CHEMISTRY

31. The number of 𝜎 and 𝜋 bonds in a molecule of benzene is

(a) 6𝜎 and 9𝜋 (b) 9𝜎 and 3𝜋 (c) 12𝜎 and 3𝜋 (d) 6𝜎 and 6𝜋
32. The ratio of 𝜎 and 𝜋 bonds in benzene is
(a) 2 (b) 4 (c) 6 (d) 8
33. The most stable carbonium ion among the following is
+ + + +
(a) C 6 H 5 C HC 6 H 5 (b) C 6 H 5 C H 2 (c) CH 3 C H 2 (d) 𝐶6 𝐻5 𝐶𝐻2 𝐶 𝐻2
34. Attacking or reactive or electrophilic species in nitration of benzene is or In the
nitration of benzene with concentrated 𝐻𝑁𝑂3 and 𝐻2 𝑆𝑂4 the attack on ring is made
by
(a) 𝑁𝑂2− (b) 𝑁𝑂2+ (c) 𝑁𝑂3− (d) 𝑁𝑂2
35. Which of the following reactions takes place when a mixture of concentrated 𝐻𝑁𝑂3
and 𝐻2 𝑆𝑂4 reacts on benzene at 350𝐾
(a) Sulphonation (b) Nitration (c) Hydrogenation (d) Dehydration
anhydrous
36. 𝐶6 𝐻6 + 𝐶𝐻3 𝐶𝑙 → 𝐶6 𝐻5 𝐶𝐻3 + 𝐻𝐶𝑙 is an example of
𝐴𝑙𝐶𝑙3
(a) Friedel-Craft's reaction (b) Kolbe's synthesis
(c) Wurtz reaction (d) Grignard reaction
37. On heating a mixture of sodium benzoate and sodalime, the following is obtained
(a) Toluene (b) Phenol (c) Benzene (d) Benzoic acid
38. Benzene on treatment with a mixture of conc. 𝐻𝑁𝑂3 and conc. 𝐻2 𝑆𝑂4 at 100𝑜 𝐶 gives
(a) Nitrobenzene (b) m-dinitrobenzene
(c) p-dinitrobenzene (d) o-dinitrobenzene
39. Aromatisation of n-heptane by passing over (𝐴𝑙2 𝑂3 + 𝐶𝑟2 𝑂3 ) catalyst at 773 K gives
(a) Benzene (b) Toluene (c) Mixture of both (d) Heptylene
40. Which among the following is anti-aromatic ?

(a) (b) (c) (d)

41. Identify the aromatic compound ?

(a) (b) (c) (d)

42. Aromatic compounds burn with sooty flame because :

(a) They have a ring structure of carbon atoms.
(b) They have a relatively high percentage of hydrogen.
(c) They resist reaction with oxygen of air.
(d) They have a relatively high percentage of carbon.
43. Which of the following compound is an Aromatic in nature.
O
..
– O
..
(a) (b) (c) (d)

44. Which of the following ion is nonaromatic in nature.

(a) + (b) – (c) + (d)

–

45. Which of the following compound is not aromatic in nature.

(a) (b) (c) (d)

46. Which of the following molecules are aromatic hydrocarbon?

–
(a) (b) (c) (d) All of these

47. The hybridisation of nitrogen in (pyrrole) is :

(a) sp3 (b) sp2 (c) sp (d) dsp2

48. In the compound C6H5Z which of the following set of groups is predominatly
ortho/para directing ?
(a) Z = – NO2, — Cl, — OH (b) Z = – OMe, — CN, — NH2
(c) Z = – NHCOCH3, — Cl, — COOH (d) Z = – NHCOCH3, — CH3, — OH
49. Which of the following is aromatic hydrocarbon ?

(a) (b) (c) (d)

50. Which one contains 10𝜋 electrons?

(a) (b) (c) (d)

51. Number of 𝜋 electrons in conjugation for these compounds

, , and will be respectively :
 (a) 8, 6, 6, 6 (b) 6, 4, 6, 6 (c) 6, 6, 6, 6 (d) 6, 6, 8, 6

52. Among the following the anti aromatic speceis is :

(a) (b) (c) (d)

53. Which one of the following is non Aromatic?

O ..
– O
..
(a) (b) (c) (d)

54. which of the tropylium cation ?

+ – + –
(a) (b) (c) (d)
55. Which of the following molecules have all C–C bonds are of equal length?
–

(a) (b) (c) (d) All of these

56. In the compound C6H5Z which of the following set of groups is predominatly
meta directing ?
(a) Z = – NO2, (b) Z = – OMe, — NH2
(c) Z = – NHCOCH3, — Cl, (d) — CH3, — OH

57. Which of the following compounds reacts slower than benzene in electrophilic
bromination ?
(a) C6H5CH3 (b) C6H5OH (c) C6H5NO2 (d) C6H5NH2

58. -NH2 group in aniline is :

(a) m-directing and deactivating (b) o, p-directing and deactivating
(c) o, p-directing and activating (d) m-directing and activating
59. o,p-directing group are mostly :
(a) activating group (b) deactivating groups
(c) neutral groups (d) none of these
60. Benzene reacts with acetyl chloride in presence of anhydrous aluminium chloride to
form:
(a) acetophenone (b) phenyl acetate (c) chlorobenzene (d) benzoic acid