This document contains questions about haloalkanes and haloarenes. It asks the student to arrange compounds by boiling point, explain differences in dipole moments, reactivity in SN1 and SN2 reactions, and distinguish between similar compounds. It also asks the student to draw structures of monohalo products and describe conversions between organic compounds.
This document contains questions about haloalkanes and haloarenes. It asks the student to arrange compounds by boiling point, explain differences in dipole moments, reactivity in SN1 and SN2 reactions, and distinguish between similar compounds. It also asks the student to draw structures of monohalo products and describe conversions between organic compounds.
This document contains questions about haloalkanes and haloarenes. It asks the student to arrange compounds by boiling point, explain differences in dipole moments, reactivity in SN1 and SN2 reactions, and distinguish between similar compounds. It also asks the student to draw structures of monohalo products and describe conversions between organic compounds.
3.Which one of the following has the highest dipole moment?
(i) CH2Cl2 (ii) CHCl3 (iii) CCl4 4.Explain why (i) the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride? (ii) alkyl halides, though polar, are immiscible with water? (iii) Grignard reagents should be prepared under anhydrous conditions? 5.Arrange the compounds of each set in order of reactivity towards SN2 displacement: (i) 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane. (ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane. (iii) 1-Bromobutane, 1-Bromo-2, 2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-3-methylbutane. 6.
7.Give reasons: [CBSE Delhi 2016]
(i) C—Cl bond length in chlorobenzene is shorter than C—Cl bond length in CH3—Cl. (ii) SN1 reactions are accompanied by racemisation in optically active alkyl halides. 8.How will you distinguish between the following pairs of compounds: (i) Chloroform and carbon tetrachloride. (ii) Benzyl chloride and chlorobenzene. 9.Draw the structures of the major monohalo product for each of the following reactions:
10.How do you convert the following:
(i) Prop-1-ene to 1-fluoropropane (ii) Chlorobenzene to 2-chlorotoluene (iii) Ethanol to propanenitrile