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Metals & Non-Metals
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Chapter
METALS & NON-METALS
Chapter Outline
Graphite conducts
electric current Carbon Fibres
ELEMENTS
Metals
Metals are the electropositive elements which possess tendency of losing one or more of their valence
electrons attaining octet and thereby forming cations.
Non-Metals
Non-metals are the electronegative elements which possess tendency to form anion (negative ions) by
gaining one or more electrons.
Aluminium foil
COMPETITIVE LEVEL
The most expensive metal is rhodium, which sells for more than $ 176,000 per kilogram. Platinum
and gold, numbers two and three.
Alumininum is mostly used in making beverage cans and recycling one aluminium can save enough
energy to run a TV for three hours.
(vi) Non-metals are not lustrous: Non-metals are not lustrous and cannot be poslihed.
Exception: Graphite and Iodine are lustrous non-metals.
(vii) Non-metals have low densities: Generally non-metals have low densities.
Exception: Iodine has high density and diamond which is almost as heavy as Al.
(viii) Non-metals have low melting and boiling points: Generally non-metals have generally low
melting and boiling points.
Exception: Graphite, another allotropic form of Carbon, has a melting point of about 3730°C.
Other exceptions are C, B, Si which have high melting and boiling points.
(ix) Tensile strength: Non-metals have low tensile strength.
Exception: Carbon fibre is as tensile as steel.
(x) Sonorous: Non-metals are non-sonorous, i.e., when struck with a hammer they do not produce
sound.
(xi) Colour: Chlorine is a greenish yellow gas, while bromine is brown in colour. Iodine is violet in
colour , while oxygen and nitrogen are colourless gases.
COMPETITIVE LEVEL
Coming up too fast from deep sea diving gives the "bends" which is nitrogen bubbles in your blood.
The sound you hear when you crack your knuckles is actually nitrogen gas bubbles popping.
(c) Graphite
Different forms of Carbon
(iii) Hardness Generally hard, except for sodium Generally soft, except for diamond
and potassium
(iv) Density High Low
(v) Malleability and ductility Malleable and ductile Brittle
(vi) Thermal conductivity Generally good conductors Generally bad conductors
(vii) Electrical conductivity Generally good conductors Generally bad conductors, except for graphite which
conducts electricity through it.
(viii) Sonority Sonorous Non sonorous
(ix) Tensile strength High Low
Melting and boiling points High, except for sodium and Low, except for graphite
(x)
potassium
Na Na+ + e–
(2,8,1) (2,8)
Mg Mg2+ + 2e–
(2,8,2) (2,8)
Al Al3+ + 3e–
(2,8,3) (2,8)
Since the metal atoms lose electrons and form positively charged ions, therefore, the metals are called
electropositive elements.
Sodium oxide reacts with water to form an alkali called sodium hydroxide. Therefore, sodium
oxide is a basic oxide.
Na2O + H2O 2NaOH
(Sodium hydroxide)
Due to the formation of sodium hydroxide (which is an alkali), the solution of sodium oxide in
water turns red litmus blue (common property of all alkaline solutions).
Similarly, magnesium is a metal and it reacts on heating with oxygen, catches fire and burns
with a brilliant white flame to form magnesium oxide.
2Mg + O2 2 MgO
(Magnesium oxide)
The magnesium oxide reacts with acids (say sulphuric acid) to form magnesium sulphate
(a salt) and water as the only products. Thus, magnesium oxide is a basic oxide in nature.
MgO + H2SO4 (dil.) MgSO4 + H 2O
(Magnesium (Sulphuric acid) (Magnesium (Water)
Oxide) sulphate)
COMPETITIVE LEVEL
(ii) Amphoteric Nature: Aluminium oxide, zinc oxide, Beryullium oxide etc. are amphoteric and
show both acidic as well as basic behaviour. These react with both acids and bases to form
salts. For example.
(2) Reaction with Water: Different metals behave differently in their chemical reaction with water.
(i) Metals like sodium and potassium react with water as follows-
When a small piece of sodium or potassium is dropped in cold water -
It floats and at the same time melts to form a silvery ball of metal.
The silvery ball of the metal darts over the surface of water with a hissing noise producing
tiny bubbles of the hydrogen gas.
The silvery ball becomes smaller in size and catches fire.
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In case of sodium, it burns with a golden yellow flame, whereas in case of potassium, it
burns with a lilac flame.
2K + 2H2O 2KOH + H2
Hydroxide)
When calcium metal is dropped in water, the following observations are made:
It gradually dissolves in water and the colour of water becomes milky due to the formation
of partially soluble calcium hydroxide.
Ca + 2H2O Ca(OH)2 + H2
Zn + H2O
ZnO + H2
Heat
3 Fe + 4 H2
O Fe3O4 + 4 H2
Heat
Activity
Aim: To observe the reaction of sodium with water.
Procedure:
(i) Take a 250 mL beaker containing about 200 mL of water.
(ii) Put a small piece (of wheat grain size) of sodium into it and observe what happens.
Do you see a vigorous reaction with the evolution of fumes in the beaker? Why does the piece of
sodium catch fire sometimes?
(iii) Dip a red litmus paper into the solution in the beaker. Why did the red litmus turn blue? Why does
the solution become basic?
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Reaction of sodium with water
Conclusion: Sodium is highly reactive. On reaction with water, it produces sodium hydroxide
(basic) and hydrogen gas which catches fire. It is due to this sodium hydroxide that the litmus
paper changes its colour.
Sulphuric acid, hydrochloric acid and nitric acid are called mineral acids. These acids in dilute
form react with metals to form their respective salts and hydrogen gas.
Many metals react with dilute acids and liberate hydrogen gas. Only less reactive metals such
as copper, silver, gold etc. do not liberate hydrogen from dilute acids.
The reactions of metals with dilute hydrochloric acid (HCl) and dilute sulphuric acid (H2SO4)
are similar. With dil. HCl, they give metal chlorides and hydrogen, whereas with dil. H 2SO4,
they give metal sulphates and hydrogen.
Displacement reaction: A more reactive metal can displace a less reactive metal from its salt
solution.
For example:
(i) Sodium, magnesium and calcium react violently with dilute hydrochloric acid (HCl) or
dilute sulphuric acid liberating hydrogen gas and corresponding metal salt.
Similarly,
(Magnesium Sulphate)
(Ferrous Sulphate)
COMPETITIVE LEVEL
Reaction of Metals with dilute Nitric acid: Metals on reacting with dilute nitric acid do not
give hydrogen gas due to strong oxidizing nature of nitric acid which oxidizes the hydrogen (H 2)
produced in the reaction to water (H2O). Nitric acid itself gets reduced to an oxide of nitrogen
such as nitrous oxide (N2O), nitric oxide (NO) or nitrogen dioxide (NO 2).
Note: Copper does not react with dilute HCl or dil. H 2SO4
Hydroxide)
(5) Displacement Reactions of Metals with Salt Solutions:
When a more reactive metal is placed in a salt solution of less reactive metal, then the more
reactive metal displaces the less reactive metal from its salt solution.
For example: When a strip of zinc metal is put in the blue colour solution of copper sulphate, it
is observed that the blue colour of the solution fades gradually and copper metal is deposited on
the zinc strip. This means that the following reaction occurs:
Zinc
Zinc
Solution
solution
becomes
becomes
colourless
colourless
Copper sulphate
Copper sulphate Depositof
Deposit of
Solution
solution (blue)
(blue) copper
copper
However, if we take zinc sulphate solution and put a strip of copper metal in this solution, no
reaction occurs.
ZnSO4 (aq) + Cu(s) No reaction
This means that copper cannot displace zinc metal from its solution. Thus, we can conclude that zinc is
more reactive than copper. However, if we put gold or platinum strip in the copper sulphate solution,
then copper is not displaced by gold or platinum. Thus, gold and platinum are less reactive than copper.
Activity
Aim: To observe displacement reaction.
Procedure:
(i) Take five beakers with about 50 cc of water in each and label them as I, II, III, IV and V.
(ii) Now dissolve about 2 g of each substance (given below) in the beakers as shown in figure.
(iii) Stir the contents in each beaker and record your observation.
Beaker I: Iron nails/filings + Copper sulphate.
Beaker II: Iron nails/filing + Zinc sulphate.
Beaker III: Copper turnings + Iron sulphate.
Beaker IV: Copper turnings + Magnesium sulphate.
Beaker V: Zinc granules + Copper sulphate.
Why do you see no change in beakers II, III and IV, while copper precipitates in beakers I and V
with the formation of iron sulphate and zinc sulphate respectively?
In the process the blue colour of copper sulphate disappears in beaker I and V.
Displacement reaction
Conclusion: More reactive zinc and iron displace less reactive copper from its salt.
Fe Iron
Ni Nickel
Sn Tin
Pb Lead
[H] [Hydrogen]
Cu Copper
Hg Mercury
Ag Silver
Au Gold
Pt Platinum Least
Reactive
It may be noted that hydrogen is not a metal, but even then it has been placed in the reactivity
series. This is due to the fact that:
(i) Hydrogen can also lose electron and form positive ion, H +.
(ii) Hydrogen has also been included in the series to compare the reactivities of metals with respect
to it.
The more reactive nature of iron as compared to copper can be easily shown by dipping some iron
nails in the solution of copper suphate. The iron nails get covered with copper layer and the blue
colour of copper sulphate solution change to greenish colour of ferrous sulphate.
Fe(s) + CuSO4 (aq) Cu(s) + FeSO4 (aq)
(Blue) (Green)
Similarly copper displaces silver from silver nitrate solution.
2AgNO3(aq) + Cu(s) Cu(NO3)2(aq) + 2Ag(s)
(Blue) (White)
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Utility of Activity Series
The activity series is very useful and it gives the following information:
(i) The metal which is higher in the activity series is more reactive than the metals which are placed
below it. Lithium is the most reactive and platinum is the least reactive metal.
(ii) The metals which have been placed above hydrogen are more reactive than hydrogen and can
displace hydrogen from its compounds like water and acids to liberate hydrogen gas.
(iii) The metals which are placed below hydrogen are less reactive than hydrogen and cannot displace
hydrogen from its compounds like water and acids.
(iv) A more reactive metal (placed higher in the activity series) can displace the less reactive metal
from the solution of its salt.
(v) Metals at the top of the series are very reactive and, therefore, they do not occur free in nature,
while the metals at the bottom of the series are least reactive and, therefore, they normally occur
free in nature.
Note:Metals more reactive than hydrogen lose electrons more readily than hydrogen and metals less
reactive than hydrogen lose electrons less readily than hydrogen.
(i) Acidic Oxides: The oxides of Carbon, Sulphur, Phosphorus etc. are acidic and they turn blue
litmus solution red.
For example:
Carbon reacts with oxygen of air to form carbon dioxide gas which dissolves in water to
form an acid called carbonic acid.
Sulphur burns in air to form sulphur dioxide gas which dissolves in water to form an acid
called sulphurous acid.
Pentaoxide)
Note: White phosphorus has been extensively used in bombs, artillery, short-range missiles and
mortars since world war II.
Pure phosphorus exists in several forms called allotropes – white, red, violet and black
phosphorus. All the allotropes have different physical properties.
COMPETITIVE LEVEL
(ii) Neutral oxides: Some oxides of non-metals are neutral. For example, carbon monoxide (CO), nitric
oxide (NO), nitrous oxide (N2O), water (H2O), etc. These oxides do not turn blue litmus solution
red.
Non-metal oxides are covalent in nature and are formed by the sharing of electrons.
Activity
Aim: To observe the action of oxygen on sulphur.
Procedure:
(i) Take a small amount of sulphur powder in a deflagrating spoon and heat it as shown in figure.
(ii) Heat the sulphur powder on a low flame. When sulphur starts burning, introduce the spoon into a
glass jar and cover it with a lid. Do not expose yourself to the fumes as they are toxic.
(iii) Now put a small amount of water into the jar and shake it.
Test the solution with a blue litmus paper. What do you observe? Does the blue litmus turn red?
Why?
Conclusion: Sulphur reacts with oxygen in the air to form sulphur dioxide, which when dissolved in
water forms sulphurous acid that turns blue litmus red.
Uses of metals
(viii) Some metals play an important role in the functioning of living systems in animals and human
beings. Iron is a constituent of haemoglobin in blood which carries oxygen in various parts of the
body. Copper and zinc are constituents of enzymes. Sodium and potassium take part in electrical
activity in nerves and in contraction of muscles.
(ix) Zinc is used in making dry cells.
(x) Lead is used in making automobile batteries, type metal, bullets, protective screens for X-rays
and sanitary fittings.
Note: Thermite, a mixture of iron oxide and fine aluminium powder, is used for welding of rails together
when they are broken.
Fe2O3 + Al Al2O3 + Fe
Sulphur
(i) It is used in many medicines as a germicide. It is also used in skin ointments as an antiseptic.
(ii) Sulphur is used in the vulcanization of rubber.
The process of heating rubber with sulphur or sulphur compounds under heat and pressure to improve
elasticity and strength or to produce a hard substance is known as vulcanization
Phosphorous
(i) It makes an alloy with bronze which can resist corrosion.
(ii) It is used in the preparation of matchsticks, fireworks and smoke screens.
Nitrogen
(i) Plants use nitrogen to prepare protein, an essential ingredient of our food.
(ii) Nitrogen is inert in nature, so liquid nitrogen is used to preserve blood and other donated organs. It
is also used in food packaging as food does not spoil easily in an inert medium.
Note: Nitrogen is used in the preparation of ammonia by Haber's process. Ammonia is used to prepare
nitrogenous fertilizer.
Haber's Process: It is the commercial method of producing ammonia. It was invented by a
German chemist Fritz Haber.
500ºC, 200atm
N2(g) + 3H2(g) 2NH3(g)
Fe, Mo
Silicon
(i) Silicon is used to make silicon-steel alloy and in the preparation of silicones, which have a wide
variety of uses.
(ii) Silicon is used in making semiconductor devices such as transistors.
Chlorine:
(iii) It is used as a bleaching agent in paper and textile industries. It is also used in the preparation of
bleaching powder.
Ca (OH) 2 + Cl 2 CaOCl 2 + H 2 O
(Slaked lime ) ( Chlorine ) ( Bleaching powder ) Water
Iodine
(i) It is used as an antiseptic. Its solution in alcohol with some potassium iodide is called tincture of
iodine which is applied on cuts. Its paste in petroleum jelly is used to relieve pain.
(ii) It is used in the preparation of iodized salt to prevent a disease called goitre.
Corrosion
Most of the metals get degraded when kept exposed to moist air.
The process of slowly eating up of metals due to this conversion into oxides, carbonates, sulphide, etc.,
by the action of atmospheric gases and moisture is called corrosion.
For example,
Corrosion of Iron (Called Rusting): Iron when exposed to moist air for a long time acquires a
coating of a brown flaky substance called rust. Rust in mainly hydrated ferric oxide, Fe2O3. xH2O.
3
2Fe + O2 + xH2O Fe 2 O3 . xH 2 O
Iron 2 Hydrated ferric oxdie
( Rust )
Q.1 Which Non-metal is used in vulcanization Q.16 (i) All metals are hard except …………….
of rubber? and ………………… .
Q.2 Write one use of nitrogen.
(ii) …………………. is the only non-metal
Q.3 Name the gas that burns with a pop sound which is liquid at room temperature.
Q.4 The elements which show the properties of (iii) …………………. is the best conductor of
both metals and non-metals. electricity.
Q.6 Name the Non-metal used in the (v) ………………………. is the only non-
preparation of Ammonia? Also write the metal, which is a good conductor of
chemical reaction. heat and electricity.
Q.12 (i) Why lemon pickle cannot be stored in Match the Column
an aluminium foil?
(ii) Why gold is preferred in making jewellery ? Q.18
Column-A Column-B
Q.13 Explain the following terms (a) Gold (i) Liquid metal
(i) Sonorous (b) Mercury (ii) Sodium oxide
(ii) Lustrous (c) Acidic oxide (iii) Iron oxide
(iii) Metalloids. (d) Basic oxide (iv) Noble metal
(e) Rust (v) Sulphur dioxide
Q.14 Diffentiate between metal & Non-metals
Q.2 What is the chemical formula of hydrated Q.12 The solution of ash of magnesium ribbon
copper sulphate? is -
(A) CuSO4 . 5H2O (B) CuSO4 . 7H2O (A) Acid (B) Basic
(C) CuS (D) Cu2S (C) Neutral (D) All of these
Q.3 Which non-metals catches fire if exposed to Q.13 Which metal is found in liquid state at
air? room temperature?
(A) Sodium (B) Phosphorus (A) Fe (B) Zn (C) Hg (D) Al
(C) Calcium (D) Uranium
Q.14 Which among the following is the poorest
conductor of heat?
Q.4 Which metal is present in Haemoglobin?
(A) Silver (B) Gold
(A) C (B) O (C) Fe (D) H
(C) Copper (D) Lead
Q.5 Which one of the following metals reacts
Q.15 Solid fuel is –
vigorously with oxygen and water?
(A) Petrol (B) Diesel
(A) Sodium (B) Aluminium
(C) Coke (D) Alcohol
(C) Calcium (D) Magnesium
Q.16 Iron is galvanized by coating it with –
Q.6 Sodium metal is stored in –
(A) Nickel (B) Chromium
(A) Water (B) Alcohol (C) Manganese (D) Zinc
(C) Kerosene (D) Ether
Q.17 Diamond is measure in which unit?
Q.7 Oxides of Non metals are ……………….. in (A) carat (B) grams
nature – (C) ponds (D) Micrograms
(A) Basic (B) acidic
(C) neutral (D) All of these Q.18 22 carat gold is mixture of?
(A) Cu and Au (B) Zn and Au
Q.8 Sulphuric acid turns blue litmus paper (C) Al and Au (D) Mg and Au
into –
(A) Red (B) Green Q.19 Which metal is use to wrap food items?
(C) yellow (D) dark blue (A) Iron (B) Zinc
(C) Aluminium (D) Calcium
Q.9 The form of carbon used for cutting rocks is
(A) diamond. (B) graphite. Q.20 Argon, krypton and xenon are known as
(C) lampblack. (D) charcoal. (A) free gases.
(B) inert gases.
Q.10 When sulphur dioxide is dissolved in water (C) reactive gases.
what is formed? (D) atmospheric gases.
(A) Sulphur (B) Sulphur trioxide
(C) Sulphuric acid (D) Sulphurous acid
EXERCISE - 1
Fill in the Blanks:
16. (i). Sodium, Potassium
(ii). Bromine
(iii). Silver
(iv). acidic, acid
(v). graphite
EXERCISE - 2
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. C A A C A C B A A D A B C D C
Ques. 16 17 18 19 20
Ans. D A A C B
EXERCISE - 3
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Ans. C B A C A C B D A B A C C C
Sol.20 [B]
Noble gases or Inert gases, the name comes
from the fact that these elements are
virtually unreactive towards other elements
or compounds.
Sol.5 [A]
Bromine is a non-metal which exists as a
liquid at room temperature.
Sol.6 [C]
Metals are sonorous which means metals
produce ringing sound on being hit. This
happens due to high delocalisation of
electrons in metals.