DPP-6

Chemical Bonding
Which molecule has the largest dipole moment

A HCl

B HI

C HBr

D HF
Which molecule has the largest dipole moment

A HCl

B HI

C HBr

D HF
Solution:
HF has largest dipole moment because electronegativity
difference of both is high so it is highly polar.
Which of the following will show least dipole character

A Water

B Ethanol

C Ethane

D Ether
Which of the following will show least dipole character

A Water

B Ethanol

C Ethane

D Ether
Solution:
Due to its symmetrical structure.
The dipole moment of chlorobenzene

is 1.5 D. The dipole moment of is

2.86 D B 2.25 D
A

C 1.5 D D 0D
The dipole moment of chlorobenzene

is 1.5 D. The dipole moment of is

2.86 D B 2.25 D
A

C 1.5 D D 0D
Solution:

Dipole moments of 2Cl and 5Cl are vectorically cancelled.

An ether is more volatile than an alcohol having the same
molecular formula. This is due to

A dipolar character of ethers

B alcohols having resonance structures

C inter-molecular hydrogen bonding in ethers

D inter-molecular hydrogen bonding in alcohols

An ether is more volatile than an alcohol having the same
molecular formula. This is due to

A dipolar character of ethers

B alcohols having resonance structures

C inter-molecular hydrogen bonding in ethers

D inter-molecular hydrogen bonding in alcohols

Solution:
In alcohol intermolecular H-bonding is possible whereas in ether
it is not possible.
The vapour pressure of

is higher than due to

A Dipole moment B Dipole-dipole interaction

C H – bonding D Lattice structure

The vapour pressure of

is higher than due to

A Dipole moment B Dipole-dipole interaction

C H – bonding D Lattice structure

Solution:
Ortho-nitrophenol has intramolecular H-bonding

and para-nitrophenol has intermolecular H-bonding.

Hence former is more volatile than latter.

Which one of the following arrangements of molecules is correct
on the basis of their dipole moments?

A BF3 >NF3 >NH3

B NF3 > BF3 > NH3

C NH3 > BF3 > NH3

D NH3 > NF3 > BF3

Which one of the following arrangements of molecules is correct
on the basis of their dipole moments?

A BF3 >NF3 >NH3

B NF3 > BF3 > NH3

C NH3 > BF3 > NH3

D NH3 > NF3 > BF3

 Solution:

Both NF3 and NH3 have identical shape and a lone pair of electrons on nitrogen. The dipole
moment of NH3 is higher than NF3 due to different directions of moments of the N - F and N -
H bond. BF3 has zero dipole moment.
In the following which bond will be responsible for maximum
value of hydrogen bond

A O–H

B N–H

C S–H

D F–H
In the following which bond will be responsible for maximum
value of hydrogen bond

A O–H

B N–H

C S–H

D F–H
Solution:
Hydrogen bonding will be maximum in F–H bond due to greater
electronegativity difference.
The reason for exceptionally high boiling point of water is

A Its high specific heat

B Its high dielectric constant

C Low ionization of water molecules

D Hydrogen bonding in the molecules of water

The reason for exceptionally high boiling point of water is

A Its high specific heat

B Its high dielectric constant

C Low ionization of water molecules

D Hydrogen bonding in the molecules of water

Solution:
Hydrogen bonding increases the boiling point of compound.
In the following which has highest boiling point

A HI

B HF

C HBr

D HCl
In the following which has highest boiling point

A HI

B HF

C HBr

D HCl
Solution:
HF has highest boiling point because it has hydrogen bonding.
The dipole moments of CCl4, CHCl3 and CH4 are in the
order

A CHCl3 < CH4 = CCl4

B CCl4 < CH4 < CHCl3

C CH4 = CCl4 < CHCl3

D CH4 < CCl4 < CHCl3

The dipole moments of CCl4, CHCl3 and CH4 are in the
order

A CHCl3 < CH4 = CCl4

B CCl4 < CH4 < CHCl3

C CH4 = CCl4 < CHCl3

D CH4 < CCl4 < CHCl3

Which molecules has zero dipole moment?

A H2O

B CO2

C HF

D HBr
Which molecules has zero dipole moment?

A H2O

B CO2

C HF

D HBr
Solution :
CO2 is a symmetrical molecule so its dipole moment is
zero.

CO2 molecule
Which of the following species will have intramolecular
hydrogen bonding?

A B

C D
Which of the following species will have intramolecular
hydrogen bonding?

A B

C D
Solution :

C
O
Intramolecular
H Hydrogen bonding
O
Which of the following is nonpolar?

A PCl5

B PCl3

C SF6

D IF7
Which of the following is nonpolar?

A PCl5

B PCl3

C SF6

D IF7
Solution :
SF6 is symmetrical and hence non polar because its
net dipole moment is zero.
Which has maximum dipole moment?

A C

B D
Which has maximum dipole moment?

A C

B D
Solution:
Which of the following molecules will have polar
bonds but zero dipole moment?

A O2

B CHCl3

C CF4

D None of these
Which of the following molecules will have polar
bonds but zero dipole moment?

A O2

B CHCl3

C CF4

D None of these
Solution:

If CF4, all C–F bonds are polar but due to regular geometry it has zero
dipole moment.
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