STD : XI THERMODYNAMICS

2 & 3 Marks Questions

1.State Zeroth law of thermodynamics
2. State first law of thermodynamics
3. Give Clausius statement of second law of thermodynamics
4. Give Kelvin Planck statement of second law of thermodynamics
5. Define (i) isothermal process (ii)adiabatic process(iii)isobaric process(iv)isochoric process
6. Define the following terms
*System
* surroundings
*Homogeneous system
* Heterogeneous system
* Isolated system
* closed system
*open system
*Reversible process
*Irreversible process
*Cyclic process
7. What are extensive and intensive properties?Give two examples each.
8. What are state and path functions?Give two examples each.
9. Define a)Calorie (b) Joule
10. State the third law of thermodynamics
11. Define Enthalpy
12. State Hess’s law of constant heat summation .
13. Define lattice energy.
14. Give the entropy statement of second law of thermodynamics.
15. Define enthalpy of combustion.
16. Define Gibb’s free energy.
17. What are spontaneous reactions? What are the conditions for the spontaneity of a process?
18. Identify the state and path functions out of the following a) enthalpy b)entropy c)heat
d)temperature e)work f)free energy.
19. Define entropy .Give its unit.
5 Marks Questions
1. Characteristics of internal energy (pg 191)
2. Various statements of first law of thermodynamics (pg 195)
3. Calculate the lattice energy of sodium chloride using Born Haber cycle.(pg 209)
4. Write down the Born Haber cycle for the formation of CaCl 2.
5. Calculate the work involved in expansion and compression process . (pg 193)
6. Derive the relationship between ∆H and ∆U for an ideal gas.Explain each term involved in the
equation.
7. Characteristics of Gibb’s free energy.
8. Mathematical statement of the first law of thermodynamics _- four cases.
9. Show that decrease in free energy is equal to the net work done by the system,
Problems:
1. 7.10 - pg 211
2. Evaluate yourself 5 – pg 211
3. 7.6 -pg 212
4. Evaluate yourself 6 pg 212
5. 7.7 - pg 213
6. Evaluate yourself 7 - pg 213