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ARJUNA JEE 2023

Chemical Bonding DPP – 06

1. In which of the following molecules, the central atom 9. The geometry of the molecule XeO2 F2 is
has two lone pairs of electrons? (1) distorted octahedral
(1) SF4 (2) BrF5 (2) square planar
(3) SO2 (4) XeF4 (3) trigonal bipyramidal
(4) tetrahedral
2. Incorrect matching amongst the following is:
(i) Linear - H2O, SO2 10. Match list I (compounds) with list II (structures), and
(ii) V-shaped - :CH2 , SnCl2 select the correct answer using the codes given below
(iii) See Saw – SF4 , TeCl4 List I List II
(iv) T-shaped - ICl3 , ClF3 (a) XeO4 (i) square planar
(1) only (i) (2) both (ii and (ii) (b) BrF4− (ii) tetrahedral
(3) only (iii) (4) both (iii) and (iv) (c) (iii) Distorted tetrahedral
SeCl4
3. In XeF2, XeF4 and XeF6 the number of lone pair of (1) (a – ii) (b – iii) (c – i)
electrons on Xe is respectively. (2) (a – iii) (b – i) (c – ii)
(Atomic numbers: F = 9, Xe = 54) (3) (a – ii) (b – i) (c – iii)
(1) 2, 3, 1 (2) 1, 2, 3 (4) (a – i) (b – ii) (c – iii)
(3) 4, 1, 2 (4) 3, 2, 1
11. Which of the following atomic orbital overlappings
4. The molecule which has T-shaped structure is: are not allowed?
(1) BCl3 (2) NCl3
(3) ICl3 (4) PCl3
5. The geometry around the central atom in ClF4+ is (P) (Q)
(1) square planar
(2) square pyramidal
(3) octahedral (R) (S)
(4) trigonal bipyramidal

6. According to VSEPR model, the shape of [XeOF5 ]− is

(1) octahedral (T)
(2) trigonal bipyramidal
(3) square pyramidal (1) All of these (2) (P) (Q) (R)
(4) pentagonal monopyramidal (3) (P) (R) (T) (4) (Q) only

7. According to VSEPR theory, the geometry (with lone 12. In which of the following pairs both the species have
pair) around the central iodine in I3+ and I3− ions sp 3 hybridization?
respectively are (1) SiF4 , BeH2 (2) NF3 , H2O
(1) tetrahedral and tetrahedral (3) NF3 , BF3 (4) H2S, BF3
(2) trigonal bipyramidal and trigonal bipyramidal
(3) tetrahedral and trigonal bipyramidal 13. Which of the following statements is correct?
(4) tetrahedral and octahedral
(1) sp 3 hybrid orbitals have equal s and p character.
8. The number of lone pair(s) of electrons on the central (2) The bond angle decreases with the decrease of s
character of hybridized orbital.
atom in [BrF4 ]− , XeF6 and [SbCl6 ]3− are, respectively
(3) Resonance decreases the stability of a molecule.
(1) 2,0 and 1 (2) 1,0 and 0 (4) Resonance is due to delocalization of sigma
(3) 2,1 and 1 (4) 2,1 and 0 electrons.
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14. What is the percentage of 𝑠-subshell in H2 O molecule? 17. The state of hybridization of C2 , C3 , C5 and C6 of
(1) 33.33% (2) 50% the hydrocarbon,
(3) 25% (4) 75% CH3 CH3
CH 3 6C CH CH C C CH
15. The hybridisation and shape of ClO3− is: 7 5 4 3 2 1
(1) sp3 and tetrahedral CH3
(2) sp3 and triangular pyramidal is in the following sequence:
(3) sp3 and triangular planar
(4) sp3d and trigonal bipyramidal (1) sp, sp 2 , sp3 and sp 2
(2) sp, sp3 , sp 2 and sp3
16. In the following molecule, the two carbon atoms
marked by asterisk (∗) possess the following type of (3) sp3 , sp 2 , sp 2 and sp
hybridized orbitals: (4) sp, sp 2 , sp 2 and sp3
* *
H3C – C  C – CH3
18. Which has sp 2 - hybridization?
3 2
(1) sp -orbital (2) sp -orbital (1) CO2 (2) SO2
(3) sp -orbital (4) s-orbital
(3) N 2O (4) CO
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Note: Kindly find the Video Solution of DPPs Questions in the Quiz Section

Answer Key
1. (4) 10. (3)
2. (1) 11. (2)
3. (4) 12. (2)
4. (3) 13. (2)
5. (4) 14. (3)
6. (4) 15. (2)
7. (3) 16. (3)
8. (3) 17. (2)
9. (3) 18. (2)

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