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  • Chapter 8 - Part 2

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    Mohamed Salah
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    The document discusses phase diagrams for binary systems. It explains that phase diagrams show the phases present (liquid, vapor, or liquid-vapor mixture) over a range of temperatures and compositions. Key points on the diagrams are labeled to indicate phase boundaries and triple points. Both temperature-composition diagrams at constant pressure and pressure-composition diagrams at constant temperature are presented.

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    Chapter 8_Part 2

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    The document discusses phase diagrams for binary systems. It explains that phase diagrams show the phases present (liquid, vapor, or liquid-vapor mixture) over a range of temperatures and compositions. Key points on the diagrams are labeled to indicate phase boundaries and triple points. Both temperature-composition diagrams at constant pressure and pressure-composition diagrams at constant temperature are presented.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    14 views5 pages

    Chapter 8 - Part 2

    Uploaded by

    Mohamed Salah
    The document discusses phase diagrams for binary systems. It explains that phase diagrams show the phases present (liquid, vapor, or liquid-vapor mixture) over a range of temperatures and compositions. Key points on the diagrams are labeled to indicate phase boundaries and triple points. Both temperature-composition diagrams at constant pressure and pressure-composition diagrams at constant temperature are presented.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 5

    7/14/2019

    Explaining Phase Diagrams


    Tajammal Munir

    Process

    a – more volatile V

    yi
    b – less volatile ya
    yb

    xi xa xb

    1
    7/14/2019

    Txy Phase Diagram


    100 % b 100 % a

    V or superheated vapour
    𝑇
    L+V
    150

    T [C] 100

    𝑇
    50
    Pressure is constant 1

    L or subcooled liquid
    0
    0 0.25 0.50 xa & ya 0.75 1.0

    1.0 0.75 0.50 xb & yb 0.25 0

    Txy Phase Diagram


    100 % b 100 % a

    V or superheated vapour
    𝑇
    L+V
    150
    T [C]

    100 2 3

    𝑇
    50
    Pressure is constant 1

    L or subcooled liquid
    0 4
    0 0.25 0.50 xa & ya 0.75 1.0

    1.0 0.75 0.50 xb & yb 0.25 0

    2
    7/14/2019

    Txy Phase Diagram


    100 % b 100 % a

    V or superheated vapour
    𝑇
    L+V
    150 3 2

    T [C] 100

    𝑇
    50
    Pressure is constant 1

    L or subcooled liquid
    0 4
    0 0.25 0.50 xa & ya 0.75 1.0

    1.0 0.75 0.50 xb & yb 0.25 0

    Txy Phase Diagram


    100 % b 100 % a

    V or superheated vapour
    𝑇
    L+V
    150

    v
    3 2 3
    T [C]

    100
    l

    𝑇
    50
    Pressure is constant 1

    L or subcooled liquid
    0 4 4
    0 0.25 0.50 xa & ya 0.75 1.0

    1.0 0.75 0.50 xb & yb 0.25 0

    3
    7/14/2019

    Pxy Phase Diagram


    100 % b 100 % a

    L or subcooled liquid
    𝑃
    3

    P [atm] 2 l

    3 2 3

    v
    L+V
    1
    Temperature is constant 1
    𝑃

    V or superheated vapour
    0 4 4
    0 0.25 0.50 xa & ya 0.75 1.0

    1.0 0.75 0.50 xb & yb 0.25 0

    xy Phase Diagram
    1.0

    0.75

    0.50
    ya

    0.25
    Pressure is constant

    0
    0 0.25 0.50 0.75 1.0
    xa

    4
    7/14/2019

    b a

    d c
    McCabe and Thiele
    f e

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