164

Interhalogen ompoundo are

720 Hydrogen Chloride the individual halogens
79. HO(an be prepared by (a) they are prepared by
(a) Nacl H,SO,
(b) NaHsO, Natl
420 K
823 K
halogens
(b) X X'bonds weakert
Aire1
() NaNO, H,S0, () they are thermally
(d) both (a) and (b). (d) there is alarger
SO. When three arts of conc. HCland one part o
COn. HNO, is mixed, aconnpound 'X is fomed.
Ihe corret option related to 'N is
86. Match the column !
appropriate choce.
Column I
Afferermolnneitlete
with
(a) is known as aqua tega
(b) 'N is used for dissolving gold
(c) Nis used tor decomposition of salts of weaker
(A) CIE,
Csdumn
acids
(d) both (a) and (b).
(B) E;
() IE;
(D) BrF
\hentyyra'Ttde
7.21 Oxoacids of Halogens (a) (A) - (ii); (B)
(b) (A) -’ (i); (B)
SI. The correct order of acidity of oxoacids of halogens is (c) (A) ’ (i); (B) (iv);: (C)
(a) HCIO <HCIO, < HCIO, < HCIO, (d) (A) -’ (iii); (B) >();
(b) HCio, <HCIO, <HCIO, <HCIO
(c) HClo <HCIO, <HCIO, <HCIO,
() ,
(d) HCIO, <HCIO, <HCIO, <HCIo 7.23 Group 18 Elements
82. The following acids have been arrangedlin order of 87. Xenon has closed shell
decreasing acid strength. ldentify the correct order.
ClOH II. BrOH
to give compounds with
(a) Xe atom has
conf
fluigur
uoria
nti
e on
large size and becaue
but t
III. IOH potential as compared to
othJower
er wae a
(a) I> II> II (b) II> I> III (b) Xe has unpaired electrons whichnobi
(c) III > II >I (d) I> III > II covalent bonds
(c) Xe has highest boiling point
83. Which of the following increasing order is not hence it cor
correct as mentioned in the property with it? compounds with fluorine
(d) fluorine is the smallest element hence
(a) HCIO< HCIO, < HCIO, <HCIO4
(thermal stability) react with all noble gases.
(b) HCIO, <HCIO, <HCIO, <HCIo 88. Which compound is prepared by the fol
(oxidising power) reaction?
(c) F<CI <Br <I (reducing nature) Xe + F 673 K
(d) HIO, < ICl < I, < HI (2:1 volume ratio)
(oxidation number of iodine) (a) XeF, (b) XeF;
(c) XeF, (d) None of these
722 Interhalogen Compounds 89. Which of the following statements is not c
84. Match the column I with column Il and mark the about XeF,?
appropriate choice. (a) It can be obtained by direct reation be
F, and Xe at high pressure.
Column I Column II (b) XeF, undergoes alkaline hydrolysis tog
(A) (CN), () Hydrogen bonding and Xe.
(B) IF, (ii) Deacon's process (c) XeF, is a powerful reducing agent.
and thrt
(C) CI, (ii) Pseudohalogen (d) XeF contains two bond pairs
(D) HF (iv) sp'd' hybridisation pairs. reac
(a) (A)’ (iv); (B)’ (); (C) ’ (iü); (D) ’ (ii) 90. What are the products formed in
the
silicon dioxide!
(b) (A) -’ (ii); (B) ’ (ii); (C)’ (iv); (D) ’ () Xenon hexafluoride with Sif,
(c) (A) ’ (iii); (B) ’ (iv); (C)’ (i); (D) (i) (a) XeSiO, + HF (b) XeF,+
Sif;
(d) (A)-’ (i); (B) -’ (ii); (C) ’ (iv); (D)’(iüi) (c) XeOF, + SiF4 (d) XeO,+