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LAKSHYA JEE 2023

Electrochemistry DPP-04

1. The Nernst equation giving dependence of electrode 7. The standard EMF of the cell reaction:
oxidation potential on concentration is
Zn + Cu+2  Zn+2 + Cu is 1.10 volt at 25°C.
2.303RT
(1) E  Eo  log[M  n ] The EMF for the cell reaction when 0.1 M Cu+2 and
nF
2.303RT [M n  ] 0.1 M Zn+2 solutions are used at 25°C is
(2) E  Eo  log (1) 1.10 V (2) 0.110 V
nF [M]
2.303RT (3) –1.10 V (4) –0.110 V
(3) E  Eo  log[M n  ]
nF
2.303RT [M] 8. Eo for F2 + 2e–  2F– is 2.8 V. Eo for
(4) E  Eo  log n 
nF [M ] 1
F2 + e–  F– is
2. The potential of single electrode depends upon 2
(1) The nature of the electrode (1) 2.8 V (2) 1.4 V
(2) Temperature (3) –2.8 V (4) –1.4 V
(3) Concentration of the ion with respect to
which it is reversible
9. For the redox change
(4) All of the above
2 2
Zn(s) + Cu (0.1 M)  Zn (1 M) + Cu(s)
3. The oxidation potential of Hydrogen half-cell will
be negative if taking place in a cell, E ocell is 1.10 volt. Ecell for the
(1) P(H 2 ) = 1 atm and [H+] = 1 M cell would be
(2) +
P(H 2 ) = 1 atm and [H ] = 2 M (1) 1.07 V (2) 0.82 V
(3) 2.14 V (4) 1.80 V
(3) P(H 2 ) = 0.2 atm and [H+] = 1 M
(4) Both (2) and (3)
10. E ocell for the cell reaction
4. The oxidation potential of a hydrogen electrode at
Zn + Cu+2  Zn+2 + Cu
pH = 10 and PH 2 = 1 is
( Eo = – 0.76 V, E o = 0.34 V)
(1) 0.51 V (2) 0.00 V Zn 2 /Zn Cu 2 /Cu
(3) 0.59 V (4) 0.059 V (1) 2.20 V (2) 3.30 V
5. Standard electrode potential for (3) 0.55 V (4) 1.10 V
Cu+2 + e–  Cu+
Cu+ + e–  Cu 11. Which is the correct representation for Nernst
are 0.15 V and 0.50 V respectively. equation?
The value of E o will be 0.059 [oxidant]
Cu 2 /Cu (1) E RP  E oRP  log
n [product]
(1) 0.150 V (2) 0.50 V
(3) 0.325 V (4) 0.650 V o 0.059 [oxidant]
(2) E OP  E OP  log
n [reductant]
6. G o for the reaction Cu+2 + Fe  Fe+2 + Cu is
o 0.059 [reductant]
 E o 2 (3) E OP  E OP  log
 0.34V, E o 2  0.44V  n [oxidant]
 Cu /Cu Fe /Fe 
(1) 19.3 kJ (2) 180.8 kJ (4) All of these
(3) 150.5 kJ (4) 28.5 kJ
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12. The standard oxidation potential Eo for the half

reactions are
Zn  Zn+2 + 2e– Eo = 0.76 V
Ag  Ag+ + e– Eo = –0.77 V
The standard EMF of the cell
Ag+ + Zn  Zn+2 + Ag is
(1) 1.53 V (2) –1.53 V
(3) –0.01 V (4) 0.01 V