Revolution created a vast new opportunity for the use of
petroleum. Machinery powered by steam engines quickly became too slow,
small-scale, and expensive. Petroleum-based fuel was in demand. The
invention of the mass-produced automobile in the early 20th century
further increased demand for petroleum.
Although that seems like an impossibly high amount, the uses for
petroleum have expanded to almost every area of life. Petroleum makes our
lives easy in many ways. In many countries, including the U.S., the oil
industry provides millions jobs, from surveyors and platform workers to
geologists and engineers.
The United States consumes more oil than any other country. In 2011, the
U.S. consumed more than 19 million barrels of oil every day. This is more
than all of the oil consumed in Latin America (8.5 million) and Eastern
Europe and Eurasia (5.5 million) combined.
Petroleum is also used in liquid products such as nail polish, rubbing alcohol,
and ammonia. Petroleum is found in recreational items as diverse as
surfboards, footballs and basketballs, bicycle tires, golf bags, tents,
cameras, and fishing lures.
Carbon Cycle
Not all of the carbon on Earth is involved in the carbon cycle above ground.
Vast quantities of it are sequestered, or stored, underground, in the form of
fossil fuels and in the soil. This sequestered carbon is necessary because it
keeps Earth’s “carbon budget” balanced.
The taiga, for example, sequesters vast amounts of carbon in its trees and
below the forest floor. Drilling for natural resources not only releases the
carbon stored in the fossil fuels, but also the carbon stored in the forest
itself.
Gasoline and diesel also directly pollute the atmosphere. They emit toxic
compounds and particulates, including formaldehyde and benzene.
However, a developing country’s access to oil can also affect the power
relationship between a government and its people. In some countries,
having access to oil can lead government to be less democratic—a situation
nicknamed a “petro-dictatorship.” Russia, Nigeria, and Iran have all been
accused of having petro-authoritarian regimes.
Peak Oil
Oil is a nonrenewable resource, and the world’s oil reserves will not always
be enough to provide for the world’s demand for petroleum. Peak oil is the
point when the oil industry is extracting the maximum possible amount of
petroleum. After peak oil, petroleum production will only decrease. After
peak oil, there will be a decline in production and a rise in costs for the
remaining supply.
Measuring peak oil uses the reserves-to-production ratio (RPR). This ratio
compares the amount of proven oil reserves to the current extraction rate.
The reserves-to-production ratio is expressed in years. The RPR is different
for every oil rig and every oil-producing area. Oil-producing regions that
are also major consumers of oil have a lower RPR than oil producers with low
levels of consumption.
According to one industry report, the United States has an RPR of about
nine years. The oil-rich, developing nation of Iran, which has a much lower
consumption rate, has an RPR of more than 80 years.
It is impossible to know the precise year for peak oil. Some geologists argue
it has already passed, while others maintain that extraction technology will
delay peak oil for decades. Many geologists estimate that peak oil might be
reached within 20 years.
Petroleum Alternatives
Bioasphalts, for example, are asphalts made from renewable sources such as
molasses, sugar, corn, potato starch, or even byproducts of oil processes.
Although they provide a nontoxic alternative to bitumen, bioasphalts
require huge crop yields, which puts a strain on the agricultural industry.
FA ST FAC T
FA ST FAC T
Playtime
A “petroleum play” is full of drama! A petroleum play is a group of oil fields
in a single geographic region, created by the same geologic forces or
during the same time period. A petroleum play may be defined by a time
period (Paleozoic play), rock type (shale play), or a combination of both.
FA ST FAC T
FA ST FAC T
Proven Reserves
These nations have the world’s largest proven oil reserves.
1. Saudi Arabia
2. Venezuela
3. Canada
4. Iran
5. Iraq
Source: U.S. Energy Information Administration
FA ST FAC T
Tar Pits
In Los Angeles, California, United Stats, bitumen has been seeping to Earth’s
surface for thousands of years at what is now called the La Brea Tar Pits. The
pits have preserved fossils of saber-toothed cats, mastodons, turtles, dire
wolves, horses, and other plants and animals that were trapped in the sticky
substance 40,000 years ago. Bitumen continues to bubble up through the
ground today.
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