electrolytic cells X and Y connected in seriee

33. (a) Asteady current of 2 Amperes was passed through two cathode of cell X. How long did
containing electrolytes FeSO, and ZnSO, until 2.8 gof Fe deposited at the
the current flow? Calculate the mass

(Molar mass: Fe = 56 g mol, Zn = 65.3 g mol, 1F =96500Cmol)

following curve obtained for two
(b) In the plot of molar conductivity A.. Vs. square root of concentration (C"),
electrolytes A and B:
B

^m

Answer the following:

(i) Predict the nature of electrolytes Aand B:
5
(i) What happens on extrapolation of A,, to concentration approaching zero for electrolytes Aand B?
OR

(a) Calculate e.m.f. of the following cell:

Zn(s)|Zn² (0.1 M) || (0.01 M) Ag*|Ag(s)
Given:E - 0 . 7 6 V, E.... =+0.80 V
[Given: log 10 = 1]
(b) Xand Yare two electrolytes. On dilution molar conductivity of 'X increases 2.5 times while that Yincreases
25 times. Which of the two is a weak electrolyte and why? 5
33. (a) How is a double salt different from a complex ?
(b) What is the denticity of coordination compound used for the treatment of lead poisoning ?
(c) Write the coordination number and oxidation state of platinum in the complex (Pt(en),CILJ.
(d) What is meant by chelate effect ?
OR

(a) Write the IUPAC name of the following complex:

[P(NH),CI,]
(b) Write the formula for the following:
Tetraammineaquachloridocobalt (II) nitrate
(c) How is stepwise stability constants and overall stability constant formed are related ?
Explain with an example.
31. Read the passage given below and answer the following questions:
Products of electrolysis depend on the nature of material being electrolysedthe and the type of electrodes being used.
in chemical reaction and acts oniy as
If the electrode is inert (e.g., Platinum or gold), it does not participate
reactive,it participates in the electrode reaction.
source or sink for electrons. On the other hand, if the electrode is inert electrodes. The products of electrolysis
reactive and
Thus,the products of electrolysis may be different for presernt in the electrolytic cell and their standard electrode
depend on the different oxidising and reducing species
potentials. whether Ti species
the basis of the standard electrode potential values stated for acid solutions, predict
(a) On
Fe(III).
may be used to oxidise Fe(Il) to
E° = +0.01V
T+ +e T;3+ 1
+ e ’ Fe2+ E° = +0.77V
Fe +2 oxidation state.
data, arrange Fe*, Mn* and Cr* in the increasing order of stability of
(b) Based on the
(Give a brief reason)
Ectc2 =0.4V
Mn3tMn2+ = +1.5V 1
E°,
+0.8V
E Fe3tFe2+ =
generally used in hearing aids.
(c) (i) Name the cell which is 2
of electrolysis depends?
(ii) On which factor do the product OR
electrode?
reactions occurring on their surtace? What is the role of inert
Do inert electrodes participate in the 2