Professional Documents
Culture Documents
Clothing Comfort
1 2
Thermal Transmission
8
Introduction Sweat Rate
Perspiration from human body
transmits through the clothing
to the atmosphere in two forms,
Liquid (sensible)
Vapour (insensible)
Sweat Rate
Factors Affecting the Moisture
The volume of water lost in sweat daily is highly Transmission
variable, ranging from 100 to 8,000 mL/day.
Factors affecting the moisture transmission
Exercise simulation, walking, running or through textiles are
bicycling, to induce the SRmax was conducted in a Moisture content of the fabric
hot climatic chamber or in the desert. Type and structure of material used
Perspiration rate
The SR max due to marathon running were 1,000 Atmospheric conditions (humidity,
to 1,200 g/h in the cold season and 1,500 to 2,000 temperature and wind speed)
g/h in the hot season.
11 12
Principles of Transmission through
Clothing
In normal activity level, the metabolic heat
produced by the body is transferred to the
atmosphere by
Conduction, Convection and Radiation; and
Vapour form of perspiration
The wet and the dry heat loss, as well as the metabolic heat and the basal
13
metabolic rate (BMR) is measured in Watts. 14
Sense of comfort
Comfort and Discomfort Sensations
Moisture Accumulation
material absorbs sweat and moisture well
in microclimate and
}
Perspiration in Liquid &
Sense of coldness
Cotton
Human
Body
Atmosphere
Human Atmosphere
material absorbs moisture and sweat well
material disperses moisture poorly
}
Body Human Atmosphere
Produced Perspiration Body
Produced Perspiration Warmth is lost rapidly
passes through the
clothing results in does not pass through Moisture Accumulation
the clothing completely results in Sense of dampness
‘Comfort’ ‘Discomfort’
Polyester
material absorbs moisture and sweat poorly
sweat and moisture remains in the micro-space
}
A clear understanding of the role of moisture transmission
between skin and clothing
through clothing is required Humidity is high
15 16
Clothing results in a bad microclimate (Dampness) Clothing results in a bad microclimate (Coldness)
17 18
Moisture Transmission
19 20
Contact Angle & Young’s Equation
Liquid Water Transfer: Wicking and
Water Absorption
Liquid water transmission through clothing
primarily depends on fibre properties
Fibre–Water molecular attraction
Which is decided by the Surface tension
Capillary pore distribution – Structure of
Yarns and fabrics
γSL ↓ ~ θ ↓
Liquid Transfer Process through a Porous Media Liquid Transfer Process through a Porous Media
P LV cos
The magnitude of the capillary pressure through a channel is
given by the Laplace equation, Where, P is the capillary pressure developed in the channel when the liquid enters in it,
θ is the contact angle between the liquid drop and fibre surface, and
θ ↓ ~ cosθ ↑ ~ P ↑ LV
P LV cos
is the resultant surface tension between liquid-vapour interface
[γSV – γSL = γLV cosθ]
Where,
L is the distance travelled in horizontal capillary in time t,
and
η is the viscosity of the liquid.
2nd Phase: Capillary Wicking 29 30
31 32
Effect of viscose proportion on vertical wicking of fabric (At 1 min) Studies on Wicking of Liquid in Textile Material
With the increase in
viscose proportion,
wicking height along the
warp and weft directions of
the fabric reduces.
Studies on Wicking of Liquid in Textile Material Studies on Wicking of Liquid in Textile Material
Following variables were taken to design the experiment - Polyester Multifilament Normal Denier, Micro Denier
Trilobal Trilobal 5.24 36.92 16.84 358 174 0.8317 184.03 1.01
Shape Factor- 1, 1.156, 1.271
Triangula Triangul
5.24 36.92 16.84 365 181 0.8451 188.47 1.04
r ar
Circular Circular 5.24 36.92 17.11 360 178 0.8361 193.83 1.05
Microden
Irregular 0.93 36.92 18.62 370 186 0.8571 207.33 1.05
ier
37 38
Studies on Wicking of Liquid in Textile Material Studies on Wicking of Liquid in Textile Material
Effect of fibre shape factor
Vertical wicking test
Effect of fibre diameter
10
24 R2 = 0.827
Height reached by water (cm)
6 Trilobal 5
18 9
y = 2.8715x + 0.2793
4
4 R2 = 0.9492
12 Triangular
Microdenier 6
3 3 min
Normal-circular 2
6 1 min
Microdenier Circular 2
3 0
0 0.9 1 1.1 1.2 1.3 1.4
Normal-circular 0 5 10 15
0 1 2 3 4 5 6 Time (min) Poly. Shape factor
0
Time (min) (Trilobal)
0 2 4 6 8 10 12
Time (min) Poly.
(Triangula
In-plane wicking test Vertical wicking test r)
Poly.
39 40
(Circular)
Studies on Wicking of Liquid in Textile Material Studies on Wicking of Liquid in Textile Material
Effect of fibre shape factor
Conclusions
In-plane wicking test
30
23 With increase in fibre shape factor wickability
y = 10.459x + 6.199
of fabric increases
20 17
Trilobal
10 Triangular
3 min
y = 3.8175x + 3.7449
1 min With decrease in fibre diameter wickability of the
11 2
R = 0.9985
fabric increases, as the number of capillaries
Circular
0
0 2 4 6
5 increases along with reduction in capillary
0.9 1 1.1 1.2 1.3 1.4
Time (min) Poly.
(Trilobal) Shape factor radius (Rc)
Poly.
(Triangular
)
Poly.
41 (Circular) 42
Fabric structure
Some of the fabric samples (S3, S4, S5 and T5) are of plaited
constructions which are knitted by using two sets of yarns
with different deniers and shape factors.
43 44
Sample code. Fibre
Details of fabric samples
Fabric Fibre cross Shape Filament Yarn linear
Fabric structure
type structure sectional factor linear density
shape density denier
denier
T1 PET Interlock Elliptical 1.087 1.50 85.5
T2 PET Interlock Elliptical 1.096 1.50 82.2
T3 PET Interlock Elliptical 1.083 1.70 81.0
T4 PET Interlock Hexagonal , 1.053, 0.80, 165
Triangular 1.095 4.90 177
S1 PET Interlock Hexagonal 1.054 1.50 96.9
S2 PET Interlock Hexagonal 1.055 1.40 83.5
S3 PET Plain plaited Flat , 1.240, 1.34, 53.3,
Figure 1. Microscopic images and
structure of interlock fabrics Figure 3. Microscopic images and
Hexagonal 1.047 0.84 166 structure of float plaited fabrics
S4 PET Float plaited 2/1 Flat, 1.240, 1.34, 53.3,
Hexagonal 1.047 0.84 166
S5 PET Float plaited 1/1 Hexagonal, 1.072, 1.50, 61,
near circular 1.021 1.00 170
T5 PET Float plaited 2/2 Hexagonal, 1.065, 1.50 85.2, Figure 2. Microscopic images and
Elliptical 1.087 1.50 245 structure of plain plaited fabrics
T6 PET 2 layer Hexagonal 1.054 1.20 77
S6 PET 2 layer Hexagonal 1.055 0.92 82.8
45 46
Walewise Coursewise
found to be more than
T1 168 0.500 75.82 48 56 11.1 10.3 60 2.36
course wise wicking for
T2 167 0.490 75.47 46 53 11.5 10 52 2.47
all the interlock fabrics.
T3 156 0.520 78.41 46 54 9.9 9 54 3.26
Wicking height was
T4 206 0.600 75.29 35 33 10.35 8.8 59 2.47
Vertical wicking
For float plaited, course In-plane wicking
wise wicking was found to
be similar or higher than
wale wise wicking.
In-plane wicking took place in pattern of ellipse
In float plaited samples for interlock fabric – due to difference in course
(S4, S5 and T5) the and wale wicking
sample S4 with maximum
shape factor show
highest wicking height
which is due to high The samples with elliptical cross section fibres
specific surface area.
took less time to wick same distance as
compared to samples with hexagonal cross
Among two-layer fabrics, section due to higher surface area offered by
sample S6 with fine them.
Wale-wise and course-wise
filament denier have
vertical wicking characteristics of
higher wicking as plaited fabrics
compared to other. 51 52
Absorbency
Absorbency characteristics of
interlock fabrics
Absorption capacity of all fabric
samples is high and saturation
completes in a few seconds.
57 58
Studies on Wicking of Liquid in Textile Material Studies on Wicking of Liquid in Textile Material
Where,
Q is the rate of flow of liquid
∆P is the pressure head Where,
L0 is the length of sample in the direction of flow
k is the permeability of the porous medium
K is the proportionality constant (i.e. hydraulic conductivity of
the porous medium), depends on properties of the fluid
(viscosity) and on the pore structure of the medium η is the viscosity of the liquid
61 62
Studies on Wicking of Liquid in Textile Material Studies on Wicking of Liquid in Textile Material
63 64
Studies on Wicking of Liquid in Textile Material
Studies on Wicking of Liquid in Textile Material
Dynamic Surface Wetness and Type of Fibre
Dynamic Surface Wetness
In cotton (High Sweating Condition)
Presence of moisture between skin and clothing layer
In micro-denier Polyester,
Presence of higher number of capillaries Liquid water transfer takes place in 2 stages
results in higher moisture uptake 1st Stage: Wetting (Initial Process)
Dry and comfort feel to wearer.
2nd Stage: Wicking
Wettability
can be measured by Tensiometer is an instrument used to measure the
wettability of the fabric by measuring the wetting
Tensiometry
force by Wilhelmy method.
Goniometry In this method the wetting force (force applied by
the surface, when liquid comes in contact with the
surface) is measured.
The contact angles are calculated indirectly from
the wetting force when a solid is brought in
contact with the test liquid using Wilhelmy
69 principle. 70
73 74
chloride, the change in the colour due to
E sw Wm 2 0.42 M 58 absorption of moisture can be observed.
Where,
M is the metabolic rate and Esw the sweat evaporation
(W/m2) Thereby dynamic moisture change can
be measured subjectively
77 78
79 80
Measurement of Wicking Terms and Units
Liquids generally used for wicking test, The terms and units generally used for
Should represent close to human sweat
measuring wicking of fabrics are
Surface energy properties similar to human perspiration
Amount of Water Wicked (AWW) g g -1 : determine the
wicking capacity of the fabric away from the
Heated to human skin temperature of around 35°C
absorption zone
Sweat include sodium, sodium chloride, potassium,
Surface-Water Transport Rate (SWTR) gg-1s-1 :
potassium chloride etc.
calculates the amount of water wicked by 1 gm of
Most human sweat contains at an average of 1000 mg/l, fabric per second
and at least 700 mg/l of sodium
Wicking Time (WT) s : is the time in second for water
0.0025 g NaCl/ml or a 0.25% solution may simulate the to wick across a specified distance (3.25 cm)
sweat
The terms spontaneous transplanar or
Sodium chloride (NaCl) has an atomic mass of 58 g/mol
transverse wicking are used when the
with the Na atom occupying 40% of that mass
transmission of a liquid is through the thickness of
Therefore, 1 gram of sodium per liter equals 2.5 grams
the fabric, i.e. perpendicular to the plane of the
of NaCl per liter 81 82
fabric
Types of Wicking
Transplanar or transverse
Evaluation of Liquid Water Transfer wicking
In-plane wicking
83 84
Types of Wicking Test Method for Transverse Wicking
Uptake of Water Uptake of Water along Horizontal sintered glass plate kept moist by a water
through the thickness the thickness of the
of the Fabric Fabric supply
It should be adjusted to keep the water level at the
upper surface of the plate
Controlled Water Controlled Water Fabric can be kept over the sintered glass plate to
supply supply
Direction of water
Transverse Wicking In-plane Wicking
Wicking Uptake of water is measured by suitable method
Fabric By the movement of meniscus
85 86
Electronic
balance
Height
adjusting
knob
87 88
Test Method for In-plane Wicking Test Method for In-plane Wicking
Fabric is placed on the horizontal base plate which is Possibility arises that air bubble might be trapped in the
connected to the Siphon tube fabric or between the plates and fabric which can be
Fabric is covered with plate to ensure intimate contact escaped from the edges of the fabric
with the base plate
Moment the fabric is placed, it starts wicking of liquid Two extra capillaries
Wicking can be measured by One is between Bottom plate and fabric
Measuring by water uptake by the fabric sample Another is between Fabric and Top plate
89 90
91 92
Schematic Diagram of Vertical Present Techniques
Manual : Simple visual observation of travel of
Wicking
liquid front and manual recording
Scale
- Chances of manual error
Image processing : Becomes difficult in some
cases, e. g. in porous fabrics very accurate video
Fabric recording and shooting is required and thus
Clamp
becoming more complex. Also, imaging the actual
liquid travel is very difficult, particularly for thicker
fabrics
A method and instrument called the moisture
Reservoir management tester (MMT) is developed by Hong
Kong Polytechnic University to evaluate textile
93 moisture management properties 94
97 98
101 102
Vertical Wicking Tester
oTime Vs. water front flow point was plotted in real time
105 106
Liquid flow : In-plane wicking tester Liquid flow : In-plane wicking tester
107 108
In plane wicking measurement system
(Capacitance Principle)
Flow of liquid through porous material
Reason - Capillary action
109 110
Flow of liquid through porous material Flow of liquid through porous material
Reason - Capillary action Reason - Capillary action
111 112
Basic body of the instrument Basic body of the instrument
113 114
• Hence in general,
C = KAƐo/d ,
117 118
119 120
Moisture Transmission
Moisture Vapour Transmission
Liquid Water Transmission
through Textile Materials
121 122
Fabric layer
Vapour diffuses through the air spaces
between the fibrous materials Evaporating fluid layer
123 124
Diffusion
Mechanisms Vapour pressure gradient acts as the driving force
Occurs on a molecular level at lower speed
Moisture in vapour form transmits through textile
Moisture vapour is transported from the higher
materials by the following four mechanisms concentration zone to the lower concentration zone
1. Diffusion of the water vapour through the As per Fick’s Law, the relation between the flux of the
air spaces between the fibres diffusing substance and the concentration gradient
(dCA/dx)
2. Absorption, transmission and desorption
127 128
Diffusion: Non-fickian Diffusion Principles of Diffusion through textile
WVT = D.S. (p1-p2)/l medium
where,
(p1-p2) = Partial pressure gradient between the two Moisture vapour can diffuse through a
surfaces textile medium by two principles
l = Thickness of the material
Simple diffusion through the air spaces
D = Diffusion coefficient (i.e. The diffusion coefficient is
within the fibrous structure (Fickian
the amount of a particular substance that diffuses across
a unit area in 1 s under the influence of a gradient of one diffusion)
unit. It is usually expressed in the units m2/s. Diffusion along the fibre itself (Non-
S = Solubility coefficient (The volume of a gas that can be Fickian diffusion)
dissolved by a unit volume of solvent)
Hydrophilic materials transfer water vapor according to
Non-Fickian diffusion. 129 130
Diffusion Along the Fibre (Non-Fickian ) Diffusion Along the Textile Materials
Moisture vapour diffuses from one surface of the
At a specific concentration gradient,
fabric
diffusion rate depends upon
Porosity of the material
Surface of fibre
Water vapour diffusivity of the fibre
Water vapour diffusion has direct correlation In general, the diffusion co-efficient of fibres increases
with the air permeability of the fabric with the increase in the concentration of water in the
fibres
135 136
Sorption-Transmission-Desorption Sorption-Transmission-Desorption
It is an important phenomenon of moisture Reduce the moisture built up in the microclimate
vapour transmission which is responsible for This process enhances the transmission of
maintaining the microclimate during transient moisture vapour from the human skin to the
conditions environment.
Sorption-Transmission-Desorption Adsorption-Migration
During absorption–desorption process the Adsorption of water molecules takes place below
absorbing fabric works as a moisture a critical temperature
source to the atmosphere.
It also works as a buffer by maintaining a Van-der-Waals forces occurs between the
constant vapour concentration in the air moisture vapour molecules and the solid surface
of textile fibres
immediately surrounding it, i.e. a constant
humidity is maintained in the adjoining air,
though temperature changes due to the The higher the vapour pressure and the lower the
temperature, the higher is the amount adsorbed
heat of sorption.
139 140
Factors Affecting Adsorption Factors Affecting Adsorption
With the increase in fibre swelling the capillary
The amount of moisture adsorption depends on channels between the fibres get reduced which
Moisture regain
results lower vapour transmission
The distortion caused by the fibre swelling
Environmental humidity
results in built up of internal stresses which
Sorption hysteresis
affects the moisture adsorption process.
Temperature
The adsorption hysteresis increases with the
Dimensional changes
increase in the hydrophilicity of fibre
141 142
Forced Convection
82.58 3
61 y=62.97-
x
R2=0.8666 2.9 y=3.57-0.098x0.5
In a windy atmosphere the convection 60 R2=0.8781
2.8
method plays a very significant role in 2.7
59
transmitting moisture from the skin to the 2.6
20 40 60 80 100 0 25 50 75 100
atmosphere through clothing Viscose% Viscose%
With
145 146
147 148
So as the fabric sett and structure of all the
fabrics are almost same, diffusion through air A hygroscopic fabric absorbs water vapour from
should not differs for the fabrics. the humid air close to the sweating skin and
releases it in dry air.
As the viscose proportion in the fabric
increases, moisture regain of the material This enhances the flow of water vapour from the
increases causing higher diffusivity. skin to the environment as compared to a fabric
which does not absorb and reduces the moisture
In the same way moisture transfer through built up in the microclimate.
sorption-desorption process increases with the
hygroscopicity of the material. Whereas fabric with less hygroscopicity will
provide higher resistance to the water vapour
transfer.
149 150
24.6 48
y = -2.8962x + 27.122
The results indicate that the fabric with circular filament
Rel. water vapour
Air permeability
y = -13.787x + 59.643
(cm3/cm2/min)
46
permeability%
R2 = 0.9769 2
24
has the highest water vapour permeability and it reduces with
R = 0.9998
44
23.4 the increase in fibre shape factor.
42
22.8
0.9 1 1.1 1.2 1.3 1.4
40
0.9 1.1 1.3
A good correlation has also been found between air
Shape factor Shape factor permeability and relative water vapour% of the fabrics.
30
25 25.5
As fibre shape factor increases the specific surface area of
Rel. water vapour
permeability%
20 24
y = 0.132x + 17.92
R² = 0.962
15 22.5
air and the water vapour flow through the fibre surface
10 21
25 30 35 40 45 50
decreases with the increase in fibre shape factor, which
results in low air and water vapour permeability for these
5
Air permeability
0
Trilobal Triangular Circular Microdenier fabrics.
151 152
Air permeability and water vapour permeability decreases
with the decrease in fibre diameter.
This result can also be explained by higher specific area of Moisture Evaporation
the fibres. Finer the specific area of the fibre is higher, lower (Evaporative Heat Transfer)
is the air and water vapour permeability of the fabric. and
Condensation
153 154
Moisture Evaporative and Condensation Moisture transmission & Evaporative Heat Transfer
Evaporation and condensation also have significant During the evaporation of liquid body perspiration
effects on moisture vapour transmission through Latent heat is taken away from the body, thus
porous textile materials body cools down
These depend on Also, increase in the surrounding atmospheric
Temperature temperature (close to skin temperature)
Moisture distribution in porous textile materials In this case, due to the low temperature difference
The importance of evaporative heat transfer in between the human body and the environment the
maintaining thermal balance becomes more crucial heat transmission through radiation, conduction and
with the increase in the surrounding atmospheric convection reduces
temperature
155 156
Moisture transmission & Evaporative Heat Transfer Condensation of Moisture Vapour
When a negative temperature gradient (i.e. in a very hot Condensation of moisture vapour is a direct result of a
climate) exists between the skin and the environment, fabric being saturated by liquid perspiration and it generally
evaporative heat transfer becomes the only way to cool occurs within the fabric whenever the local vapour
down the body temperature pressure increases to saturation vapour pressure at
certain temperature
Latent heat of evaporation of water is vary large (about 2300
kJ/kg) It generally occurs when,
So, small amount of evaporation results in significant amount of • the atmospheric temperature is very low
heat flow and cools down the body • the relatively warmer and moist air from the skin comes
The presence of wind enhances the evaporative heat transfer into contact with relatively cooler fabric surface, the
due to enhanced evaporation rate and results in additional fabric surface works as a cold wall and condensation
cooling that is desirable in periods of peak performance occurs
161 162
24 G
WVT ; g / m2 / 24hr
Where, AT
WVT = water vapor transmission rate (g/m2/day)
G = change in mass (g)
T = testing time (hr)
A = test area (m2).
Standard: ASTM E 96-80 procedure B 167 Standard: ASTM E 96-80 procedure B 168
Evaluation: Inverted Cup Test Method
Evaluation: Inverted Cup Test Method
a = test area
T 269 10 7 % RH
1440
Time Interval
Standard: ISO 15496 2004 173 174
Evaluation: Dynamic Moisture Permeable Cell Microclimate simulator cum moisture vapour
transmission tester:
Capable of evaluating the moisture
transmission properties of textiles under
various conditions,
Pure diffusion
Pure convection
177 178
Microclimate simulator cum moisture vapour Microclimate simulator cum moisture vapour
transmission tester: transmission tester:
179 180
Evaluation: Holographic Bench Technique Evaluation: SGHP
In this method the mass flow is measured with
high accuracy using a micro-weighing
technique
The resistance to the water vapour transfer
depends on the (i) resistance of the air layer
and (ii) the outer clothing
Holographic bench technique separately
measures the water vapour flow resistance
offered by different air layers; thus it provides
the precise vapour resistance value of the
textile layer.
181 182
measuring head, with and without the fabric mounted on the Plastic ring
plate, is measured.
Relative water vapour permeabili ty (%)
Heat lost when the fabric is placed on the measuring head
100
Heat lost from the bare measuring head
Measuring head of Permetest
Temperature of measuring head is maintained in Water vapour resistance Ret (m2 Pa/W) is given by
isothermal conditions at 35 °C
1 1 1 1
When water evaporates from the measuring head, Ret ( p wsat p wo ) C 100
Su o Su s us u o
the heat loss from it is measured indirectly by the
Where,
heat sensor pwsat is partial water vapour pressure in saturated air in Pascal;
Difference threshold
191 192
Moisture Sensation & Clothing Comfort
193