REVISION SERIES ISOMERISM

of form I
keto to end in Basic medium
Immersion um :

· =
& O

O GUz-
If-
-
1

Got
2

TacidicH Il
I
t a
o
regenerated why
that
truely
is can it
say
we

let
acts as a cata

~H
i HS
gin
&=
CHz-c-Ch2-
Chz-c-Cz =+
I
CHz-c=cz

↓ OH
Cs-k =2
In -
acidic medium

H-chz-
↓to
-

it ht
H-CH2-c-H i

* =
Taulomeriemingene(c-atom)
shownby and
-

a
end
to
sp3 hybrid atom
 :
of
Tantomesic
Position
Equilibrium
8 OH
I
CH- -

H = CHz = c -
H

Keto end

general ketofum
In
key 1 is more

stable than end

for

eno
-[aso-55ks/mal
Keto

RC
Reaction co-ordinate
 In
group bifurcates proceed
*
care a
,
one must

along highest precedence

the branch the
providing
untill a
difference is encounted

The decision must be made at the earliest

opportunity & be
changed
once made can not
,

consideration
ofsubstitutes farther along
the
the
from
chair .

H > - -C
-
As
-

-
↑

CHz CH3
I
- = -

I
-

CH2- C- CH ~

2
H > -
C2--C2-OH .

In
-
- -

Ch
-
- -
-
&: out the chiral
following
Find centre in the molecule?
-
Us

① In
~ As
-
- # om *

I II I
-

41z

③
oh
O OH
Il I
-
*
*
*
# GOH 1
-
-

on on
I
am
⑪ * *

I I

⑤ T
③
[↳
*

*
-
: #

bu

T
⑥ ④
[3T
#

⑰ F
7 *
*

7
*

O
[7 *-
&
different types of Proj e cti o ns : [
If you details
in
want to revise
then watch
R

①
I lecture from adyis
Flying wedge I -R2
Projection
·

3
a
② Fischer
Projection E
6 =J
f +
In
Fischer Projection ·
the carbon chain is taken at the vertical line
.
longest
highest
at the
and the oxidized carbon is
kept top
.

The horizontal line

represents theatoms so
comin

towards the viewer and

going away from

the atom the viewer
represents
.

③ Newmann
H
Projection :
CH3-Uz H

#
im
⑨

H
H
I
staggered form