1. Which catalyst is used in Gatterman Koch formylation?

A. Anhyd. AlCl3 & Cu2Cl2

B. Anhyd. AlCl3
C. Cu2Cl2
D. CuCl2

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2. Which one of the following is used as an anticancer drug?
A. cis- [Pt(Cl2)(NH3)2]
B. cis- K2[Pt(Br2)(Cl2)
C. Na2[Co(Cl)4]
D. TiCl4 + Al (OC2H5)3

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3. Buna- N is used in :-
A. For electrical switches.
B. Making oil seals, adhesives, gaskets & tank lining.
C. Manufacture of paints & lacquers.
D. Manufacture of raincoats.

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4. Identify multimolecular solid ?
A.Aqueous starch sol.
B.Soap sol
C.Alcoholic polystyrene sol
D.Aqueous solution of sodiumlaurylsulphate
E. Sulphur sol in water.

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5. A metal crystallizes in BCC unit cell. The atomic mass of metal is 55.8 g/mol
& density is 7.9 g/cm3. Calculate the edge length of unit cell?

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6. What is the formula for cell constant?
A. Resistance × 𝐶𝑜𝑛𝑑𝑢𝑐𝑡𝑎𝑛𝑐𝑒
B. Resistance × 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 𝐶𝑜𝑛𝑑𝑢𝑐𝑡𝑎𝑛𝑐𝑒
C. 𝐶𝑜𝑛𝑑𝑢𝑐𝑡𝑎𝑛𝑐𝑒 × 𝑆𝑝𝑒𝑐𝑖𝑓𝑖𝑐 𝑅𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒
D. Resistance × 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 𝑅𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒

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7. Which of the following statements are correct for interstitial compounds?
A. They donot retain metallic conductivity.
B. They are chemically reactive.
C. They are chemically inert.
D.They have higher melting points than pure metal.

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8. How many no. of carbon atoms are there in undecane ?
A.10
B.11
C.20
D.110

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9. How many allotropes does Se have ?
A.2
B.3
C.4
D.5

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11. Identify chiral molecules among the following?
A. Isopropyl alcohol
B. Isobutyl alcohol
C. 2- pentanol
D. 1-bromo-3-butene

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12. Which one of the following amines cannot be prepared by Gabriel
phthalimide synthesis?
A. sec-propyl amine
B. tert-butylamine
C. N-methyl benzylamine
D. 2-phenylethylamine

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13. Which of the acids cannot be prepared by Grignard reagent?
(A)Acetic acid
(B) Succinic acid
(C) Formic acid
(D) All of these

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14. Glucose on reaction with Br2 water
(A) glucaric acid
(B) gluconic acid
(C) saccharic acid
(D) citric acid

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15. Schiffs reagent gives pink colour with :-
A. Acetaldehyde
B. Acetone
C. Acetic acid.
D. Methyl acetone.

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16. In resonance hybrid of ozone molecule, O-O bond length is
(A)148 pm
(B)134.5 pm
(C) 121 pm
(D) 128 pm

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17. In hydrogen peroxide, the oxidation state of oxygen is :-
A. +1
B. +2
C. -1
D. -2

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18. Identify structure of cresol?

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19. Which polymer gel is used in electrophoresis?

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20. The degree of dissociation of 0.1 M monobasic acid whose pH is 2.38?

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21. Which one have complete 4d orbitals?
A. Zn
B. Cd
C. Hg
D. As

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22. Which halogen found in liquid state at room temperature?
A. F2
B. Cl2
C. Br2
D. I2

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23. Which unit cell has packing efficiency of 52 %?
A. SCC
B. BCC
C. FCC
D. HCP

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24. Identify orbital with n=4 & l =3?
A. 4f
B. 4d
C. 3d
D. 3p

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25. Which one of the following statement is not correct about SN1 mechanism?
A.Formation of Carbocation.
B. Takes place in protic solvent.
C. Independent of concentration of OH-
D. Stronger Nucleophile favoured the reaction.

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26. Which is not a carbocyclic compounds?
A.Benzene
B.Cyclohexane
C.Pyridine
D.Naphthalene

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27. Which sugar is found in milk?
A. Lactose
B. Glucose
C. Sucrose
D. Galactose

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28. Which glycosidic linkage is present in maltose?
A. Beta 1,4 glycosidic linkage
B. Alpha 1,4 glycosidic linkage
C. Beta 1,6 glycosidic linkage
D. Alpha 1,2 glycosidic linkage

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28. Find no. of electron in d orbital for Z = 48

@crackmhtcet

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