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Question 1
Correct
Chemical equilibrium is described as a dynamic process because there is a movement in which the forward and reverse reactions
occur at the same rate to reach a point where the amounts or concentrations of the reactants and products are unchanging with time.
a. True
b. False
Question 2
Correct
a. False
b. True
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Question 3
Correct
If the reaction quotient Q has a smaller value than the related equilibrium constant, K, __________
a. The reaction is not at equilibrium, and will make more products at the expense of reactants.
d. The reaction is not at equilibrium, and will make more reactants at the expense of products.
Question 4
Correct
b. Calorimetry
c. Hess's Law
Question 5
Correct
a. True
b. False
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Question 6
Correct
Question 7
Correct
Which of the following is true regarding the concentration of products, for a chemical reaction that is already at equilibrium, assuming
no disruptions to the equilibrium?
a. The concentrations of products will not change because the forward and reverse rates are equal.
c. The concentrations of products will not change because there are no more reactants.
d. The concentrations of products will not change because the limiting reagent is gone.
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Question 8
Correct
Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from liquid at 10° C to vapor at 30° C.
a. 120kJ
b. 119kJ
c. 126Kj
d. 130kJ
Question 9
Correct
Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298 K.
a. 0.45KJ
b. 0.50Kj
c. +0.45 J
d. -0.45 kJ
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Question 10
Correct
___ is the state at which the concentration ratio of products to reactants is observed to be constant.
a. Equilibrium
b. Solid
c. Oxidation
d. Liquid
Question 11
Correct
A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of methanol is 64.7 o C and the molar enthalpy of
vaporization if 71.8 kJ/mol. The value of ΔS when 2.15 mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.
a. 0.457
b. 457
c. 5.21x107
d. 2.39x10 3
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Question 12
Correct
What happens to the internal energy of the system if work is done by the system?
Question 13
Correct
The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of 1 cm³ of water by one degree Celsius.
a. Watt
b. Joule
c. Mole
d. Calorie
Question 14
Correct
An isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains
constant.
a. False
b. True
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Question 15
Correct
a. True
b. False
Question 16
Correct
Total change in energy is equal to the sum of the heat and work transferred between the systems and surroundings.
Question 17
Correct
a. Closed system
b. Isolated system
c. Open system
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Question 18
Correct
a. False
b. True
Question 19
Correct
If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees Celsius, what is the specific heat of substance
B?
a. 0.167 J/g. C
b. 1.67 J/g. C
c. 1.76 J/g. C
d. 0.176 J/g. C
Question 20
Correct
Which phase of matter has the greatest motion and least orderly arrangement?
a. Gas
b. Solid
c. Liquid
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Question 21
Correct
A reversible reaction has ΔG negative for forward reaction. What will be the sign for the backward reaction?
a. No sign
b. Positive
c. Negative
Question 22
Correct
In thermodynamics, an ___process is a type of thermodynamic process in which the pressure P of a system remains constant.
a. Isothermal
b. Isometric
c. Isochoric
d. Isobaric
Question 23
Correct
Spontaneous processes are those that can proceed with any outside intervention.
a. False
b. True
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Question 24
Correct
___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy change for the reaction is the sum of all
changes.
a. Hess's Law
c. Calorimetry
Question 25
Correct
Non-spontaneous processes are those that do not take place by themselves or is a type of reaction which cannot occur without the
input of work from an external source.
a. False
b. True
Question 26
Correct
If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees Celsius, what is the specific heat of substance A?
a. 2.5 J/g. C
b. 250 J/g. C
c. 10 J/g. C
d. 0.250 J/g. C
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Question 27
Correct
____ constant tells how far the reaction has proceeded once the equilibrium is reached.
a. Dielectric
b. Equilibrium
c. Universal gas
d. Cell
Question 28
Correct
a. Isothermal
b. Isobaric
c. Isometric
d. Isochoric
Question 29
Correct
What happens to the internal energy of the system if work is done on the system?
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Question 30
Correct
Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from graphite and oxygen:
a. 2.86 J/mol.K
b. 1.76 J/mol.K
c. 5.31 J/mol.K
d. 3.35 J/mol.K
Question 31
Correct
The standard free energy is found to be zero. What is its equilibrium constant?
a. 0
b. 1
c. 5
d. 10
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Question 32
Correct
Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a coffee cup calorimeter and the temperature
drops from 295 oC to 285 o C. Find the value of q for the calorimeter.
(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)
a. -5430 J
b. 5500 J
c. -5300 J
d. 5430 J
Question 33
Correct
The standard enthalpy of formation for a simple substance in its most stable state must be non-zero
a. True
b. False
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Question 34
Correct
A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work done on it. What is the heat change of
the system?
a. -130 J
b. -30 J
c. +30 J
d. +130 J
Question 35
Correct
The lower the concentration of the weak acid decreases the pH of the buffer solution.
a. True
b. False
Question 36
Correct
a. ΔS will increase
b. ΔS will decrease
c. ΔS = 0
d. ΔS remains constant
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Question 37
Correct
Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.
a. ΔS = 0
b. ΔS < 0
c. ΔS > 0
d. ΔS remains constant
Question 38
Correct
The higher the number of types of molecules, the higher is the degree of disorder.
a. True
b. False
Question 39
Correct
Reactions in which the products can react to form back the reactants are said to be ___.
a. Irreversible
b. Combination
c. Decomposition
d. Reversible
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Question 40
Correct
a. K = Q.
b. a value of K >> 1.
c. a value of Q << 1.
d. a value of K << 1.
Question 41
Correct
a. Internal energy
c. Entropy
d. Work
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Question 42
Incorrect
Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum from 45 to 65 degrees Celsius. Molar heat
capacity of aluminum is 24 J/mole.K.
a. 1.065kJ
b. 1.25 kJ
c. 1.35kJ
d. 1.44 KJ
Question 43
Correct
The ____ of a substance is the amount of energy required to raise the temperature of 1 gram of the substance by 1 degree Celsius.
a. Specific heat
b. Mass
c. Temperature
d. Volume
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Question 44
Correct
The increased in internal energy of the system is 80 J and has 70 J of work done on it. What is the heat change of the system?
a. -10 J
b. +10 J
c. -0.10 J
d. +0.10 J
Question 45
Correct
a. Reactants only
c. Products only
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Question 46
Correct
The equilibrium constant for the reaction is 10. What will be the value of ΔG?
a. 4457 J
b. 7544 J
c. -5744 J
d. 4475 J
Question 47
Correct
In thermodynamics, an ___process is a type of thermodynamic process in which the temperature T of a system remains constant.
a. Isochoric
b. Isometric
c. Isobaric
d. Isothermal
Question 48
Correct
a. False
b. True
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Question 49
Correct
a. False
b. True
Question 50
Correct
The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at a certain temperature.
a. II and III
b. I and IV
c. II and IV
d. I and III
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