Statistics 13th Edition McClave

Solutions Manual
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 The processes in so far as lead enters can best be divided into—
(1) Glaze; (2) decorative.
1. Glaze Processes.—The charge of glaze is made by weighing
out and mixing carbonate of lead with the necessary silicates and
silico-borates in the lead house or mixing-room, where wet grinding
prepares the mixture for the dipping-tub. “Putters-up” hand the ware
to the dipper, from whom “takers-off” place it on boards for removal
to the drying still, or place it (in large works) directly on to the shelf of
an appliance known as a “mangle,” in which an endless chain carries
the ware through a heated chamber. Subsequently superfluous glaze
has to be removed from the base, rims, and not infrequently also
other parts of the articles. This ware cleaning is performed with a wet
sponge or flannel, either while the ware is still moist or by scraping,
the particles removed dropping into a vessel of water; or, if the glaze
is dry, over a grating provided with exhaust draught. The ware is next
removed by the glost-placer on boards, and each piece is separately
placed by him in the sagger (fireclay receptacle) and carried into an
oven to be fired.
2. Decorative Processes.—Majolica painting is the application of a
coloured glaze rich in lead by means of a brush. Ground-laying
consists in dusting powdered enamel colour on to a pattern first
printed on glazed ware with an oily medium. Colour dusting differs
from the same only in detail.
Aerographing (colour blowing) is the blowing on to the ware, by
means of a jet of compressed air, coloured glaze, or enamel colour
held in suspension in oil or other liquid in a glaze kettle or aerograph
instrument.
Dangers.—Apart from risk inseparable from, and increased by,
defective lighting, uneven floors of wood or brick, collection of dust
on benches and floors, and the risk entailed in the sweeping of these
even when watering is practised, and lack of care and attention to
detail on the part of the worker, the following special dangers are
incidental to the various processes: In dipping the glaze (except in
tiles, where the surface only is allowed to touch the liquid), splashes
on to the face and overalls of the dipper, “hander-up,” and “taker-off”
(dipper’s assistants), and “threader-up” (in the case of china
furniture), especially when, as with plates, there is much shaking of
the ware. These splashes dry, and the overalls may become so
coated with glaze that every movement, such as carrying boards or
leaning against the mangle, crumbles it off as dust into the air. As the
dipper shakes the ware, some of the drops are disseminated into the
atmosphere as a fine spray. In ware cleaning the work may have to
be done so rapidly that it is difficult always to observe proper care,
and the worker is tempted to withdraw the article from the range of
the exhaust. Sometimes a ware cleaner is seen blowing away with
her mouth dust lying on the ware.
Dipping-boards, unless freed from adherent glaze by washing after
use, create dust whenever ware is placed on, or removed from,
them, when they are handled and placed on or taken off the stillage
bars, and when they are stacked. Persons gathering at the mangle
are exposed to dust if there is any outward current of air from it. The
glost-placer raises a slight amount of dust as he takes the ware from
the board and places it in the sagger. The dangerous practice
formerly almost universal of rubbing the bottoms and rims of cups,
etc., either together (without use of an exhaust) or rubbing them on a
piece of leather fixed round the chest, is generally replaced by
removal of the glaze on a moist piece of flannel, but it is still possible
to find men doing it in outlying potteries. In majolica dipping and
painting (apart from the obvious risk of splashing and contamination
of the hands), danger arises mostly from scraping the edges and
under surfaces of the tiles on to which glaze, when applying the
background, has overflowed. The amount of glaze so removed is
considerable, and if it is not all caught in the trough of water, the floor
becomes an added source of danger.
In all the decorative processes—ground-laying, aerographing,
colour-dusting, and grinding of colours for aerographing, etc., the
danger is one solely arising from dust.
Prevention.—Meticulous attention to detail, not only in the
provision, but also in the maintenance, of the locally-applied exhaust
ventilation, alone can allay the danger in the processes to which dust
is incidental, such as ware cleaning, gathering at the mangle, glost-
placing, and the decorative processes. The Lead Committee
considered that, as there was no rapid method of testing the actual
degree of moisture, exhaust ventilation might be required in the case
of ware that was not cleaned within fifteen minutes of the application
of the glaze. Such a requirement would prevent the practice now
prevalent of painting as many as three dozen tiles, piling them one
on top of another, and then proceeding to the operation of scraping.
No danger attaches to removal of glaze with a damp sponge or
flannel, but means must always be at hand for washing and damping
them. In the dipping-house, (a) impervious floors should be provided,
which could be washed down so as to prevent the risks from
sweeping, and from glaze drying, and being raised as dust; (b)
partial covering of the dipping-tub to prevent splashing and spray;
and (c) substitution for the overalls at present worn by persons in the
dipping-house, glost-placers, millers and mixers of glaze, majolica
paintresses, and others, of overalls of some light waterproof material
which could be sponged, or of aprons of waterproof material worn in
front of the overalls. Dipping-tubs and walls and floors in close
proximity to them can with advantage be painted red. Dipping-boards
should be washed with clean water after every time of use.
Automatic machines for washing and scrubbing boards are in use in
some factories.
To reduce risk or remove the danger of lead poisoning in this
industry, use of low solubility glazes or of leadless glazes are
advocated. On this point the Lead Committee say: “The effect of
melting the lead with silicious matter amounts to imprisoning it in
such a manner as to render it less liable to the action of the acids
which it meets in passing through the human body, and in
consequence largely reduces the likelihood of its absorption into the
blood. If the frit is properly compounded, all but a small fraction of
the lead is rendered insoluble, and glazes so made are spoken of as
‘low solubility glazes.’ The finished glaze generally contains from 12
to 22 per cent., or more, of lead oxide, but after the process of fritting
with sufficient silicious material only from 2 to 5 per cent. remains
soluble.”[A]
[A] Raw lead comprises red lead, white lead, and litharge. If introduced in
this form as a constituent of glaze it is soluble in dilute acids. If, however,
the raw lead is fluxed by heating with a part or the whole of the silica, it is
converted into “fritted lead.” The solubility of the frit depends upon the
relative proportions of material taken. Thorpe[23], as a result of numerous
 analyses of lead silicates (after determining their solubility as regards lead),
both simple and complex, in use in the potteries and on the Continent,
found that the quantity of lead dissolved had no necessary relation to the
quantity of lead in the silicate. “Primarily and in the main the insolubility of
the lead depends not upon any one oxide or group of oxides, but upon the
maintenance of a certain proportion between the whole of the basic oxides
on the one hand and the whole of the acidic oxides on the other. If the value
of ratio bases/acids is higher than, or approximately equal to, two, the
amount of the lead extracted is small, but if it fall much below two, the
quantity of lead dissolved begins rapidly to increase.”

On the subject of the use of leadless glazes, the Committee

conclude that in all classes of pottery ware a great many articles can
be manufactured in a very high state of perfection, with reduction in
the cost of production of certain classes of common ware, such as
jampots and Persian painted ware; but that in certain other classes,
owing to the excessive number of “seconds,” their use would entail
increased cost or sacrifice of quality, so much so as to involve loss of
important markets; and, finally, that certain kinds of ware, in
consequence of difficulties relative to accuracy in reproducing old
patterns, colours, or methods of decoration, cannot at present be
made at all without use of lead.
In the case of manufacturers who are able to conform to the
Thorpe test of low solubility—i.e., glaze which yields to a dilute
solution of hydrochloric acid not more than 5 per cent. of its dry
weight of a soluble lead compound, calculated as lead monoxide
(PbO)—important relaxation of certain special rules are allowed,
such as limitation placed on the employment of females and young
persons, and periodical medical examination of the workers.
H. R. Rogers[24], one of H.M. Inspectors of Factories, Stoke-on-
Trent, has worked out a simple test to show approximately how
much lead has been used in the glaze of a piece of pottery. Thus, by
treating glazes with hydrofluoric acid for forty seconds, absorbing the
liquid with filter paper, precipitating the lead on the paper as the
sulphate, dissolving out the sulphate soluble in water, and then
precipitating the lead on the paper as sulphide, stains are produced
varying, in depth of colour, according to the proportion of lead in the
glazes concerned (see Plate IV.).
 Briefly summarized, the recommendations of the Potteries
Committee in regard to the processes are—
Manufacture of Glazes.—No handling of white or red lead without
at least 5 per cent. of added moisture, and no weighing out, etc., nor
employment in the room, to be allowed within thirty minutes of such
weighing out, etc., without the wearing of a respirator.
Lawning—i.e., straining glaze so as to remove insufficiently
ground material through a fine lawn sieve—to be done by an adult
male only, except where less than a quart of glaze is lawned.
Dipping.—Impervious floors sloped towards a drain to be cleaned
by an adult male, after work has ceased, with a jet of water and a
mop. Walls adjacent to dipping-tubs to be tiled or painted with
washable paint, and cleaned daily. Dipping not to be done where
artificial light is necessary during hours of daylight.
Threading-up and Thimble-picking to be done in a room
sufficiently separated from any place where scheduled processes
are carried on.
Drying Ware after Dipping.—The same requirement as to floors as
in dipping-house.
Boards.—To be cleaned with clean water by an adult male after
each time that dipped ware has been placed on them and before
subsequent use. Boards for use in lead processes to be painted red
at the ends.
Mangles.—Ventilation to be so arranged as to maintain a flow of
air into the hot chamber from the workroom. Mangle shelves to be
thoroughly wet cleansed once a week.
Ware Cleaning.—Local exhaust ventilation to be applied except
when the process is carried on entirely with use of wet materials
(damp sponges, etc.), or when done within fifteen minutes of
application of glaze. Troughs to be provided to collect glaze, and to
be cleaned out and supplied with fresh water at least once a week.
The floors and standard of lighting to be the same as for the dipping-
house.
Glost-placing.—Boards to be treated as already described. Floors
to be impervious. Women, young persons, and children to be
excluded, except that women to be allowed to place china furniture
and electrical fittings.
 Majolica Painting and Mottling.—A sponge and clean water to be
placed beside each paintress; special washing accommodation in
the painting-room or adjoining it; splashes to be removed
immediately by wet sponging. Work-benches and floors to be subject
to the same conditions as potters’ shops.
Flow Material—i.e., the substance usually containing much lead in
the form of powder and placed in the sagger to cause certain colours
applied to biscuit ware to run slightly—to be weighed out in front of
an exhaust draught and delivered to the glost-placer by an adult
male.

PLATE IV

Fig. 1.—No Lead used. Fig. 2.—Fritted Lead used.

0·9 per cent. solubility.
Fig. 3.—Fritted Lead used. Fig. 4.—Fritted Lead used.
1·5 per cent. solubility. 5·0 per cent. solubility.
13·9 per cent. total lead. 5·0 per cent. total lead.

Fig. 5.—Raw Lead used. Fig. 6.—Raw Lead used.

19·4 per cent. solubility. 44·1 per cent. solubility.

19·4 per cent. total lead. 45·2 per cent. total lead.
 Fig. 7.—Rockingham (Raw Lead)
used.
50·9 per cent. solubility.
50·9 per cent. total lead.

Ground-laying, colour-dusting, and aerographing to be done under

locally applied exhaust ventilation. Proper receptacles to be provided
for cotton-wool used and waste cotton-wool to be burnt. No short-
sighted person to be employed to do either glaze or colour blowing,
unless wearing suitable glasses, and certificate to this effect to be
entered in the Health Register.
Litho-Transfer Making.[25]—Transfers for the decoration of
earthenware and china are made in special factories, of which there
are seven, employing 257 persons. The patterns are impressed in
the ordinary chromo-lithographic fashion, but as the enamel colours,
containing high percentages of lead, are dusted either mechanically
in the machine, or by hand by means of a pad of cotton-wool, danger
from dust is great in the absence of maintenance of a negative
pressure inside the dusting machine and an efficient exhaust draught
behind the bench where the final dusting with flour, to remove the
superfluous colour, is done. In one factory, before a fresh colour was
applied to the adhesive pattern on the sheets, the machines had to
be cleaned as far as possible of the previous colour used. To do this
it was necessary for the attendant to enter a closed chamber at the
back of each machine, so as to supply the powder to the hoppers
which feed the rollers, or to clean them by means of a brush,
sometimes as often as every half-hour. The upward exhaust
ventilation applied to the interior of the machine tended to draw the
dust created in brushing past the worker’s face, and led to severe
incidence of poisoning. The remedy suggested by Pendock[26] was
to dispense altogether with the need for entering the chamber, to
maintain a slight negative pressure inside the machine by downward
exhaust, and to remove the dust by means of a small vacuum
cleaning plant.
At the same factory the flouring bench was in the same room as
the machines, and the locally applied exhaust drew its air-supply
from the general atmosphere of the room. Apart from faulty
arrangement of the exhaust ducts leading to effects of too local a
character, dust was drawn from other parts of the room, including the
machines, so much so as to necessitate frequent cleaning of the
glass hoods. Poisoning among those employed in flouring occurred.
To remedy this, an air-grid with curved inlets at intervals of 2 inches
apart, leading into a trunk in connection with a fan, was placed along
the back of the bench and under the top of the glass hood. In order,
however, that its action should not interfere unduly with the general
ventilation of the room, but be, in large measure, independent of this,
a somewhat similar grid, introducing air from the street outside, was
fitted along the front of the bench. The whole arrangement was
operated by one suction fan. Ten cases occurred in this factory in the
year before this arrangement was carried out. In the three years
since, three cases only have been reported. In the ten years 1900-
1909, 48 cases were reported among 257 persons employed.
Vitreous Enamelling.[27]—Surfaces, such as sheet iron for
advertisement signs, cast iron for baths and gas stoves, copper for
copper letters and tablets, brass for jewellery, and glass for lettering
and decoration, are treated with glaze or enamel colours, which,
either in the mode of application or subsequent treatment before final
vitrefaction, give rise to dust.
 In the manufacture of advertisement signs, glaze is swilled on to
the sheet of iron. After drying, it is fired or vitrified, and upon this
surface as many other coats of glaze are applied as may be wanted.
As soon as the colour is dry, lettering is effected by brushing away
the dried (but not fired) glaze exposed through stencils.
Dangers and Prevention.—Exhaust ventilation for the removal of
the dust is essential, but it is, unfortunately, unable to draw the dust
away when brushing is done at a distance of more than about 18
inches from the exhaust opening. And some of the plates required
are very large. No exhaust-pipe has yet been invented which will
follow the hand of the worker without impeding movement. In
consequence of severe incidence of poisoning, mainly on young
women who do the work of brushing, when the process was first
introduced with enamel glazes containing from 15 to 75 per cent. of
lead, manufacturers quickly turned their attention to use of enamels
free from lead. For this class of work they appear to have been
entirely successful, and now lead poisoning is almost a thing of the
past. Thus, of 122 samples examined in 1910 from factories claiming
exemption from the regulations by reason of the use of enamels
containing less than 1 per cent. of lead, excess was found in three
only[28].
Porcelain Enamelling.—The cast-iron bath or stove is heated
to redness in a muffle furnace. On withdrawal from the furnace it is
placed by the helpers on a table capable of being turned in every
direction. Enamel powder is then dusted on to the heated metallic
surface through a sieve attached to a long wooden handle, held by
the duster, who protects himself from the intense heat by a mask and
an asbestos cloth covering.
Fig. 12.—The first glaze is sprayed on with an aerograph. The portion of the stove
to be glazed is shown on supports on the sliding table, which is half out of the
cabinet. When the casting is fully in the cabinet, the end piece and the centre
piece close the cabinet sides, and, fitting on a felt beading, make an air-tight
joint. The spray, shown in front of the cabinet, is worked through the holes in the
glass front. Exhaust is provided at the top.

Dangers and Prevention.—The heated column of air carries up

much of the powdered glaze as it is unevenly distributed by jolting
the handle of the receptacle, and in the absence of very efficient
exhaust ventilation this dust will, as the current of air strikes the roof
and cools, fall down again. The hood placed over the bath must have
steep sides and be brought down as low as is possible without
interfering with work, and the duct leading to the fan must be
unusually wide, so as to be able to cope with the up-rush of heated
air. If the sides of the hood be shallow, not only will the dust fail to be
removed, but the hood itself may become so hot as noticeably to
increase the discomfort from heat to which the men are exposed
during the three or four minutes, five or six times an hour, that the
dusting operation lasts. A method has been patented by M. Dormoy
of Sougland[29], Aisne, France, for carrying out automatically in a
closed chamber the process of dusting on to small red-hot castings,
such as are required in the manufacture of stoves. It is not applicable
for baths.
Occasionally, in the case of small castings, again, the enamel is
sprayed on by means of an aerograph. For this excessively
dangerous process we have seen simple and ingenious devices for
carrying it on quite safely in a space under negative pressure, and
covered in except for the necessary openings through which to work
the spray (see Figs. 12, 13, 14).[A]
[A] The cabinets have been patented by Messrs. Wilsons and Mathiesons,
Ltd., Leeds, by whom they are made and supplied. Since using them there
has been no trace of illness among the persons employed.
Fig. 13.—After firing the casting is lifted out for treatment with dry glaze, which is
sprinkled on with a sifter shown on the table. The turntable enables the operator
to manipulate the red-hot casting more easily.

White enamel powders free from lead are used entirely by some
firms, but the black and coloured enamels on stove grates contain
lead. A frit analyzed in the Government Laboratory was found to
contain 26·66 per cent. of lead oxide. The fact that all the lead used
is in the form of a silicate, even although the silicate is readily soluble
in dilute acid, tends, we believe, to cause incidence of poisoning to
be less than might have been expected from the amount of dust
often present in the air, and attacks, when they occur, to be less
severe, as a rule, than they would be were raw carbonate of lead
alone used. For the arduous work entailed the men are specially
selected. Despite their exposure to lead dust, the majority continue
to work for many years without marked signs of lead absorption. The
management should provide a suitable room for the men to cool
themselves in the intervals of dusting.
Fig. 14.—The cabinet is shown when dry dusting is being done. The casting is
worked by tongs through a slot in the side of the cabinet (not seen), while the
worker dusts the casting with his arms through the two front holes. He can see
his work through the square pane of glass. (Photographs kindly made by Mr. F.
W. Hunt, Leeds.)

Manufacture of Electric Accumulators.[30]—Electric

accumulators are secondary batteries which serve for the storage of
electricity, in order to allow of a current when desired. A primary
battery is one in which the materials become exhausted by chemical
action, and, unless a portion or the whole of the materials is
renewed, fails to supply electricity. The secondary battery becomes
exhausted in the same way, but the chemical contents are of such a
nature that it is merely necessary to pass a current of electricity
through the battery (charging) in order to recharge them. In the
accumulator battery the positive element is peroxide of lead, and the
negative element spongy lead. The elements—several positive
connected together and several negative—are placed in dilute
sulphuric acid contained in vessels of glass.
The form of accumulator in almost universal use now is the pasted
plate, but it varies greatly in size, according to the use for which it is
required. It may be either large, to act as an equalizer or reservoir of
current in electric-lighting installations, or quite small for ignition
purposes in motor-cars. The litharge smeared on to one plate
becomes converted into the positive element, peroxide of lead,
during what is called the “forming process” (passage of the electric
current through the dilute sulphuric acid solution in which it is
placed), and red lead smeared on to the other becomes spongy lead
to form the negative.
The industry gives employment to about 1,200 persons. Plates are
first cast in moulds from a bath containing molten lead or of lead with
admixture of antimony. Irregularities in the plates so cast are
removed by a saw or knife (trimming), and sometimes filed or
brushed with a wire brush. The interstices in the plates are next filled
in by means of a spatula with paste of litharge or red lead, as the
case may be, which has been previously mixed either by hand at the
bench or in a special mechanical mixing machine. After drying, the
plates are removed to the formation room to be charged. To allow of
the passage of the current, positive elements are connected
together, and negative also, by means of a soldering iron or, more
frequently, of an oxy-hydrogen blowpipe flame. After formation is
complete the plates have to be built into batteries, or “assembled.”
Tailpieces, technically known as “lugs,” have to be connected with
each plate, effected usually by the oxy-hydrogen blowpipe flame.
Finally, a connecting bar of lead is cast on or burnt on to the lugs.
Dangers and Prevention.—In casting, danger is mainly from
dust in depositing the skimmings, and from fume also when old
accumulator plates are melted down. For these reasons exhaust
ventilation over the melting pots should be provided, embracing also
(by branch ducts if necessary) the receptacles into which the lead
ashes are thrown. In mixing and pasting, the danger is from dust of
oxides of lead to be controlled (see Fig. 6) by—(1) Exhaust
ventilation by branch ducts protecting (a) the barrel from which the
material is scooped, (b) the mechanical mixer into which the weighed
quantity of oxide is discharged, (c) the bench at which the mixing by
hand is done; (2) dampness of benches and floor to prevent raising
of dust either by manipulation of the (often) heavy plates or trampling
into powder the paste which may fall on the ground.
In assembling or putting together of the formed plates, and in
earlier stages of the manufacture also, filing or use of a wire brush
causes production of metallic lead dust and of the oxides when the
brush touches them—a danger only to be met by exhaust ventilation.
How far the poisoning to which the lead burners engaged in
assembling plates is attributable to lead fume, produced by the high
temperature of the blowpipe flame, and how far to handling (with
inevitable dislodgment of dust) has not been satisfactorily settled.
Incidence of poisoning on this class of worker in the past has been
marked.
Generally there is need for impervious floors, solidly built, so as to
prevent vibration and the raising of dust from passage of trolleys
conveying the heavy plates. Gloves are frequently provided, more to
protect the hands from contact with the sulphuric acid used in
making the paste and jagged edges of the plates than as a
preventive of lead absorption.
In the 10 years 1900-1909 incidence, according to precise
occupation, has been—Casting, 33; pasting, 114; lead burning, 69;
and assembling the plates, etc., 69.
Glass-Cutting.[31]—Red lead enters largely into the mixture of
raw materials for the manufacture of glass. Flint glass, for instance,
contains 43 per cent. of lead. The raw materials (white sand, red
lead, and generally saltpetre) require to be very carefully mixed, and
a few cases of poisoning have been reported from the dust raised in
sieving. One man works the sieve, resting on two runners across the
bin, while another shovels the mixture into the sieve. The operation
is not a continuous one, and respirators have principally been relied
on to protect the workers. It should be possible to carry out the
mixing operations in a dust-tight closed apparatus.
Poisoning from lead fumes generated in a glass furnace is
unknown. Lead poisoning used to be common in the process of
polishing cut glass on a brush by means of “putty powder” (oxide of
tin, 29 per cent.; and oxide of lead, 71 per cent.), mixed with water to
the consistency of a paste. The brush was made to revolve at high
speed, with dissemination of the putty powder as a fine spray into
the atmosphere of the workroom. Although rouge and oxide of iron
have replaced putty powder to some extent—especially for the
polishing of the bevelled edges of plate glass—no substitute can at
present be found to give the final lustre and brilliancy required in the
case of cut glass and in certain kinds of high-class work, such as
polishing lenses.
Locally applied exhaust ventilation has robbed the process of its
dangers. Pyramidal-shaped hoods enclose the spindle and putty box
and brush before which the workman sits. The draught of the fan
prevents escape of spray. The lad who feeds the brush with putty
powder stands at the side, and in our experience his cap and clothes
are now free from signs of splashing. Formerly the polishing was
done by each man at his own berth, thus endangering the health of
all working in the vicinity, as the custom of the trade is that the same
man carries through the work both of cutting and polishing. Polishing
occupies only about a fifth of a man’s time, and it has now, owing to
the position of the fan, to be carried out in one particular part of the
room.
Dr. D’Arcy Ellis[32], Certifying Surgeon for the Stourbridge district, has described
the processes as formerly carried out:
“The mixture of lead and tin is heated over a bright fire in a shallow iron pan. As
it melts, the top scum which forms is skimmed off, dried, pounded to a powder in
an iron mortar, and afterwards sieved. The person who does this work always
suffers more or less. He usually protects himself by wearing a respirator—there is
a good draught at the flue, and the sieve is enclosed in a box—but there is always
a certain amount of dust. This putty-powder is used on the wooden wheel, and is
dabbed on the wheel as it revolves. All good bold work can be polished in this way,
and there is not much risk to the workman, as the speed at which the wheel
revolves causes the mixture to cling and not fly about. This process does not
answer for any fine work, so it is contended; and to enable this kind of work to be
properly polished brushes made of bristles are used. They are mounted on an iron
spindle, and are usually about 6 inches to 7 inches in diameter, with a face of 1
inch to 1¹⁄₂ inches broad. They are driven at a speed of about 2,000 revolutions a
minute. The putty powder is applied to these brushes (which are of various sizes)
in the same way as to the wooden wheel—that is, by dabbing it on. For smaller
work, such as tumblers and wine-glasses, the workman applies the putty mixture
himself, holding the glass against the brush with his right hand, and using his left
underneath to apply the mixture. Where, however, larger work has to be done in
which the workman cannot manage with one hand, the service of a boy is called
in, who does what is called the ‘feeding up.’ This boy stands partly in front and
partly at the side of the brush, and applies the mixture with one hand with the wisp
of straw. In this position the boy gets splashed with the putty mixture which flies off
the brush, and it is generally believed by the workmen to be the most dangerous
occupation. At one time—not very long ago—all the various processes of the work
were done indiscriminately in the workshop, and consequently the men were
frequently found working in a perfect haze of fine dust, which had been thrown off
from the brushes. There was no attempt made to separate and detach the less
injurious part of the work, such as the roughing and cutting, from the general
workshop, the lead polishing only occupying about one-fifth of the workmen’s time.
After the glass has been polished by the putty it is taken away to another
department, where girls are employed as 'wipers out.’ They take the glass with the
dried putty upon it, dip it into a basin of water, and then wipe it dry. Some of these
girls have been known to suffer from lead poisoning.... Drop-wrist was frequently to
be seen—in fact, there was hardly a workshop in the district in which cases of
wrist-drop could not be found. They were all anæmic, and the albuminuric and
prematurely aged were frequently met with.”

In this small industry in the past the poisoning must have been
considerable. In 1898 nineteen cases were reported. Reference to
the table on p. 47 shows that the number now is greatly reduced.
Those reported are generally cases which have ended fatally from
the sequelæ of lead poisoning contracted many years previously.
Stained-glass painting—a form of vitreous enamelling—very rarely
gives rise to poisoning, as no dust is generated (see vitreous
enamelling for use of aerograph in glass-painting).
Paints and Colours.[33]—Most of the cases have occurred in
the manufacture of white-lead paint, although manufacture of
chromate of lead and of Brunswick greens (barytes with which
Prussian blue and chrome yellows are mixed) account for several.
The following table shows the precise occupation of persons
affected, the number of cases distributed according to precise
occupation, and the proportion of these to the total in 225 cases
which were closely examined:

Precise Occupation Number Proportion

of Person affected. of Cases of Cases
 in each to Total
Subdivision. (per Cent.).
Mixing and grinding (mainly of white lead) 144 64·0
Packing (mainly of red lead) 19 8·4
Sieving 2 0·9
Manufacture of chrome yellow 22 9·8
Colour house and filters 16 7·2
Painting and stencilling 6 2·7
Other processes 16 7·0

Knowing the conditions of work, we can confidently assert that the

poison must have entered the system in the form of dust in at least
90·0 per cent. of the cases, and in the remainder the possibility of
dust having been the cause is not excluded.
In a small factory the cask of white lead is broken and the material
scooped out into a pail. Scales are at hand, and when the amount of
lead removed weighs half a hundredweight the contents of the pail
are discharged either into a cylindrical pug-mill or into the pan of an
edge-runner to be mixed with oil. In large factories the dry white lead
is generally shovelled directly from the cask down openings or
shoots in the floor to the grinding mills below.
Dangers and Prevention.—Dust arises in unheading the casks
from the displacement of air following the scooping or shovelling out
of the lead, in filling the pails, and in discharging the lead into the
mill. All points should, and can, be adequately protected by locally
applied exhaust ventilation at each one of the points enumerated. A
telescopic arrangement of the branch duct in connection with the
barrel enables dust generated in scooping out to be removed as the
contents of the barrel get lower and lower (see Fig. 15).
 Fig. 15.[A]

[A] Fig. 15 shows the arrangement for preventing dust at every point where
it is produced in a factory where dry colours are ground, sifted, and packed
on a large scale. On the upper floor, the chamber is shown in which the
contents of a cask are tipped down a shoot leading in the one case to the
burr stone mill on the left, and in the other into the Blackstone sifters.
Exhaust is arranged at two levels to catch the dust arising from the
displacement of air. After grinding in the closed-in burr stone mill, a hood
and duct is arranged over the point where the material is discharged into
the barrel. Similarly, the casing of the two Blackstone sifters is connected
with the exhaust fan, and also the cover of the barrel into which the ground
material falls. Inside the edge-runner (the door of which is shown open) a
negative pressure is maintained, and one branch duct controls the dust in
the scooping out of the material from the barrel, while another is connected
to the cover of the receptacle into which the ground material is discharged.
Tapering of the ducts, tangential entry of branches, fan-box, and collecting
filters, are all shown. In the factory in question there are four edge-runners,
three burr stone mills, and two Blackstone sifters. Altogether exhaust
ventilation is applied at twenty-five points. (Drawing kindly supplied by the
Sturtevant Engineering Company, Limited, London.)