Important Instructions:

1. Immediately fill in the particulars on this page of the Test Booklet with Blue or Black Ball Point Pen.
To mark answers on the OMR Sheet, use Blue or Black ball point pen only.
2. The Test Booklet consists of 180 questions. There are three sections in the question paper, Subject I, II and
III consisting of Physics (45 Questions), Chemistry (45 Questions), Botany (45 questions) & Zoology (45
questions) in each subject of equal weightage.
3. Each question is allotted 4 (four) marks for correct response. For each wrong answer, 1 (One) mark will be
deducted. No deduction from the total score will be made if no response is indicated for an item in the
answer sheet.
4. There is only one correct response for each question. Filling up more than one response in any question
will be treated as wrong response and marks for wrong response will be deducted accordingly as per
instruction 3 above.
5. No candidate is allowed to carry any text material, printed or written, mobile phone or any electronic
device, etc. inside the examination room/hall.
6. Do not fold or make any stray mark on the Answer Sheet.
7. The candidates are governed by all Rules and Regulations of the Examination body with regard to their
conduct in the Examination Hall. All cases of unfair means will be dealt with as per Rules and Regulations
of the Examination body.
SUBJECT SYLLABUS COVERED
System of particles and Rotational Motion, Gravitation, Mechanical Properties of solids
PHYSICS
and fluids, Thermal properties of matter
States of Matter, Solid State, Thermodynamics and Thermochemistry, Chemical and
CHEMISTRY
Ionic Equilibrium, Chemical Kinetics, Electrochemistry, Surface Chemistry
Anatomy of flowering plants, Transport in plants, Mineral nutrition, Photosynthesis,
BOTANY
Respiration in Plants, Plant growth and movement
Digestion & Absorption, Breathing & Exchange of gases, Body fluids & Circulation,
ZOOLOGY
Excretory products and their elimination, Locomotion & Movement
 Vidyamandir Classes
SECTION - II (CHEMISTRY) 180 MARKS
46. The EMF of the following cells are: (1) –0.476 V (2) –0.404V
Cu / Cu 2
1M  || Ag 1M  / AgE

 0.46 V (3) +0.404V (4) +0.777V
Zn / Zn 2 (1M) || Cu 2 (1M) / Cu E   1.10V 51. Equivalent conductance of 1M ethanoic acid is
The EMF of the cell 10 ohm –1cm2 eq –1 and at infinite dilution is 200
17 Zn / Zn 2 (1M) || Ag  (1M) / Ag will be: ohm –1cm2 eq –1 . pH of ethanoic acid solution is
(1) +0.64V (2) +1.56V 17 (log 5 = 0.6990):
(3) –0.64V (4) –1.56V (1) 7 (2) 3.3
47. How much will E° of hydrogen electrode (3) 1.3 (4) 6.8
change when its solution initially at pH = 0 is
52. For the complex
neutralized to pH = 7?
(1) Increase by 0.059 V Ag   2NH 3   Ag  NH 3  2 

17 (2) Decrease by 0.050 V  
(3) Increase by 0.41V dx
 2  107 L2 mole 2 sec 1  Ag    NH3 
2
(4) Decrease by 0.41V dt  
48. Eored of different half cells are given below 
1  102 sec1  Ag  NH3 2 
EoCu 2 /Cu  0.34V EoZn 2 /Zn   0.76V
16  
Hence, ratio of rate constants of the forward and
backward reaction is:
E oAg 1 /Ag   0.80V E oMg 2 /Mg   2.37V
(1) 2  107 L2 mol2
17 In which cell G° is most negative:
(1) Zn / Zn 2 (1M) || Ag  (1M) / Ag (2) 2  109 L2 mol 2

(2) Cu / Cu 2 (1M) || Ag  (1M) / Ag (3) 1  10 2 L2 mol2

(3) Ag / Ag  (1M) || Mg 2 (1M) / Mg (4) 0.5  10 9 L2 mol2
(4) Zn / Zn 2 (1M) || Mg 2 (1M) / Mg 53. Following reaction can take place in both
K
direction A ‡ˆ ˆˆ ˆ1ˆ †ˆ B for the forward reaction
49. The standard E° for OCl – /Cl – and K 2
– and for the backward reaction
Cl / 1 / 2Cl2 respectively are 0.94V and –1.36
V. The E° of OCl – / 1 / 2Cl2 will be:
Rate
(1) –0.42V (2) –2.20V
16 (Msec-1)

(3) +0.52V (4) 1.04V

50. Standard electrode potential: [A] M
2 –
Fe  2e  Fe E  –0.440V [B] Rate

Fe 3  3e –  Fe E  – 0.036V 0.01 M 1 102 M sec1

17
The E° for Fe 3  1e –  Fe 2 is: 0.02 M 2  102 M sec1

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 Vidyamandir Classes
Hence net reaction rate is: (4) K1  NO2   K CO
(1)  K1  A   K 2  B 56. For the reaction
(2)  K1  K 2  B A(g)  B(g)  C(g)
(3)  K1  A   K 2  dA   K
Rate law is  A
dt
(4)  K1  K 2
At the start time pressure is 100 mm and after
54. The reaction of NO 2 (g) and O3 (g) is first order 10 min, pressure is 120 mm.
in NO 2 (g) and O3 (g) . Hence, rate constant ( Min –1 ) is:
2NO 2 (g)  O3 (g)  N 2O5 (g)  O2 (g) 2.303 6
(1) K 10g
The reaction can take place by mechanism 10 5
16 I. NO2  O3 
slow
 NO3  O 2 16 (2) K
2.303
10
log 5
fast
NO3  NO 2 
 N 2 O5
2.303 5
fast (3) K log
II. O3 ‡ˆ ˆˆ ˆˆ †ˆ O 2  O 10 4
slow
NO2  O 
 NO3 2.303 5
(4) K log
fast 10 6
NO3  NO2 
 N 2 O5
57. For a third order kinetics 2NO  O2  2NO2
Select correct mechanism:
(1) Ist only (2) IInd only d  NO 
 K  NO  O 2 
2
(1) 
(3) Both I and II dt

(4) None of I and II.

16 d  NO 
 K  NO   O 2 
2
(2) 
dt
55. Following reaction takes place by mechanism
1 d  NO  d O 2  1 d  NO 2 
NO2  CO  NO  CO2 (3)   
2 dt dt 2 dt
K1
Step – I NO 2  NO 2   NO3  NO (4) Both (2) and (3)
slow

K2 58. In the reaction, A  B  C  D the initial

Step – II NO3  CO   NO 2  CO 2
fast concentration of reaction is 1mole/lit each. The
16 Hence
dx
for the given reaction is:
equilibrium concentration of each product is 0.9
dt moles l it –1 . Its K C is:

K1  NO 2  — K 2  NO3  CO 
2
(1) (1) 0.9 (2) 0.81
(3) 81 (4) 8.1
K1  NO2   K 2  NO3 CO
2
(2)
59. Given KSP (AgI)  8.5  10 –17 M 2 . The
K1  NO2 
2
(3) solubility of AgI in 0.1 M KI solution is:

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 Vidyamandir Classes
(1) 8.5  10 –15 M 64. If P is the pressure of gas, then the kinetic
energy per unit volume of the gas is:
(2) 8.5  10 –16 M 5 (1) P/2 (2) P
(3) 8.5  10 –17 M (3) 3P/2 (4) 2P
65. A gas is heated through 1°C in a closed vessel
(4) 8.5  10 –18 M
and so the pressure increases by 0.4%. The
60. In a structure, A atom have fcc arrangement, B initial temperature of the gas was:
atoms occupy all the tetrahedral sites and C
atoms occupy half the octahedral sites. The
5 (1) 250°C
(2) 100°C
14 formula of the compound is: (3) –75°C
(1) A 2 B2 C 2 (2) A 2 B4 C (4) –23°C
(3) AB2 C (4) A 4 B2 C 66. Two vessels A and B have volumes V and 4V
61. The intermetallic compound LiAg crystallizes respectively. Both vessels contain some water.
in a cubic lattice in which lithium and silver The pressure in the space above water is P1 in
atoms have co-ordination number of 8. To what vessel A and P2 in vessel B at temperature T
crystal class does the unit cell belong? which one is correct:
14 (1) Simple cubic (1) P1  P2 (2) 4P1  P2
(2) Face centred cubic
(3) P1  4P2 (4) P1  16P2
(3) Body-centred cubic
(4) End centred cubic 67. As the temperature is raised from 20°C to 40°C,
the average kinetic energy of neon atoms
62. The pK a of acetic acid and pK b of ammonium
changes by a factor:
hydroxide are 4.763 and 4.75 respectively.
Calculate the pH of ammonium acetate 5 (1) 2 (2)
313

g solution.
293

(1) 7.005 (2) 4.005 313 1

(3) (4)
(3) 2.005 (4) 11.0 293 2
63. Consider the statements as given below: 68. Which one of the following reactions at
equilibrium, with all reactants and products in
a. CH 4 gas diffuses 2 times faster than
the gaseous phase, would be unaffected by an
O2
increase in pressure.
b. He diffusion 2 times faster than O 2 (1) N 2  3H 2 ƒ 2NH 3
- c. O 2 diffuse 2 times more than SO 2 (2) 2CO  O 2 ƒ 2CO 2
d. He gas diffuses 1.414 times slower than (3) 2H 2  O2 ƒ 2H 2 O
H 2 gas (4) N 2  O 2 ƒ 2NO
Among the above, the correct statements are:
69. For the reaction PCl3 (g)  Cl2 (g) ƒ PCl5 (g) , the
(1) b, c (2) a, c
(3) c, d (4) a, d value of K C at 250°C is 26 mol –1 /litre. The value
of K p at this temperature will be:

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 Vidyamandir Classes
(1) 0.61 atm –1 (2) 0.57 atm –1 (3) It contains only two species H3O and
(3) 0.85 atm –1 (4) 0.46 atm –1 OH –
70. What would happen to a reversible reaction at (4) It contains three species H 2 O
equilibrium when temperature is raised, given (molecules), H3O and OH 
that its H is positive:
(1) More of the products are formed 75. Equal volumes of two solutions of a strong acid
(2) Less of the products are formed having pH 3 and pH 4 are mixed together. The
(3) More of the reactants are formed pH of the resulting solution will then be equal
(4) It remains in equilibrium to:
(1) 3.5 (2) 3.26
71. For the reaction, 2NO 2 (g) ƒ 2NO(g)  O 2 (g) , (3) 7 (4) 1.0
K C  1.8 1016 at 185C. At 185C, the value 76. In a mixture of CH 3COOH and CH3COONa ,
of K C for the reaction. the ratio of salt to acid concentration is
1 increased by ten folds. The pH of the solution
NO(g)  O 2 (g) ƒ NO 2 (g) is:
2 will increase by:
(1) 0.9  106 (2) 7.5 102 (1) Zero (2) 1
(3) 1.95 10 –3
(4) 1.95 103 (3) 2 (4) 3

72. One mole of N 2 O4 (g) at 300K is kept in a 77. Which of the following expressions is not true?
closed container under one atm. It is heated to (1) [H  ]  [OH  ]  K W for a neutral
600K when 20% by mass of N 2 O4 (g) solution
decomposes to NO 2 (g) . The resultant pressure (2) [H  ]  K W and [OH  ]  K W for an
is: acidic solution
(1) 1.2 atm (2) 2.4 atm (3) [H  ]  K W and [OH  ]  K W for an
(3) 2.0 atm (4) 1.0 atm
alkaline solution
73. 40% of a mixture of 0.2 mol of N 2 and 0.6 mol
(4) [H  ]  [OH  ]  107 M for a neutral
of H 2 react to give NH3 according to the
solution at all temperatures
equation. N 2 (g)  3H 2 (g) ƒ 2NH 3 (g) at
constant temperature and pressure. Then the 78. 10 5 M NaOH solution at 25°C is diluted 1000
ratio of the final volume to the initial volume of times. The pH of the solution will:
gases are: (1) be equal to 8
(1) 4:5 (2) 5:4 (2) lie between 7 and 8
(3) 7:10 (4) 8:5 (3) lie between 6 and 7
(4) remain unchanged
74. Correct statement regarding pure water
amongst the following is: 79. In decinormal solution, CH 3COOH is ionized
(1) It contains only single specie i.e. H 2 O to the extent of 1.3%. If log 1.3 = 0.11 what is
molecules the pH of the solution?
(1) 3.89 (2) 4.89
(2) It contains three species: H 2 O
(3) 2.89 (4) 2.89
(molecules), H  and OH –
80. The co-ordination number of metal crystallizing
in a hexagonal close packed structure is:
I
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 Vidyamandir Classes
(1) 12 (2) 4 2NO(g )  O 2 (g )  2NO 2 (g)  y kJ
(3) 8 (4) 6 The value of H f of NO(g) is:
81. In closest packing of atoms: 1
(1) The size of tetrahedral void is greater (1) (y  x)
2
than that of the octahedral void. (2) y – 2x
(2) The size of the tetrahedral void is smaller
(3) x–y
14 than that of the octahedral void.
(3) The size of tetrahedral void is equal to (4) 2(x – y)
that of the octahedral void. 87. The value of H° for the hypothetical reaction
(4) The size of tetrahedral void may be A 2 B(s)  2A(s)  ½ B2 (g ) is + 7.3 kJ
larger or smaller or equal to that of the
The value of Uº for the reaction is:
octahedral void depending upon the size
of atoms. (1)  7.3 kJ (2)  7.3 kJ
(3) = 7.3 kJ (4) Unpredictable
82. If a be the edge-length of the unit cell, r be the
radius of an atom, then for face centered cubic 88. Given
NH3 (g)  3Cl2 (g) ƒ NCl3 (g)  3HCl(g)
14 lattice, the correct relation is:
H1
(1) 4r  3a (2) 4r  2a
(3) 4a  3r (4) None of these N 2 (g)  3H 2 (g) ƒ 2NH 3 (g)  H 2
H 2 (g)  Cl2 (g) ƒ 2HCl(g) H3
83. The heat of neutralization of a strong base and
The heat of formation of NCl3 (g) in the terms
strong acid is 57.0 kJ eq 1 . The heat evolved
of H1 , H 2 and H3 is:
when 0.5 mole of HNO3 solution is added to 6 H 2 3
0.2 moles of NaOH solution, is: (1) H f  H1   H3
(1) 57.0 kJ (2) 28.5 kJ 2 2
(3) 11.4 kJ (4) 34.9 kJ H 2 3
(2) H f  H1   H3
84. The temperature of a 5 ml of strong acid 2 2
increases by 5°C when 5 ml of a strong base is H 2 3
(3) H f  H1   H3
added to it. If 10 ml of each are mixed, 2 2
temperature should increase by: (4) None of these
(1) 5°C (2) 10°C 89. Which of the following is best protective
(3) 15°C (4) Cannot be known colloid?
85. Difference of enthalpy change and internal (1) Gelatin (2) Albumin 18
energy change for the formation of carbon (3) Starch (4) Gum Arabic
mono oxide from its constituent elements at 90. Which of the following has maximum
298 K is: flocculation value for Fe(OH)3 sol?
(1) –1238.78 J mole –1
(1) PO34
–1
(2) +1238.78 J mole
(3) –2477.57 J mole –1
(2) SO24 18
(4) 2477.57 J mole –1 (3)  Fe(CN)6  4

86. N 2 (g )  2O 2 (g )  2NO 2 (g )  x kJ (4) Cl

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