Semester 1 MOUNT CARMEL SR. SEC.

SCHOOL SET B
Time 90 min MCQ BASED PAPER (ISC PATTERN) Mark: 70
1. Which type of crystalline solid /crystal is expected Assertion and Reason based questions:
to be soft and have low melting point:
Directions : In the following questions, a statement of
(a) Covalent (b) metallic assertion is followed by a statement of reason.
(c) Molecular (d) Ionic Mark the correct choice as:
2. The substance which is used as an collector in froth
floatation process is: 13. Assertion: Roasting is a process in which the Ore
is heated strongly in presence of air.
(a) Sodium Cyanide (b) Potassium cyanide
(c) Copper sulphate (d) Pine oil Reason: Concentration of sulphide ore is done by
Calcination.
3. If the vapour pressure of solutions of two liquids
are less than those expected from ideal solution (a) both assertion and reason are true and reason is the
They are said to have: correct explanation of assertion.
(a) negative deviation from ideal behaviour (b) both assertion and reason are true but reason is not
(b) Positive deviation from ideal behaviour the correct explanation of assertion.
(c) ideal behaviour (c) assertion is true but reason is false.
(d) positive deviation for lower concentration (d) both assertion and reason are false.
4. Reaction between formaldehyde and CH3MgBr , 14. Assertion: Halogens are not found in free state in
followed by hydrolysis will give: nature.
Reason: Halogens are highly reactive compounds.
(a) tertiary alcohol (b) iso-butyl alcohol
(c) primaryl alcohol (d) secondary alcohol (a) both assertion and reason are true and reason is the
correct explanation of assertion.
5) 6 g of urea is dissolved in 90 g of water the relative
lowering in vapour pressure is equal to : (b) both assertion and reason are true, but reason is not
the correct explanation of assertion.
(a) 0.02 (b) 0.05 (c) 0.1 (d) 0.04
(c) If assertion is true, but reason is false.
6. When an ether is treated with chlorine in dark (d) Both assertion and reason are false.
The final product formed is :
(a) perchlorodiethyl ether (b) diethyl ether 15. Assertion: Boiling points of alcohols are higher
than that of ethers of comparable
(c) 1,1-dichlorodiethyl ether (d) 2 chloroethyl ether
molecular mass.
7. The high viscosity and high boiling point of HF Reason: Alcohols can form intermolecular hydrogen
Is due to : bonding while ethers cannot.
(a) Low dissociation energy of F2 molecule (a) both assertion and reason are true and reason is the
(b) Associated nature due to hydrogen bonding correct explanation of assertion.
(c) Ionic character of HF (b) both assertion and reason are true, but reason is not
(d) High electronegativity of fluorine the correct explanation of assertion.
8. Benzene diazonium chloride on hydrolysis gives: (c) If assertion is true, but reason is false.
(d) Both assertion and reason are false.
(a) Benzene (b) Phenol
(c) Chlorobenzene (d) Benzyl alcohol 16. Assertion: To obtain pure alkyl halides from
alcohols thionyl chlorides are the reagents
9. In SN1 mechanism ................... are involved as
of choice.
intermediate species. Formation of phenol from
chlorobenzene is an example of .........substitution. Reason: Thionyl chloride reacts with alcohols to give
alkyl halide.
(a) Anion, electrophilic
(a) both assertion and reason are true and reason is the
(b) Ethanoic acid, nucleophilic correct explanation of assertion.
(c) Carbocation, nucleophilic (b) both assertion and reason are true, but reason is not
(d) Carbanion, electrophilic the correct explanation of assertion.
10. In XeOF4, Xenon involves the hybridisation: (c) If assertion is true, but reason is false.
2 3 2 3
(a) sp (b) sp (c) sp d (d) sp d (d) Both assertion and reason are false.
11. A semiconductor of Si can be made n-type by 17. Assertion: An ideal solution obeys Henry’s law.
adding :
Reason: In an ideal solution, solute-solute as well
(a) trivalent impurities (b) tetravalent impurities as solvent solvent interactions are not
(c) pentavalent impurities (d) divalent impurities similar to solute-solvent interaction.
12. The high viscosity and high boiling point of H2O (a) both assertion and reason are true and reason is the
Is due to : correct explanation of assertion.
(a) Low dissociation energy of F2 molecule (b) both assertion and reason are true, but reason is not
(b) Associated nature due to hydrogen bonding the correct explanation of assertion.
(c) Ionic character of HF (c) assertion is true, but reason is false.
(d) High electronegativity of fluorine (d) both assertion and reason are false

MOUNT CARMEL’S Chemistry MCQ’s EXAM

 Semester 1 MOUNT CARMEL SR. SEC. SCHOOL SET B
Time 90 min MCQ BASED PAPER (ISC PATTERN) Mark: 70
18. The bottles A and B contain 1M and 1m aqueous 28. For the extraction of metal, answer the following:
solution of sulphuric acid respectively: (i) The smelting of iron ore in blast furnace involves all
(a) A is more concentration than B the processes except:
(b) B is more concentration than A (a) Combustion (b) Reduction
(c) Conc. of A = conc. of B (c) Slag formation (d) Sublimation
(d) It is not possible to compare.
(ii) Which of the following metal is obtained by leaching
19. The standard reduction potential of Pb and Zn the concentrated ore with dilute sodium cyanide
Electrodes are -0.126 and -0.763 volts Respectively. solution, followed by treatment with zinc?
The e.m.f of the cell (a) Aluminium (b) Iron (c) Copper (d) Silver
2+ 2+
Zn / Zn (0.1M) // Pb (1 M) / Pb is : 29. Conversion of Chlorobenzene into phenol.
(a) 0.637 V (b) < 0.637 V (i) Which of the following statements is correct for the
(c) > 0.637V (d) 0.889V above conversion?
20. The chemical composition of ‘slag’ formed during (a) Heating it with alc. KOH at room temperature
the melting process in the extraction of copper is: (b) Heating it with aqueous NaOH at 623 K under pressure
(a) Cu2O + FeS (b) FeSiO3 followed by acidification with dilute HCl
(c) CuFeS2 (d) Cu2S + FeO (c) Heating it with CuCN followed by acidification with HCl
21. Alkyl halides undergo: (d) Heating it with Na metal in the presence of dry ether
(a) Electrophilic substitution reactions (ii) What is the name of the above reaction?
(b) Electrophilic addition reactions (a) Dow process (b) Wurtz reaction
(c) Nucleophilic substitution reactions (c) Sandmeyer’s reaction (d) Kolbe’s reaction
(d) Nucleophilic addition reactions
30. For IF7 molecule:
22. The reaction of Lucas reagent is fastest with:
(i) The structure of the given molecule is:
(a) (CH3)3COH (b) (CH3)2CHOH
(a) Octahedral (b) Tetrahedral
(c) CH3(CH2)2OH (d) CH3CH2OH (c) Trigonal bipyramidal (d) Pentagonal bipyramidal
23. Close packing is maximum in the crystal lattice of: (ii) The type of hybridization of the given molecule is:
3 3 3
(a) Simple cubic (b) FCC centred (a) sp hybridisation (b) sp d hybridisation
3 2 3
(c) Body centred (d) None of these (c) sp d hybridisation (d) sp d hybridisation
24. Which of the following has the highest equivalent 31. Phenol is heated with NaOH and CO2 followed by
conductance: acid hydrolysis :
(a) 0.01N NaCl (b) 0.05 N NaCl (i) What is the name of the reaction?
(c) 0.005N NaCl (d) 0.02N NaCl (a) Cannizzaro reaction (b) Gattermann reaction
25. Which of the following property does not depend (c) Reimer –Tiemann (d) Kolbe reaction
Upon the number of solute particles only? (ii) What is the main product formed in this reaction?
(a) Boiling point elevation. (a) Salicylaldehyde (b) Salicylic acid
(b) Lowering in vapour pressure. (c) Aniline (d) Phenyl isocyanide
(c) Osmotic pressure. 32. during the conversion of concentrated ore to
(d) depression in freezing point. metal oxides:
26. Copper pyrite or chalcopyrite (CuFeS2) is the main (i) Heating of Ore in presence of excess of oxygen
ore of copper. The extraction of copper from its ore involve:
involves, concentration, partial roasting, removal of (a) metal Carbonates changes to metal oxides
iron and self-reduction. (b) As and P present changes to volatile oxides
(i) On heating the mixture of Cu2O and Cu2S, which (c) hydrated Al2O3 become anhydrous
one of the following will be obtained? (d) PbCO3 changes to Pb
(ii) The process used to convert carbonate ores to
(a) Cu2SO3 (b) Cu + SO3
metal oxide is :
(c) CuO + CuS (d) Cu + SO2
(a) Smelting (b) Calcination
(ii) Iron is removed during the extraction of copper as: (c) sublimation (d) Roasting
(a) FeO (b) FeS (c) FeSiO3 (d) Fe2O3 33. During the reaction of Alcohols compound with
27. In the reaction. C2H5Cl + NaOCH3  grignard reagents followed by acid hydrolysis :
(i) Higher aldehydes give :
(i) The product formed will be:
(a) Primary alcohol (b) Secondary alcohol
(a) C2H5 – C2H5 + 2NaCl (b) C3H8 + NaCl (c) tertiary alcohol (d) isomeric alcohols
(c) C2H5OCH3 + NaCl (d) C3H8 + 2NaCl + H2O
(ii) Propanone on reaction with methylmagnesium
(ii) The above reaction is an example of : chloride give :
(a) Sandmeyer’s reaction (b) The Wurtz reaction (a) 2 methyl propan-2-ol (b) 2 methyl proan-1-ol
(c) Aldol condensation (d) Williamson’s reaction (c) 2 ethyl ethanol (d) 2methyl ethanol

MOUNT CARMEL’S Chemistry MCQ’s EXAM

 Semester 1 MOUNT CARMEL SR. SEC. SCHOOL SET B
Time 90 min MCQ BASED PAPER (ISC PATTERN) Mark: 70
34. During reaction of chlorine with Alkalis like NaOH : 39. With reference to XeOF2molecule, answer the
(i) The Product formed along with water, when Cl2 following questions.
react with hot NaOH is: (i) What is hybridisation of Xe in XeOF2 molecule?
3 3 3 3 3
(a) NaCl + NaClO (b) NaCl + NaClO3 (a) sp d (b) sp d (c) sp (d) sp d
(c) NaCl + NaClO2 (d) NaCl + NAClO4 (ii) What is the geometry of this molecule?
(ii) The Product formed along with water, when Cl2 (a) Distorted octahedral (b) Square planer
react with cold NaOH is: (c) Pyramidal (d) T-shaped
(a) NaCl + NaClO (b) NaCl + NaClO3 40. In the colligative property elevation in boiling point
(c) NaCl + NaClO2 (d) NaCl + NAClO4
(i) Calculate the molal elevation constant of water,
0
if 0.1m solution has boiling point of 100.052 C
35. In the chemical reactions of Phenol:
(i) Reaction of Phenol with Zn dust to give benzene (a) 0.052 (b) 0.02 (c) 0.52 (d) 0.0052
is an example of : (ii) The unit of Ebbliscopic constant is :
(a) Oxidation (b) Reduction (a) Kg/mol (b) K/mol (c) mol/KKg (d) KKg/mol
(c) Alkylation (d) Acylation
(ii) Reaction of Phenol with Bromine in CCl4 give : 41. In the Stoichiometric defects in crystalline solids:
(a) 4-Para-bromo benzene (i) The compound which show Schottky as well as
(b) 2-bromo benzene frenkel defect is:
(c) 2,4,6 Tri-bromo phenol (a) NaI (b) KCl (c) NaBr (d) AgBr
(d) Mixture of mono-substituted products
(ii) Schottky defect is shown by those compounds in
36. In the hydrides of group 16 elements : which:
(i) The correct decreasing order of bond length is : (a) Size of cation is bigger than anion
(a) H2O > H2S > H2Se > H2Te (b) Size of Anion is bigger than cation
(b) H2Te < H2Se < H2S < H2O (c) size of cation is equal to anion
(c) H2Te > H2Se > H2S > H2O (d) Size of cation is smaller than anion
(d) H2O > H2S > H2Se > H2Te 42. For an electrochemical cell :
(ii) The boiling point of H2O is more than H2S due to: Cu / Cu2 (aq) // Ag+(aq) / Ag .
(a) low bond order of water Given E0 (Cu2+/Cu) = + 0.34 V, E0 ( Ag+/ Ag) = +0.80 V.
(b) Small size of Oxygen (i) The E.M.F of the cell is :
(c) H-Bonding in water
(a) 0.46V (b) 0.36V (c) 0.64V (d) 0.66V
(d) Strong O—H bonds
(ii) The Gibbs free energy change for this cell is:
37. Gold has cubic crystal whose unit cell has an edge
–3
length of 407.9 pm. Density of gold is 19.3 g cm . (a) 88.78 J (b) – 88780 KJ
–1
Atomic weight of gold is 197 g mol . (c) – 88.78 KJ (d) 8.87KJ
23 –1
(NA = 6.02 × 10 mol ) 43. From the colligative property of Osmotic pressure:
(i) The number of atoms (Z) in a unit cell of gold is :
(i) The relationship between the values of osmotic
(a) 1 (b) 2 (c) 3 (d) 4 pressure of solution obtained by dissolving 6.0 g/L
of CH3COOH (π1) and 7.45 g/L of KCl (π2) is:
(ii) The type of crystal structure of gold is :
(a) Simple cubic unit cell (a) π1 < π2 (b) π1 > π2
(b) Body centred cubic unit cell (c) π1 = π2 (d) none of these
(c) Face centred cubic unit cell (ii) To Solutions having same osmotic pressure are
(d) Side centred cubic unit cell said to be :
38. At 298 K, the specific conductance of 0.1 M acetic (a) Isotopic (b) hypotonic
-1 -1
acid solution was found to be 0.00163 ohm cm . (c) Isotonic (d) hypertonic
If its molar conductance at infinite dilution is 44. For a electrochemical cell reaction to be
-1 2 -1
390 ohm cm mol
spontaneous :
(i) The degree of dissociation for acetic acid will be: 0
(i) ΔG cell of the cell must be :
(a) 0.0179 (b) 0.0219 (c) 0.04179 (d) 0.0791
(a) Negative (b) positive (c) 0 (d) none of these
(ii) dissociation Constant for acetic acid will be : (ii) At equilibrium , EM.F of the cell become :
-2 -4
(a) 1.8225 x 10 mol/L (b) 1.8225 x 10 mol/L
-4 -4 (a) Negative (b) positive (c) Zero (d) none of these
(c) 1.225 x 10 mol/L (d) 0.8225 x 10 mol/L

MOUNT CARMEL’S Chemistry MCQ’s EXAM

 Semester 1 MOUNT CARMEL SR. SEC. SCHOOL SET B
Time 90 min MCQ BASED PAPER (ISC PATTERN) Mark: 70
45. The compounds formed between two of more 48. Group 16 elements have lower value of first
hydrogen are called inter halogen compounds ionisation enthalpy as compared to group 15
elements because:
(i) Interhalogen compounds are more reactive than
individual halogens because : (a) Half-filled p-orbitals in group 15 elements are
more stable.
(a) They are prepared by direct combination of halogens
(b) X-X" bond is weaker than X-X and X”-X” bond (b) Group 16 elements have smaller size than
(c) They are thermally more stable than Halogens group 15 elements.
(d) There is large difference in their electronegativity (c) Group 16 elements contain double bond while
group 15 elements have triple bond.
(ii) Which of the following is not an interhalogen (d) Group 16 elements have more number of
compound? electrons in p-orbitals.
-1
(a) ICl4 (b) ClF5 (c) IPO4 (d) ClF3
49. The action of sodium on alkyl halide to form an
46. Extraction of zinc from zinc blende is achieved alkane is called:
by :
(a) Grignard reaction (b) Wurtz coupling reaction
(a) Electrolytic reduction (c) Isocyanide reaction (d) Halogenation reaction
(b) Roasting, followed by reduction with carbon
(c) Roasting, followed by reduction with another metal 50. Phenol on reaction with ice cold solution of
(d) Roasting, followed by self-reduction benzene diazonium chloride in basic medium
give a coloured compound is called :
47. For which of the following electrolytes the value of
Δm and Δeq are same? (a) Kolbe’s reaction (b) Coupling reaction

(a) Na2SO4 (b) BaCl2 (c) KCl (d) Al2(SO4)3 (c) Diazotisation reaction (d) Wurtz reaction

MOUNT CARMEL’S Chemistry MCQ’s EXAM