)Red

)Themal and Photochemital R

decomposition of vinyl azides 2) Thmal cleavage of - , bond +

CHa
e

-Ng
>R
R-C,
R
3) Photolytic eltavage q-G bond
2) Modi-fied No ber earYange ment CH

N
base
C-cHH)

)ing opening Teae tion

)Intramole culay cyelisation (Gabtvia) tion
Nuleophilie ring opening re
RHe-(HR+ RHH,’RHC-CHR HRH- CHR NHg NHa

cH -Electrophilic ving opening rtation

)2) Cycloaddi tion Teacbion
(nitvene inertiony - ElectroLyclic ring opening eactont
R
P-N H
C-cooHy
C-coocHy
2) Reayangement cooHy -cooCH}
HLNS
ut
 REACTIVITY
SYNTHESIS
COMPOUND
)Azisine )Theemol and Photochemitat
)Reaction at c N bond

decomposition of vinyl azides ) Thermal cleavage of N-s bond -

Ng
R Ng ) Photolytt eleavage -3 bond
2) Modified No be wearvange ment CH1
N-N),20 +

base
-CH(cH)

)Totramle cu lar cyetisation laabvia)Ring opening reation'

2) Azividines Nuuleophilic ving optning veatdon
RHC-(HR+ RHH,-’RHC-(AR HCI RH- (HR NH

H -Eltctrophilic ving optning reattion

a)2) Cycloaddi tion vtaction (nitvene inertion! - Eleetropyclie ving

opening eaction
R-N H

C-coocH
|2)Reasyoangemen t cooM, -cooH3
R-C-N
 REACTIVITY
COMPOUND
Azisine
SYNTHESIS
Thesmal and Photochermia
D
)Reaction at
DReaction at c=N bondt

decomposition of vinyl azides )Thermal cleavage of N- bond +

H

C
R Ng s) Photolytic cleavage G-G bord
2) Modified No ber wLaTYangement
N
base

reaction
|DIntramolecular cyelisation (sabeviadDRing openng
2) Azividines l) -Nuleophilic ring opning reation
RHC-CARH? RHC-HR NHa NHa
RHE-HR+RNH,
-Electrophi lic ing opening reaetiorn
H

acion
) ycloaddi tion Teaction (nitvene insertion) - Electropyclie ring open ing
A

+ ngco0GHs >
2) Reavrangemen t+
cóoLH, cooH
 WISDON
LOYOLA ACADEMY
ALWAL,SECUNDERABAD - 500010
vgcadamy
(Autonomous and affiliated to Osmania University)
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BONAFIDE CERTIFICATE
Purpose :Scholarship Date: 24-Nov-2023

This is to certify that GOLIKUSHAL KUMAR. bearing UID 111722503012

Son / daughter of SriG.SRIRAMULU, Smt.G.SHYAMALA is/was abonafide student of
this college studying / studied from M.Sc.-Organic Chemistry I Year during the
academic year 2023-2024.

His / her date of birth according to the college register is 01-Jul-2000 (in
words: One/Seven/Two Thousand)

His / her conductthroughout his/her college career has been

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VICE TAI (PG)

AVOK LOYOLAADEY
OLD ALWAL, SO U600 010
TELANANA, INDIA