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Multiple-Choice
1. There are seven common strong acids. Which of the following statements is NOT true for
strong acids?
Answer: B
Intermediate
2. There are two types of metal hydroxides, soluble metal hydroxides and insoluble
hydroxides, both of which are strong bases. Which of the following statements is NOT true for
strong bases?
Answer: B
Intermediate
A) 1.00E-07 M; 2.00E-11 M
B) 5.00E-04 M; 5.00E-04 M
C) 2.00E-11 M; 2.00E-11 M
D) 1.00E-07 M; 1.00E-07 M
E) 5.00E-04 M; 2.00E-11 M
Answer: C
Difficulty: Intermediate
Chapter 9 – Monoprotic Acid-Base Equilibria 2
Answer: D
Intermediate
Answer: B
Intermediate
6. Which of the following is NOT true for weak acids and weak bases?
A) Kw = KaKb
[B][OH - ]
B) Kb =
[BH + ]
[H + ][A - ]
C) Ka =
[HA]
D) pKa = −log Ka
E) pKb = −log Kb
Answer: B
Intermediate
Chapter 9 – Monoprotic Acid-Base Equilibria 3
[H + ][A - ]
A) Ka =
[HA]
B) F = [HA] + [A−]
C) [H+] = [A−] + [OH−]
[HA][OH - ]
D) Kb =
[A - ]
E) Kw = [H+][OH−]
Answer: D
Intermediate
8. Calculate the percentage dissociation for a 0.010 M hypochlorous acid solution. The Ka
for hypochlorous acid is 3.0 x 10−8.
A) 0.35%
B) 0.30%
C) 0.17%
D) 0.99%
E) 0.65%
Answer: C
Intermediate
9. The rule of thumb for neglecting the change in the formal concentration of a weak acid or
a weak base, x, during an equilibrium problem is valid:
Answer: E
Intermediate
Chapter 9 – Monoprotic Acid-Base Equilibria 4
10. The pH of a weak-base solution is calculated using systematic treatment. Which of the
following is NOT an equation needed to solve for pOH?
[B][H + ]
A) Ka =
[BH + ]
B) F = [BH+] + [B]
C) [OH−] = [BH+] + [H+]
[BH + ][OH - ]
D) Kb =
[B]
E) Kw = [H ][OH−]
+
Answer: A
Intermediate
11. A student calculates the pOH for a 0.01 M triethanolamine solution to be 4.12. To
simplify the math she decided to neglect the change in the formal concentration. Was she
justified in her decision? Kb = 5.78 × 10−7
A) She was justified, as the change in ×, 7.59 × 10−5, is less than 1% of the formal
concentration.
B) She was not justified, as the change in ×, 9.92 × 10−3, is greater than 1% of the formal
concentration.
C) She was justified, as the change in ×, 1.32 × 10−10, is less than 1% of the formal
concentration.
D) She was not justified, as the change in ×, 1.00 × 10−2, is greater than 1% of the formal
concentration.
E) She was justified, as the change in ×, 5.78 × 10−5, is less than 1% of the formal
concentration.
Answer: A
Difficulty: Intermediate
12. A 0.01 M solution of a weak base has a percent association of 18.32%. Calculate the Kb
for the weak base.
A) 1.83 × 10−3
B) 2.43 × 10 −11
C) 5.46 × 10−12
D) 4.11 × 10−4
E) 1.22 × 10−12
Answer: D
Hard
Chapter 9 – Monoprotic Acid-Base Equilibria 5
9-5 Buffers
A) Buffers resist changes in pH when acids or bases are added or when dilution occurs.
B) Buffers are a mixture of weak acid and conjugate base.
C) The pH of a buffer is independent of ionic strength.
D) The pH of a buffer is dependent on temperature.
E) Buffers are a mixture of weak bases and conjugate acid.
Answer: C
Intermediate
14. The buffer needed for a capillary electrophoresis experiment must have a pH of 10.0.
Which weak acid is the best choice for the buffer? Assume = 0.
Answer: C
Intermediate
15. A buffer is prepared by mixing 200.0 mL of 0.1500 M NaOH with 200.0 mL of 0.200 M
CH3CO2H in a 1-L volumetric flask and then diluted to volume with distilled deionized water.
Calculate the pH of the buffer. Ka = 1.75 × 10−5
A) 5.23
B) 9.72
C) 7.00
D) 8.77
E) 4.28
Answer: A
Intermediate
Chapter 9 – Monoprotic Acid-Base Equilibria 6
Calculated
16. Calculate the pH for a 4.3 × 10−8 M HCl solution with an ionic strength of = 0.1. H+ =
0.83, OH− = 0.76 and Cl− = 0.755.
17. Calculate the pH of 0.01 M HCN ( = 0.10) using activity coefficients, neglecting
activity coefficients, and the percent difference between the two. Ka = 6.2 x 10−10 for HCN. H+ =
0.83, OH− = 0.76 and CN− = 0.755.
Answer: pHactivities = 5.20. pH = 5.30. pHactivities is 1.92% less than pH. pH is 1.89% greater than
pHactivities.
Hard
Solve the weak-acid equilibrium problem with and without activity coefficients, then calculate
the percent difference between the pH values.
18. Calculate the percent dissociation for a 0.01 M HCN solution, neglecting activity
coefficients. Ka = 6.2 × 10−10 for HCN.
Answer: 0.0249% (Neglecting the change in x with respect to HCN because 0.0249% is less than
1%.)
Intermediate
Calculate [CN−], divide by 0.01 M and multiply by 100.
Answer: pH = 12.30 (If students report 12.00 then they failed to notice that neglecting the change
in 0.2 M results in an error of 5% of 0.2.)
Hard
Simple weak-base titration problem, and must be worked without assuming that the change in
the ethylamine concentration is less than 1% of the Kb.
Chapter 9 – Monoprotic Acid-Base Equilibria 7
9-5 Buffers
20. One liter of a pH 5.00 propionic acid buffer with a total concentration of 50 mM must be
prepared. Calculate the mmols propionic acid and sodium propionate needed to prepare the
buffer. Ka = 1.34 x 10-5 for propionic acid.
Answer: 28.6 mmols sodium propionate and 21.4 mmols propionic acid
Hard
Set mmol propionate equal to x and mmol propionic acid to 50-x. Plugged into the buffer
equation to solve for x.
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