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1/18/24, 10:02 PM SECOND QUARTER EXAM: Attempt review

Home / My courses / BAED-CHEM2122-2312S / SECOND QUARTER EXAMINATION / SECOND QUARTER EXAM

Started on Wednesday, 17 January 2024, 12:48 AM


State Finished
Completed on Wednesday, 17 January 2024, 1:13 AM
Time taken 25 mins 23 secs
Marks 49.00/50.00
Grade 98.00 out of 100.00

Question 1
Correct

Mark 1.00 out of 1.00

Chemical equilibrium is described as a dynamic process because there is a movement in which the forward and reverse reactions
occur at the same rate to reach a point where the amounts or concentrations of the reactants and products are unchanging with time.

a. True

b. False

Your answer is correct.

Question 2

Correct

Mark 1.00 out of 1.00

A photochemical reaction is one of the examples of non-spontaneous reaction.

a. False

b. True

Your answer is correct.

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Question 3

Correct

Mark 1.00 out of 1.00

If the reaction quotient Q has a smaller value than the related equilibrium constant, K, __________

a. The reaction is not at equilibrium, and will make more products at the expense of reactants.

b. The reaction is at equilibrium.

c. The value of K will decrease until it is equal to Q

d. The reaction is not at equilibrium, and will make more reactants at the expense of products.

Your answer is correct.

Question 4

Correct

Mark 1.00 out of 1.00

The equation that relates enthalpy, temperature and entropy is

a. Second Law of Thermodynamics

b. Calorimetry

c. Hess's Law

d. Gibbs Free Energy

Your answer is correct.

Question 5

Correct

Mark 1.00 out of 1.00

Melting and vaporization are examples of exothermic process.

a. True

b. False

Your answer is correct.

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Question 6

Correct

Mark 1.00 out of 1.00

Which of the following is true for a chemical reaction at equilibrium?

a. Only the reverse reaction stops

b. Both the forward and reverse reactions stop

c. The rates of the forward and reverse reactions are equal

d. Only the forward reaction stops

Your answer is correct.

Question 7
Correct

Mark 1.00 out of 1.00

Which of the following is true regarding the concentration of products, for a chemical reaction that is already at equilibrium, assuming
no disruptions to the equilibrium?

a. The concentrations of products will not change because the forward and reverse rates are equal.

b. The concentrations of products will change continually because of reversibility

c. The concentrations of products will not change because there are no more reactants.

d. The concentrations of products will not change because the limiting reagent is gone.

Your answer is correct.

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Question 8

Correct

Mark 1.00 out of 1.00

Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from liquid at 10° C to vapor at 30° C.

a. 120kJ

b. 119kJ

c. 126Kj

d. 130kJ

Your answer is correct.

Question 9

Correct

Mark 1.00 out of 1.00

Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298 K.

a. 0.45KJ

b. 0.50Kj

c. +0.45 J

d. -0.45 kJ

Your answer is correct.

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Question 10

Correct

Mark 1.00 out of 1.00

___ is the state at which the concentration ratio of products to reactants is observed to be constant.

a. Equilibrium

b. Solid

c. Oxidation

d. Liquid

Your answer is correct.

Question 11

Correct

Mark 1.00 out of 1.00

A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of methanol is 64.7 o C and the molar enthalpy of
vaporization if 71.8 kJ/mol. The value of ΔS when 2.15 mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.

a. 0.457

b. 457

c. 5.21x107

d. 2.39x10 3

Your answer is correct.

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Question 12

Correct

Mark 1.00 out of 1.00

What happens to the internal energy of the system if work is done by the system?

a. Internal energy will decrease

b. Internal energy remains constant

c. Internal energy will increase

Your answer is correct.

Question 13
Correct

Mark 1.00 out of 1.00

The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of 1 cm³ of water by one degree Celsius.

a. Watt

b. Joule

c. Mole

d. Calorie

Your answer is correct.

Question 14
Correct

Mark 1.00 out of 1.00

An isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains
constant.

a. False

b. True

Your answer is correct.

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Question 15

Correct

Mark 1.00 out of 1.00

Freezing and condensation are examples of exothermic process.

a. True

b. False

Your answer is correct.

Question 16
Correct

Mark 1.00 out of 1.00

Total change in energy is equal to the sum of the heat and work transferred between the systems and surroundings.

a. First Law of Thermodynamics

b. Third Law of Thermodynamics

c. Second Law of Thermodynamics

Your answer is correct.

Question 17
Correct

Mark 1.00 out of 1.00

What kind of thermodynamic system is coffee held in a cup?

a. Closed system

b. Isolated system

c. Open system

Your answer is correct.

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Question 18

Correct

Mark 1.00 out of 1.00

If ΔG is positive, the reaction is spontaneous in the reverse direction.

a. False

b. True

Your answer is correct.

Question 19
Correct

Mark 1.00 out of 1.00

If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees Celsius, what is the specific heat of substance
B?

a. 0.167 J/g. C

b. 1.67 J/g. C

c. 1.76 J/g. C

d. 0.176 J/g. C

Your answer is correct.

Question 20
Correct

Mark 1.00 out of 1.00

Which phase of matter has the greatest motion and least orderly arrangement?

a. Gas

b. Solid

c. Liquid

Your answer is correct.

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Question 21

Correct

Mark 1.00 out of 1.00

A reversible reaction has ΔG negative for forward reaction. What will be the sign for the backward reaction?

a. No sign

b. Positive

c. Negative

Your answer is correct.

Question 22
Correct

Mark 1.00 out of 1.00

In thermodynamics, an ___process is a type of thermodynamic process in which the pressure P of a system remains constant.

a. Isothermal

b. Isometric

c. Isochoric

d. Isobaric

Your answer is correct.

Question 23
Correct

Mark 1.00 out of 1.00

Spontaneous processes are those that can proceed with any outside intervention.

a. False

b. True

Your answer is correct.

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Question 24

Correct

Mark 1.00 out of 1.00

___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy change for the reaction is the sum of all
changes.

a. Hess's Law

b. Gibbs Free Energy

c. Calorimetry

d. Second Law of Thermodynamics

Your answer is correct.

Question 25
Correct

Mark 1.00 out of 1.00

Non-spontaneous processes are those that do not take place by themselves or is a type of reaction which cannot occur without the
input of work from an external source.

a. False

b. True

Your answer is correct.

Question 26
Correct

Mark 1.00 out of 1.00

If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees Celsius, what is the specific heat of substance A?

a. 2.5 J/g. C

b. 250 J/g. C

c. 10 J/g. C

d. 0.250 J/g. C

Your answer is correct.

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Question 27

Correct

Mark 1.00 out of 1.00

____ constant tells how far the reaction has proceeded once the equilibrium is reached.

a. Dielectric

b. Equilibrium 

c. Universal gas

d. Cell

Your answer is correct.

Question 28

Correct

Mark 1.00 out of 1.00

In thermodynamics, an ___process, also called a constant-volume process.

a. Isothermal

b. Isobaric

c. Isometric

d. Isochoric 

Your answer is correct.

Question 29

Correct

Mark 1.00 out of 1.00

What happens to the internal energy of the system if work is done on the system?

a. Internal energy will increase 

b. Internal energy will decrease

c. Internal energy remains constant

Your answer is correct.

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Question 30

Correct

Mark 1.00 out of 1.00

Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from graphite and oxygen:

C(s) + O2(g) → CO2(g)

Standard Entropy in J/mol.K for: C= 5.740 O2 = 205.14 CO2=213.74

a. 2.86 J/mol.K 

b. 1.76 J/mol.K

c. 5.31 J/mol.K

d. 3.35 J/mol.K

Your answer is correct.

Question 31
Correct

Mark 1.00 out of 1.00

The standard free energy is found to be zero. What is its equilibrium constant?

a. 0

b. 1

c. 5

d. 10

Your answer is correct.

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Question 32

Correct

Mark 1.00 out of 1.00

Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a coffee cup calorimeter and the temperature
drops from 295 oC to 285 o C. Find the value of q for the calorimeter.

(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)

a. -5430 J

b. 5500 J

c. -5300 J

d. 5430 J

Your answer is correct.

Question 33
Correct

Mark 1.00 out of 1.00

The standard enthalpy of formation for a simple substance in its most stable state must be non-zero

a. True

b. False

Your answer is correct.

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Question 34

Correct

Mark 1.00 out of 1.00

A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work done on it. What is the heat change of
the system?

a. -130 J

b. -30 J

c. +30 J

d. +130 J

Your answer is correct.

Question 35
Correct

Mark 1.00 out of 1.00

The lower the concentration of the weak acid decreases the pH of the buffer solution.

a. True

b. False

Your answer is correct.

Question 36
Correct

Mark 1.00 out of 1.00

Predict the entropy change (ΔS) if the temperature of crystal is increased.

a. ΔS will increase

b. ΔS will decrease 

c. ΔS = 0

d. ΔS remains constant

Your answer is correct.

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Question 37

Correct

Mark 1.00 out of 1.00

Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.

a. ΔS = 0

b. ΔS < 0 

c. ΔS > 0

d. ΔS remains constant

Your answer is correct.

Question 38

Correct

Mark 1.00 out of 1.00

The higher the number of types of molecules, the higher is the degree of disorder.

a. True

b. False

Your answer is correct.

Question 39
Correct

Mark 1.00 out of 1.00

Reactions in which the products can react to form back the reactants are said to be ___.

a. Irreversible

b. Combination

c. Decomposition

d. Reversible

Your answer is correct.

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Question 40

Correct

Mark 1.00 out of 1.00

An equilibrium that strongly favors products has __________

a. K = Q.

b. a value of K >> 1. 

c. a value of Q << 1.

d. a value of K << 1.

Your answer is correct.

Question 41

Correct

Mark 1.00 out of 1.00

Which one of the following thermodynamic quantities is not a state function?

a. Internal energy

b. Gibbs free energy

c. Entropy

d. Work

Your answer is correct.

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Question 42

Incorrect

Mark 0.00 out of 1.00

Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum from 45 to 65 degrees Celsius. Molar heat
capacity of aluminum is 24 J/mole.K.

a. 1.065kJ

b. 1.25 kJ

c. 1.35kJ 

d. 1.44 KJ

Your answer is incorrect.

Question 43
Correct

Mark 1.00 out of 1.00

The ____ of a substance is the amount of energy required to raise the temperature of 1 gram of the substance by 1 degree Celsius.

a. Specific heat 

b. Mass

c. Temperature

d. Volume

Your answer is correct.

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Question 44

Correct

Mark 1.00 out of 1.00

The increased in internal energy of the system is 80 J and has 70 J of work done on it. What is the heat change of the system?

a. -10 J

b. +10 J

c. -0.10 J

d. +0.10 J

Your answer is correct.

Question 45

Correct

Mark 1.00 out of 1.00

A chemical equilibrium may be established by starting a reaction with __________

a. Reactants only

b. All the above

c. Products only

d. Any quantities of reactants and products.

Your answer is correct.

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Question 46

Correct

Mark 1.00 out of 1.00

The equilibrium constant for the reaction is 10. What will be the value of ΔG?

a. 4457 J

b. 7544 J

c. -5744 J

d. 4475 J

Your answer is correct.

Question 47

Correct

Mark 1.00 out of 1.00

In thermodynamics, an ___process is a type of thermodynamic process in which the temperature T of a system remains constant.

a. Isochoric

b. Isometric

c. Isobaric

d. Isothermal

Your answer is correct.

Question 48

Correct

Mark 1.00 out of 1.00

In exothermic reaction, heat is liberated into the surroundings.

a. False

b. True

Your answer is correct.

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Question 49

Correct

Mark 1.00 out of 1.00

If ΔG is 1, the system is at equilibrium.

a. False

b. True

Your answer is correct.

Question 50
Correct

Mark 1.00 out of 1.00

The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at a certain temperature.

H2(g) + I2(s) ⇌ 2 HI(g) K = 45

Which of the following is true regarding this equilibrium?

I. The reaction is product favored.

II. The reaction is reactant favored.

III. Equilibrium lies to the right.


IV. Equilibrium lies to the left.

a. II and III

b. I and IV

c. II and IV

d. I and III

Your answer is correct.

◄ FIRST QUARTER EXAM

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