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Yashpatil TG~ @bohring_bot

Sri Chaitanya IIT Academy.,India.


 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 09-12-2023
Time: 09:00 AM to 12:00 PM CTM-13 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball
Point Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space)
on the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and
Mathematics having 30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

(II) Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if
more than 5 questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet

Name of the Candidate (in Capital): ________________________________________________


Admission Number:

Candidate’s Signature: __________________ Invigilator’s Signature: ____________________


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Test Syllabus

PHYSICS : Electrostatics upto Electric potential of standard charge distributions,


Waves, Thermodynamics (10 Q'S fix on these selected cumulative syllabus) +
20 Q's fix on present running weekend syllabus. i.e Electrostatics :Properties
of electric charge, Coloumbo's Law,Coloumbo's Law in vector form, Force on
a point charge due to multiple charges : Principal of superposition, Force on a
point charge due continuous charge distribution , ELECTRIC FIELD : Electric
Filed intensity,Electric field due to an isolated point charge,Electric field due
to a system of point charges,Electric field due to continuous charge
distribution,Electric field of a uniformly charged long thin wire , Electric field
of a uniformly charged ring,Electric field of a uniformly charged disc ,
ELECTRIC POTENTIAL : Work done in moving a test charge along a closed
path in an electric field : Conservative nature of the electric field, potential
difference, Potential due to a point charge, Potential at a point due to a
system of charges,Potential at a point due to a continues charge distribution ,
Electric potential of standard charge distributions , Miscellaneous Problems.
CHEMISTRY : BENZENE, CHEMICAL EQUILIBRIUM (10 Q'S fix on these selected cumulative
syllabus) + 20 Q's fix on present running weekend syllabus. i.e d-
BLOCK ELEMENTS: Introduction ;Electronic configurations;oxidation states and
their stability; standard electrode potentials; interstitial compounds
;alloys;Catalytic properties; Ionization enthalpy; atomic radii; colour;
magnetic properties; complex formation;(applications of d-block metals and
their compounds as per NCERT) , Introduction ;Electronic
configurations;oxidation states and their stability; standard electrode
potentials; interstitial compounds;alloys;Catalytic properties; Ionization
enthalpy; atomic radii; colour; magnetic properties; complex formation
(applications of d-block metals and their compounds as per NCERT) ,
COMPOUNDS OF Mn & Cr: preparation, structure, and reactions of
oxoanions of chromium and manganese;(KMnO4, K2Cr2O7) (Uses as per
NCERT) , preparation, structure, and reactions of oxoanions of chromium and
manganese;(KMnO4, K2Cr2O7) (Uses as per NCERT)
MATHEMATICS : Sequence & Series, Matrices, Determinants and Linear equations, Straight
Lines (10 Q'S fix on these selected cumulative syllabus) + 20 Q's fix on
present running weekend syllabus. i.e FAMILY OF CIRCLES , Relative Position
of two Circles, Length of common tangents , Angle of intersection of two
Circles, Orthogonal Circles , Miscellaneous Problems.

Sec: Jr.Super60_STERLING BT Page 2


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India
PHYSICS
09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
d
1. Three charges Q, q,  Q are placed respectively, at distance, 0, and d from the origin,
2
on the x-axis. If the net force experienced by Q , placed at x  0 , is zero, then value of q
is
Q Q Q Q
1)  2)  3)  4) 
2 2 4 4

2. Two point charges q1  10c  and q2  25 c  are placed on the x  axis at x  1m and

v
x  4m respectively. The electric field in   at a point y  3m on y  axis is
m

 1 
take  9 109 Nm 2C 2 
 4 0 

     
1) 63i  27j 102 2) 81i  81j 102 3) 63i  27j 102 4) 81i  81j 102  
3. Charges Q1 and Q2 are at points A and B of a right angle triangle OAB (see figure). The
Q1
resultant electric field at point O is perpendicular to the hypotenuse, then is
Q2

proportional to

x22 x13 x1 x2
1) 2 2) 3 3) 4)
x1 x2 x2 x1

Sec: Jr.Super60_STERLING BT Page 3


4.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
A cube of side ‘a’ has point charges Q located at each of its vertices except at the origin
where the charge is Q . The electric field at the centre of cube is

1)
Q
3 3 0 a 2
x  y  z  2)
2Q
3 3 0 a 2
x  y  z 
3)
2Q
3 3 0 a 2
x  y  z  4)
Q
3 3 0 a 2
x  y  z 
5. An inclined plane making an angle of 300 with the horizontal is placed in a uniform
N
horizontal electric field 200 as shown in the figure. A body of mass 1kg and charge
C
5mc is allowed to slide down from rest at a height of 1m. If the coefficient of friction is
0.2, find the time taken by the body to reach the bottom
 2 0 1 0 3
 g  9.8m / s ,sin 30  ,cos 30  
 2 2 

1) 0.92s 2) 0.42s 3) 2.3s 4) 1.3s

6. Two identical tennis balls each having mass ‘m’ and charge ‘q’ are suspended from a
fixed point by threads of length
' l ' . What is the equilibrium separation when each thread makes a small angle ' ' with the
vertical?
1/2 1/3 1/3 1/3
 q 2l   q 2l   q 2l 2   q 2l 2 
1) x    2) x    3) x   2 
4) x   2 2
 2 0 mg   2 0 mg   2 0 m g   2 0 m g 
Sec: Jr.Super60_STERLING BT Page 4
7.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Figure shows a rod AB, which is bent in a 1200 circular arc of radius R. A charge  Q  is
uniformly distributed over rod AB. What is the electric field E at the centre of curvature
O?

3 3Q  3 3Q  3 3Q 3 3Q 
1)
8 0 R 2

i 2)
8 2 0 R 2
i 3)
8 2 0 R 2
 
i 4)
16 2 0 R 2

i

8. A uniform electric field E   8m / e  v / m is created between two parallel plates of length


1m as shown in figure ( where m = mass of electron and e = charge of electron). An
electron enters the field symmetrically between the plates with a speed of 2m/s. The
angle of the deviation   of the path of the electron as it comes out of the field will be
___

1
1) tan 1 4 2) tan 1  2  3) tan 1   4) tan 1  3
 3
9. A heavy ball of mass M is suspended from the ceiling of a car by a light string of mass m
(m<<M). When the car is at rest, the speed of transverse waves in the string is 60ms 1 .
When the car has acceleration a, the wave – speed increase to 60.5ms 1 . The value of a, in
terms of gravitational acceleration g, is close to
g g g g
1) 2) 3) 4)
5.47 20.47 10.47 30.47
Sec: Jr.Super60_STERLING BT Page 5
10.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
A wire of length 2L, is made by joining two wires A and B of same length but different
radii r and 2r and made of the same material. It is vibrating at a frequency such that the
joint of the two wires forms a node. If the number of antinodes in wire A is p and that in
B is q then the ratio p:q is

1) 4:9 2) 3:5 3) 1:4 4) 1:2

11. n moles of an ideal gas with constant volume heat capacity CV undergo an isobaric
expansion by certain volume. The ratio of the work done in the process, to the heat
supplied is
4nR nR nR 4nR
1) 2) 3) 4)
CV  nR CV  nR CV  nR CV  nR
12. Match the thermodynamics processes taking place in a system with the correct
conditions. In the table :
Q is the heat supplied, W is the work done and U is change in internal energy of the

system.
Process Condition
I) Adiabatic A) W  0
II) Isothermal B) Q  0
III) Isochoric C) U  0, W  0, Q  0
IV) Isobaric D) U  0
1) I-B, II-D, III-A, IV-C 2) I-B, II-A, III-D, IV-C
3) I-A, II-D, III-B, IV-C 4) I-A, II-B, III-D, IV-C
13. The internal energy (U), pressure (P) and volume (V) of an ideal gas are related as
U=3PV+4. The gas is
1) Diatomic only 2) Polyatomic only
3) Either monoatomic or diatomic 4) monoatomic only
Sec: Jr.Super60_STERLING BT Page 6
14.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Two point charges q1  2C and q2  1 C are placed at distances b  1cm and a  2cm from
the origin on the y and x axes as shown in figure. The electric field vector at point (a,b)
will subtend an angle  with the x  axis given by

1) tan   1 2) tan   2 3) tan   3 4) tan   4


15. Three charges  q, q and q are kept at the vertices of an equilateral triangle of 10cm
side. The potential at the mid point in between q , q if q  5c is.
1) 6.4 105V 2) 12.8 104V 3) 6.4 104V 4) 12.8 105V
16. Figure shows three circular arcs, each of radius R and total charge as indicated. The net
electric potential at the centre of the curvature is

Q Q 2Q Q
1) 2) 3) 4)
2 0 R 4 0 R  0 R  0 R
17. Assertion (A): Coulomb force between charges is central force.
Reason (R) : Net force on the charged particles depends on the medium between charges.
1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
3) If the Assertion is correct but Reason is incorrect.
4) If both the Assertion Reason are incorrect .

Sec: Jr.Super60_STERLING BT Page 7


18.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Assertion 1): No two electric lines of force can intersect each other.
Reason (R) : Tangent at any point of electric line of force gives the direction of electric
field.
1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
3) If the Assertion is correct but Reason is incorrect.
4) If both the Assertion Reason are incorrect .
19. Assertion 1): Positive charge has a tendency to moves from a higher potential point to a
lower potential point.
Reason (R) : Electric potential is a vector quantity.
1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
3) If the Assertion is correct but Reason is incorrect.
4) If both the Assertion Reason are incorrect .
20. Assertion 1): The value of electric potential and electric intensity at the middle point of
the line joining an electron and a proton is zero.
Reason (R) : Electric potential is vector and electric intensity is scalar quantity
1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
3) If the Assertion is correct but Reason is incorrect.
4) If both the Assertion Reason are incorrect .

Sec: Jr.Super60_STERLING BT Page 8


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is
11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. Two small spheres each of mass 10mg are suspended from a point by threads 0.5m long.

They are equally charged and repel each other to a distance of 0.20m. The charge on each

a
108 c.
of the sphere is 21 The value of a will be ____.[ given g=10ms-2]

22. An infinite number of point charges, each carrying 1c charge are placed along the
y  axis at y  1m, 2m, 4m,8m.......... The total force on a 1c point charge placed at the origin is

 1 
x 103 N . The value of x to the nearest integer is _______ Take  9 109 Nm 2 / c 2 
 4 0 

23. A small speaker delivers 2w of audio output. At a distance x cm from the speaker will
one detect 120dB intensity of sound? [given reference intensity of sound as 10-12 w/m2] .
Find value of x.
24. In a resonance tube experiment when the tube is filled with water upto height of 17.0cm
from bottom, it resonates with a given tuning fork. When the water level is raised the next
resonance with the same tuning fork occurs at a height of 24.5cm. If the velocity of sound
in air is 330m/s, the tuning fork frequency is ______Hz.

Sec: Jr.Super60_STERLING BT Page 9


25.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
A set of 20 tuning forks is arranged in a series of increasing frequencies. If each fork
gives 4 beats with respect to the preceding fork and the frequency of the last fork is
twice the frequency of the first, then the frequency of last fork is ______Hz.
26. The below P-V diagram represents the thermodynamic cycle of an engine, operating with
an ideal monoatomic gas. The amount of heat extracted from the source in a single cycle
x
PV joul . Find value of x
is  2  0 0

27. A diatomic gas  r  1.4  does 400J of work when it is expanded isobarically. The heat
given to the gas in the process is _____Joul.
28. Two charges each ‘Q’ are released when the distance between is ‘d’. Then the velocity of
Q
each charge of mass ‘m’ each when the distance between them is ‘2d’ is m / sec .
x 0 dm

Find value of x
8
29. A body of mass one gram and carrying a charge 10 C passes through two points P and

Q. The electrostatic potential at Q is OV. The velocity of the body at Q is 0.2 ms-1 and at

P is 0.028ms 1 . The potential at P is __________V.

30. Three charges each 20 c are placed at the corners of an equilateral triangle of side 0.4m.

The potential energy of the system is __________Joul

Sec: Jr.Super60_STERLING BT Page 10


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India
CHEMISTRY
09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. Which of the following are d- block elements but not regarded as transition elements.
1) Cu, Ag , Au 2) Zn, Cd , Hg 3) Fe, Co, Ni 4) Ru, Rh, Pd
32. The correct outer electronic configuration of the Niobium (Nb) (z=41)
1)  Kr  4d 4 5s 2 2)  Kr  4d 3 5s 2 3)  Kr  4d 5 5s 0 4)  Kr  4d 4 5s1
33. Statement – I : The value of enthalpy of atomization is maximum about the middle of
each series.
Statement – II : There is one unpaired electron per d – orbital and this result in stronger
interatomic attraction.
1) Statement – I is correct and Statement – II is incorrect.
2) Both Statement – I and Statement – II are incorrect.
3) Both Statement – I and Statement – II are correct.
4) Statement – I is incorrect and Statement – II is correct.
34. The correct order of first ionization enthalpy of the following elements
1) Ti  Mn  Ni  Zn 2) Mn  Ti  Zn  Ni
3) Zn  Ni  Mn  Ti 4) Ti  Mn  Zn  Ni
35. Zr 4 and Hf 4 ions have similar ionic size the responsible for it.

1) Inert pair effect 2) Diagonal relationship


3) Lanthanoid contraction 4) Photo electric effect.
36. Assertion (A): D-block elements have generally high melting points.
Reason (R) : Greater number of electrons from (n-1)d in addition to ns electrons are
involved in interatomic metallic bonding.
1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
3) If the Assertion is correct but Reason is incorrect.
4) If both the Assertion Reason are incorrect .
37. Which of the following transition element cannot exhibit variable oxidation state.
1) Sc 2) Fe 3) Cr 4) Co
Sec: Jr.Super60_STERLING BT Page 11
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
38. Assertion (A): Cu in water is more stable than Cu 1
2

Reason (R) : Enthalpy of hydration of Cu 2 is much more negative than Cu 1


1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If the Assertion is correct but Reason is incorrect.
3) If the Assertion is not correct but Reason are correct .
4) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
39. The incorrect statement is.
1) Manganate and permanganate ions are tetrahedral.
2) Magnate and permanganate ions are paramagnetic.
3) In manganate and permanganate ions the  bonding takes place by overlap of p –
orbital of oxygen and d-orbital of manganese .
4) Manganate ion is green in colour and permanganate ion is purple colour.
40. Assertion (A): E 0 values for  M 2 / M  Ni is more – negative than expected
Reason (R) : Ni 2 has low hydration enthalpy due to which is quite stable.
1) If both Assertion and Reason are correct and the Reason is correct explanation of the
Assertion.
2) If the Assertion is correct but Reason is incorrect.
3) If the Assertion is incorrect but Reason are correct .
4) If both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.
41. Match the metal ions given in column-I with the spin magnetic momentum of the ions
given in column- II
Column – I Column – II
a) Co 3 i) 8B.M
b) Cr 3
ii) 35B.M
c) Fe 3
iii) 15B.M
d) Ni 2
iv) 24 B.M
Correct Order
1) a – iv, b – iii, c – ii, d – i 2) a – i, b – ii, c – iii, d – iv
3) a – iv, b – i, c – ii, d – iii 4) a – iii, b – iv, c – i, d – ii
42. In which of the following pairs are both ions are coloured in aqueous solution.
2 3
1) Ni , Ti 2) Sc 3 , Ti 3 3) Zn 2 , Co 2 4) Ni 2 , Cu 1
Sec: Jr.Super60_STERLING BT Page 12
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India
Na2CrO4  A  Na2 SO4 
09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
B KCl
 C  NaCl
43.  orange colour  orange red colour crystal

In the above equation A,B and C are respectively.


1) K 2 SO4 , K 2CrO4 and K 2Cr2O7 2) K 2 SO4 , Na2CrO4 and Na2Cr2O7
3) H 2 SO4 , Na2Cr2O7 and K 2Cr2O7 4) HCl , K 2Cr2O7 and K 2CrO4
44. The colour of MnO ion is due to .

4

1) Presence of unpaired electron in d-orbital of Mn


2) d-d transition.
3) Close packed structure
4) Charge transfer phenomenon.
45. Which of the following alloy contain Cu and Zn
1) Bronze 2) Brass 3) German silver 4) Gunmetal
46. The value of KC is 225 for the reaction N 2  3H 2  2 NH 3 . The value of KC for the
g g g
1 3
following reaction NH 3  N 2 g   H 2 g 
2 2
1 1 1
1) 2) 3) 4) 12
2 25 15
47. A vessel contain N 2O4 and NO2 in 3:2 molar ratio at 10 atm under equilibrium now Kp for
N2O4  2 NO2 is
1) 9 atm 2) 2.6 atm 3) 4.5 atm 4) 8 atm
48. In which of the following reaction Benzene is formed.
electrolyisis
1)
NaOH
C6 H 5COO  Na  
CaO
 2) 

C6 H 5COO Na  

LiAlH 4
3) C6 H5COOH   4)
NaNH 2
C6 H5COO Na   
Cl

R
ed hot

Fetube
AA
 
lCl3/ FeCl3
B
49. Acetylene ; then A&B are
1) Toulene, Benzene 2) Benzene, cummene
3) Benzene, propyl Benzene 4) Benzene, Toulene
50. Kc units for the following reaction N 2 g   3H 2 g   2 NH 3 g 
1) Mole2.lit-2 2) Mole.lit-1 3) Mole-1.lit1 4) Mole-2.lit2

Sec: Jr.Super60_STERLING BT Page 13


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is
11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. How many of the following elements do not show variable oxidation states in their
compounds. Sc, Cr, Cu, Zn, Fe, Hg, Mn, Co.
52. In chromate ion the number of Cr  O bonds are X and in dichromate ion the number of
Cr  O bonds are Y. (Consider only sigma   bonds). Then sum of X+Y __________

53. Out of the following how many oxides are amphoteric.


MnO, Mn2O, MnO2 , Cr2O3 , Mn2O7 , Mn3O4

54. How many of the following ions have spin momentum is more than 4 B.M
Ti 3 , Cu 1 , Ni 2 , Fe3 , Mn 2 , Co 2 , Mn 3
55. Number of moles of KMnO4 required to oxidize one mole of Fe  C2O4  in acidic medium
1
is x 10 moles . The value of x is ________
56. A definite amount of solid NH 4 HS is placed in a flask already containing ammonia gas at
a certain temperature and 0.1 atm pressure NH 4 HS decomposes to give NH 3 and H 2 S
and at equilibrium. Total pressure in flask is 1.1 atm if the equilibrium constant K P for
1
the reaction, NH 4 HS  NH 3 g   H 2 S g  is represented as z 10 . Then find value of z

________.
57. For the reaction, A  B  2C . The value of equilibrium constant is 100 at 298K. If intial
concentration of all three species are 1M each, then the equilibrium concentration of C is

x 102 M . The value of x is ____ nearest integer.


58. The number of pure orbitals in Benzene is Y and number of hybridized orbital is X then
X – Y value is ___

Sec: Jr.Super60_STERLING BT Page 14


59.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.

Cl
Cl Cl
X Cl2 AA
nHy

lCl3

Cl Cl
Cl
Cl
Cl Cl
Uv
Y Cl2 5
00K


Cl Cl
Cl
Then from the above reaction sum of X+Y is equal to_______

60. Among the following, the number of aromatic compound. ________


   

Sec: Jr.Super60_STERLING BT Page 15


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India
MATHEMATICS
09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. The number of terms common to the two A.P’s: 3, 7,11, ……411 and 2, 9,16, ………716
is

1) 15 2) 14 3) 16 4) 18

62. The number of terms of an A.P is even; the sum of the odd terms is 90, and that of even
terms is 110. The last term exceeds the first by 36, then the number of terms is

1) 8 2) 4 3) 6 4) 10

63. If  and      are the roots of the equation


4
7 3
2  2
 1 3  19 19  1 3  x  5 x  5
2

1 5         4 then the value of  2    2   


 4 7   4 1   4 7    3 
19 19 

1) 51 2) 12 3) -12 4) 24

64. If the straight lines 2 x  3 y  1  0 , x  2 y  1  0 and ax  by  1  0 form a triangle with the


origin as orthocentre, then (a, b) is

1) (6, 4) 2) (-3, 3) 3) (-8, 8 ) 4) (0, 7)

cos –1 x cos –1 y cos–1 z 


 –1 –1 –1 
65. Let A= cos y cos z cos x 
 cos –1 z cos –1 x cos –1 y 
 

Such that A  0 then maximum value of  x  y  z   3xyz is

1) 3 2) 0 3) 1 4) 2

Sec: Jr.Super60_STERLING BT Page 16


66.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India
 
09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
Assertion: If the circles x  y  5kx  2 y  k  0 and 2 x 2  y 2  2kx  3 y  1  0 intersect at
2 2

the points P and Q, then the line 4 x  5 y  k  0 passes through the points P & Q for no
value of k
Reason: The common chord of intersecting circles is the radical axis.
1) Both (A) and (R) are true, and (R) is the correct explanation of (A).
2) Both (A) and (R) are true but (R) is not the correct explanation of (A).
3) (A) is true and (R) is false.
4) (A) is false and (R) is true.
67. Assertion: Consider a family of circles passing through two fixed points A  3, 7  & B  6,5 
and if the chords in which the circle x 2  y 2  4 x  6 y  3  0 cuts the members of the family
23
are concurrent. Then the point of concurrency is  2, 
 3
Reason: The equation of family of circles passing through A & B is

( AB diameter circle ) +  ( AB line) = 0
1) (A) is false and (R) is true.
2) (A) is true and (R) is false.
3) Both (A) and (R) are true, and (R) is the correct explanation of (A).
4) Both (A) and (R) are true but (R) is not the correct explanation of (A).
68. Assertion:The equation of circle passing through the point (1,2) and through the points
of intersection of x 2  y 2  4 x  6 y  21  0 and 3x  4 y  5  0 is x 2  y 2  2 x  2 y  11  0
Reason: The equation of circle passing through the points of intersections of circle S = 0
& line L = 0 is S   L  0
1) (A) is false and (R) is true.
2) (A) is true and (R) is false.
3) Both (A) and (R) are true, and (R) is the correct explanation of (A).
4) Both (A) and (R) are true but (R) is not the correct explanation of (A).
69. Tangents drawn from the point P(1,8) to the circle x 2  y 2  6 x  4 y  11  0 touch the circle
at the point A and B. The equation of the circumcircle of the triangle PAB is
1) x 2  y 2  4 x  6 y  19  0 2) x 2  y 2  4 x  10 y  19  0
3) x 2  y 2  2 x  6 y  19  0 4) x 2  y 2  6 x  4 y  19  0

Sec: Jr.Super60_STERLING BT Page 17


70.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
A circle S passes through the point (0,1) and is orthogonal to the circle  x  1  y 2  16
2

and x 2  y 2  1 , then
1) Radius of S is 8 2) Radius of S is 7
3) Centre of S is (7,-1) 4) Centre of S is (-8, 1)
71. Assertion: The circles 2 x  2 y 2  px  6 y  10  0 , and
2
3 x 2  3 y 2  15 x  py  21  0 are
orthogonal then 21 p  24
Reason: The circles S  x 2  y 2  2 gx  2 fy  c  0 and S 1  x 2  y 2  2 g 1 x  2 f 1 y  c1  0
are orthogonal if and only if 2 gg 1  2 ff 1  c  c1
1) Both (A) and (R) are true, and (R) is the correct explanation of (A).
2) Both (A) and (R) are true but (R) is not the correct explanation of (A).
3) (A) is true and (R) is false.
4) (A) is false and (R) is true.
72. The locus of centres of family of circle passing through the origin and cutting the circle
x 2  y 2  4 x  6 y  13  0 orthogonally, is
1) 4 x  6 y  13  0 2) 4 x  6 y  13  0 3) 4 x  6 y  13  0 4) 4 x  6 y  13  0

73. If two circles ( x  1)2  ( y  3)2  r 2 and x 2  y 2  8 x  2 y  8  0 intersect in two distinct points
and a  r  b then a  b =
1) 10 2) 7 3) 8 4) 6
74. The angle between the circles x 2  y 2  4 x  6 y  3  0 and x 2  y 2  8 x  4 y  11  0 is
   5
1) 2) 3) 4)
3 6 2 3
75. The circles x 2  y 2  4 x  81  0 , x 2  y 2  24 x  81  0 intersect each other at points A and B.
A line through point A meet one circle at P and a parallel line through B meet the other
circle at Q. Then the locus of the mid-point of PQ is
1) ( x  5) 2  ( y  5) 2  25 2) x 2  y 2  10 x  0
3) x 2  y 2  4 x  0 4) x 2  y 2  2 x  0
76. The equation of circle which cuts the three circles x 2  y 2  4 x  6 y  4  0 ,
2 2
x 2  y 2  2 x  8 y  4  0 and x  y  6 x  6 y  4  0 orthogonally is
2 2
4) x  y  8
2 2 2 2
1) x 2  y 2  4 2) x  y  2 3) x  y  1

Sec: Jr.Super60_STERLING BT Page 18


77.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
The common chord of circles x  y 2  4 x  4 y  0 and x 2  y 2  16 substends an angle at
2

origin is equal to
   
1) 2) 3) 4)
6 4 3 2
78. If the circle x 2  y 2  2 gx  2 fy  c  0 cuts orthogonally with the two circles
x 2  y 2  2 x  4 y  7  0 & x 2  y 2  4 x  6 y  9  0 then 3g  5 f is equal to
1) 4 2) 6 3) 8 4) 16
79. Assertion:If the angle between the circles x 2  y 2  12 x  6 y  41  0 and

x 2  y 2  kx  6 y  59  0 is then k  4
4
d 2  r12  r22
Reason: If the angle between the circles S1  0 and S2  0 is  , then cos  
2r1r2
where r1 & r2 are radii of circles S1  0 , S2  0 respectively and d  c1c2
1) Both (A) and (R) are true, and (R) is the correct explanation of (A).
2) Both (A) and (R) are true but (R) is not the correct explanation of (A).
3) (A) is true and (R) is false.
4) (A) is false and (R) is true.
80. If the circle x 2  y 2  4 x  22 y  l  0 bisects the circumference of the circle
x 2  y 2  2 x  8 y  m  0 then l  m 
1) 30 2) 40 3) 50 4) 60
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is
11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. Consider a circle C1 : x2  y 2 – 4 x – 2 y   - 5 . Let its mirror image in the line y = 2x + 1
be another circle C2 : 5 x 2  5 y 2 -10 fx -10 gy  36  0 . Let r be the radius of C2 . Then
α + r is equal to _____
82. If the circumference of the circle x 2  y 2  4 x  2 y  a  0 is bisected by the circle

x 2  y 2  2 x  3 y  b  0 then a  b  ……………

Sec: Jr.Super60_STERLING BT Page 19


83.
Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.
The sum of values of �㕝 for which the equations x  y  z  1, x  2 y  4 z  p and
x  4 y  10 z  p 2 have a solution is…………..

84. The number of 3  3 matrices M with entries from 0,1, 2 , for which the sum of the
diagonal entries of M T M is 5 is …………………
85. If the system of linear equations : x  ky  3z  0, 3x  ky  2 z  0 and 2 x  4 y  3z  0 has a

xz
non-zero solution  x, y, z  then is equal to …………
y2
86. Two circles are drawn through the points (a, 5a) and (4a, a) to touch the Y-axis. Then

1  x 
they intersect at an angle tan   then x  y  ………………. (x,y are co-prime)
 y
87. If two perpendicular tangents can be drawn from (0,-3) to the circle
x 2  y 2  2ax  8 y  15  0 then the value of  a   is …………………. ( [ ] denotes G.I.F)

88. The number of common tangents, to the circles x 2  y 2  2 x  4 y  4  0 and


x 2  y 2  10 x  2 y  10  0 , is………………

89. If A and B are square matrices of order ‘3’ such that A  3 and B  2 , then the absolute

 
value of det( A . adj 2 B .adj( adj  A )) is
1 1

l 2  3 p 0 
 
90. Let S be the set of all possible values of l , m, n, p, q, r for which A   0 m  82
q 
 r 0 n 2  15

be a non-singular idempotent matrix. Then the sum of all the elements of the set S
is………..

Sec: Jr.Super60_STERLING BT Page 20


Yashpatil TG~ @bohring_bot
Sri Chaitanya IIT Academy, India 09-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-13_Q.P.

Sec: Jr.Super60_STERLING BT Page 21

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