SAFETY DATA SHEET

CALCIUM OCTOATE 10% (OPT-Ca-10)

Printed: 22/08/2022
Revision: 22/08/2022

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION:

 Product Name: CALCIUM OCTOATE 10% (OPT-Ca-10)

 Recommended Use: Paint additive; Auxiliary paint drier; Manufacture of paints, inks, and coatings;
Industrial Use.

 Restrictions on Use: None.

 Company Identification: Phone Number:

OPTICHEM SPECIALTIES FZE (+971 4) 883 9956

Chemicals Cluster, Roundabout # 11,
P. O. Box 261740, Jebel Ali Free Zone, Dubai,
United Arab Emirates
Fax (+971 4) 883 9957

 Email address: management@optichem.com

 Emergency Contact:
Saturday - Friday, 09:00 - 18:00:(+971 4) 883 9956.

2. HAZARDS IDENTIFICATION:

 Classification of the Substance or Mixture:

Flammable liquids (Category 3).
Serious Eye Corrosion /Irritation (Category 2 A).
Acute Toxicity, Oral (Category 4).
Aspiration Hazard (Category 1).
Specific Target Organ Toxicity – Repeated exposure (Category 1).

 Label Elements: Pictogram

 GHS Signal Word: Warning.

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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

Printed: 22/08/2022
Revision: 22/08/2022

 GHS Hazard Statement(s):

H226 – Flammable liquid and vapour.
H302 – Harmful if swallowed.
H304 - May be fatal if swallowed and enters airways.
H319 - Causes serious eye irritation.
H372 - Causes damage to organs <or state all organs affected, if known> through prolonged or
repeated exposure <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.

 GHS Precautionary Statements:

P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep containers tightly closed.
P235 – Keep cool.
P240 – Ground and bond container and receiving equipment.
P241 – Use explosion proof (electrical/ ventilating/lighting/…) equipment.
P242 – Use non-sparking tools.
P243 – Take action to prevent static discharge.
P264 –Wash {hands} thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P280 –Wear {protective gloves/protective clothing/eye protection/face protection}.

 GHS Response Statements:

P301+310 – IF SWALLOWED :Immediately call a POISON CENTER/ doctor/ …
P301+312 – IF SWALLOWED: Call a POISON CENTER/doctor/... if you feel unwell.
P303+361+353 – IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water [or shower].
P305+351+338 –IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P330 – Rinse mouth.
P331 – Do NOT induce vomiting.
P337+313 – If eye irritation persists: Get medical advice/ attention.
P370+378 – In case of fire: Use … to extinguish.

 GHS Storage and Disposal Statements:

P403+235 – Store in a well ventilated place. Keep cool.
P405 –Store locked up.
P501– Dispose of contents/container in accordance to local, national and international
regulations.

 Other Hazards:
No data available.

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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

Printed: 22/08/2022
Revision: 22/08/2022

3. COMPOSITION/INFORMATION ON INGREDIENTS:

Components CAS # EC No. PERCENT CLASSIFICATION

Calcium Octoate 53988-05-9 Acute Tox. 4;
258-901-1 65 - 75% Eye Irrit. 2
64216-15-5

Naphtha Asp. Toxicity 1;

(petroleum), STOT Rep. Exp.
64742-82-1 265-185-4 25-35 %
hydrodesulfurized 1; Carc. 1B;
heavy (White Spirit) Muta. 1B

4. FIRST-AID MEASURES:

 Description to First Aid measures

Inhalation:
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. If irritation develops and persists, get medical attention.

Skin Contact:
Wash affected skin with soap and water. Launder contaminated cloth before reuse.

Eye Contact:
Flush eyes with water for at least 15 minutes while holding eyelids open. Get medical attention if
irritation develops or persists.

Ingestion:
Do not induce vomiting. Rinse mouth with water. Immediately get medical attention.

 Most important symptoms and effects, both acute and delayed:

Eye contact: Irritation or pain. Watering and redness.

Inhalation : Head ache may cause irritation to respiratory tract, coughing, dizziness, nausea or
vomiting.
Ingestion : Harmful if swallowed.

 Indication of any Immediate Medical Attention and Special Treatment Needed:

No specific treatment. Consult physician, If necessary treatment should be provided
symptomatically.

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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

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Revision: 22/08/2022

5. FIRE-FIGHTING MEASURES:

 Suitable Extinguishing Media:

Extinguish with carbon dioxide (CO2), foam, water spay or dry chemical powder. As appropriate
for surrounding fire.

 Unsuitable Extinguishing Media:

Avoid water in straight hose stream, it will scatter and spread fire.

 Hazards Arising In Case of Fire:

Irritating fumes and organic vapors may develop when material is exposed to elevated
temperatures.

 Special Protective Actions for Fire Fighters:

Fight fire with normal precautions from a reasonable distance. Wear positive-pressure self-
contained breathing apparatus (SCBA) and appropriate protective clothing. Firefighter's clothing
conforming to European standard EN469 (including helmets, protective boots and gloves) will
provide a basic level of protection for chemical incidents.

 Further Information:
In the event of fire, cool drums/IBC’s with water spray. Suppress gases/vapors/mists with water
spray jet. Collect contaminated fire extinguishing water separately. Do not discharge into the
drains/surface waters/groundwater.

6. ACCIDENTAL RELEASE MEASURES:

 Personal Precautions, Protective Equipment, and Emergency Procedure:

Wear appropriate personal protective equipments; avoid direct contact with spilled material.
Avoid generation of dust. Do not breathe dust. Ensure adequate ventilation .See section 2 for
significant hazards, section 4 for first aid measures. Also see fire fighting measures in Section 5.
For emergency responders, SCBA is recommended. In case of large spills, chemical resistive full
body suit with anti static material recommended. Work gloves that are resistant to aromatic
hydrocarbons are recommended.

 Environmental Precautions:
Do not discharge into the drains, surface water or groundwater. In case of large spills, prevent
entry into water ways, confined areas, basement or sewers.

 Methods and Materials for Containment and Cleaning Up:

Soak up with inert absorbent material (e.g. sand, diatomite). Transfer to suitable container for
disposal.

 Reference to other sections:

See Section: 8, 13.
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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

Printed: 22/08/2022
Revision: 22/08/2022

7. HANDLING AND STORAGE:

 Precautions for Safe Handling:

Handle packages products carefully to prevent accidental bursting. Keep away from sunlight,
heat, and sources of ignition. Ensure good exhaust and ventilation at work place. Avoid contact
with skin and eyes. Take precautionary measures against static discharges. Do not eat, drink or
smoke when using his product. Wash hands before breaks and after work. Avoid all personal
contact. Use proper bonding, and/or ground procedures. Remove contaminated clothing or
protective equipments before entering into eating areas.

 Conditions for Safe Storage, Including Any Incompatibilities:

Previously opened containers must be carefully resealed and kept upright to prevent leakage.
Keep containers tightly closed in a cool, dry, and well-ventilated place. Incompatible with: Acids,
Halogens, and Oxidizing agents. Storage containers should be bonded and grounded which can
prevent accumulation of static charge. Natural rubber, butyl rubber, vinyl coatings are not suitable
for storage.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION:

 Occupational Exposure Limits:

COMPONENTS TWA
Calcium Octoate Not applicable
Solvent Naphtha 5 mg/m3

 Biological Exposure Limits:

No data available.

 Occupational Exposure Controls:

Avoid contact with skin and eyes. Do not breathe vapors. Avoid repeated exposure. Wear
suitable protective equipment. Hold eye wash fountain available if affected or Hold emergency
shower available. Remove soiled or soaked clothing immediately. Clean skin thoroughly after
work. Keep working clothes separately.

 Appropriate Engineering Controls:

Provide adequate ventilation.

 Individual Protection Measures:

Respiratory protection: Atmospheric levels should be controlled, in case of inadequate

ventilation wear respiratory protection. In this case half face filter respirator is suggested. Use
NIOSH/MSHA approved respirator if expose limits are of high concentration.
Eye/Face Protection: Wear chemical splash goggles. An eye wash and safe shower station
should be available nearby the workplace.
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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

Printed: 22/08/2022
Revision: 22/08/2022

Skin Protection: Wear appropriate chemical resistant protective gloves by considering physical
and chemical properties of the chemical. Any specific glove information provided is based on
published literature and glove manufacturer data. Chemical/oil resistant clothing is
recommended.
General safety and hygiene measures: Always observe good personal hygiene measures,
wash hands before breaks and at the end of the work day. When using chemical, do not eat,
drink or smoke. Ensure the eye wash stations and safely showers are close to the workplace
location. Routinely launder working clothes and clean protective equipments to avoid
contamination. Discard contaminated clothing or footwear that cannot be reused with proper
care. Handle in accordance with good industrial hygiene and safety practice.

 Environmental Exposure Controls:

Use appropriate control measures and limit or prevent the discharge or spillage of chemicals to
air, water or soil. Comply with applicable environmental regulations.

9. PHYSICAL AND CHEMICAL PROPERTIES:

 Appearance: Clear.
 Physical state: Liquid.
 Color: Yellowish.
 Odor: Solvent like.
 Odor Threshold: No data available.
 pH: Not applicable.
 Melting/Freezing Point Range: Not applicable.
 Boiling Point Range: 117 - 249°C.
 Flash Point: 950 F (350C), ASTM D93 Closed cup.
 Evaporation Rate: No data available.
 Flammability (liquid): Flammable.
 Upper Flammability Limits: No data available.
 Lower Flammability Limits: No data available.
 Vapor Pressure: 0.005 hPa at 200C.
 Vapor Density: No data available.
 Partition Coefficient: No data available.
 Explosiveness: Void of any explosive properties.
 Water Solubility: 14.9 g/L at 300C
 Relative Density: 0.88 - 1.04 at 86 F (300C).
 Solubility: Soluble in organic solvent (Sabutol/butyl carbitol).
 Oxidizing properties Non-oxidizing.
 Auto-Ignition Temperature: No data available.
 Decomposition Temperature: 2900C or higher.
 Viscosity, max: <50 Seconds (F/C No. 4 at 86 F (300C)).
 %Metal, as Ca: 09.80 – 10.20.

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CALCIUM OCTOATE 10% (OPT-Ca-10)

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10. STABILITY AND REACTIVITY:

 Chemical Stability:
Material is stable under normal conditions of use and storage.

 Reactivity:
No hazardous reactions if stored and handled as prescribed/indicated.

 Possibility of Hazardous Reactions:

Avoid contact with strong acid and strong base.

 Conditions to Avoid:
Keep away from high energy ignition sources/open flames. No smoking.

 Incompatible Materials:
Acids, Halogens, Oxidizing Agents.

 Hazardous Decomposition Products or byproducts:

Material does not decompose at ambient temperatures.

11. TOXICOLOGICAL INFORMATION:

 Principal Principle Routes of Exposure

Inhalation, Eye contact, Skin contact, Ingestion.

 Acute Toxicity:
According to regulation (EC) 1272/2008, the acute oral toxicity estimate (ATEoral) is 1289 thus it
requires a classification as acutely toxic via oral route category 4.

 Skin corrosion/irritation:
No adverse effect.

 Serious Eye damage / irritation:

May cause discomfort to eyes. In long term exposure oedema/redness/corneal opacity can be
caused.

 Respiratory or skin sensitization

No adverse effect.

 Chronic Toxicity
No data available.

 Germ Cell Mutagenicity:

Not to be classified according to regulation (EC) 1272/2008 or Directive 67/548 EC as genetic
toxicant.

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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

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Revision: 22/08/2022

 Carcinogenicity:
No data available.

 Reproductive Toxicity:
No adverse effect.

 STOT-Single Exposure:
No data available.

 STOT-Repeated Exposure:
Target organ: Central Nervous system.

 Aspiration Hazard:
Harmful if swallowed.

 Symptoms Related to the Physical, Chemical, and Toxicological Characteristics:

No data available.

 Interactive Effect:
No data available.

 Mixture Effect:
No data available

12. ECOLOGICAL INFORMATION:

 Toxicity:
No data available.

 Persistence and Degradability:

Readily biodegradable (according to OECD 301A guideline).

 Bioaccumulation Potential:
Aquatic/sediment: No significant bioaccumulation potential is expected.
Terrestrial: No data available.

 Mobility in Soil:
No data available.

 Results of PBT and vPvB Assessment:

PBT AND vPvB assessment does not apply.

 Other Adverse Effects:

No data available.

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 SAFETY DATA SHEET
CALCIUM OCTOATE 10% (OPT-Ca-10)

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Revision: 22/08/2022

13. DISPOSAL CONSIDERATIONS:

 Waste Disposal Methods:

Disposal must be in accordance with current local, state or national regulations and material
characteristics at the time of disposal. Dispose of empty containers or non recyclable products
via licensed waste disposal contractor.

 Contaminated Packaging:
Uncontaminated packaging can be re-used. Empty contaminated packaging thoroughly; they
can be recycled after thorough and proper cleaning. Inform the consumer about the possible
hazards of unclean empty packaging for recycling or disposal. Packaging that cannot be
cleaned are to be disposed of in the same manner as the contents.

14. TRANSPORT INFORMATION:

 Land Transport (ADR/RID):

UN Number: 1263
UN Proper Shipping Name: Paint Related Material
Transport Hazard Class: 3
Packing Group: III

 Marine Transport (IMDG):

UN Number: 1263
UN Proper Shipping Name: Paint Related Material
Transport Hazard Class: 3
Packing Group: III
EmS code: EmS(Fire) :F-E / EmS (Spill): S-E

 Air Transport (IATA/ICAO):

UN Number: 1263
UN Proper Shipping Name: Paint Related Material
Transport Hazard Class: 3
Packing Group: III
Passenger and Cargo Aircraft Quantity 60 L Packaging instructions 355
limitation:
Cargo Aircraft Only Quantity limitation: 220 L Packaging instructions: 366 Limited
Quantities - Passenger Aircraft Quantity
limitation: 10 L Packaging instructions: Y344

 Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable.
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CALCIUM OCTOATE 10% (OPT-Ca-10)

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Revision: 22/08/2022

15. REGULATORY INFORMATION:

 Safety, health and environmental regulations/legislation specific for the substance or mixture

US Federal Regulations:

Calcium Octoate(53988-05-9)
Listed on United States TSCA 8 (b) (Toxic Substances Control Act) inventory.

 International National regulations:

Calcium Octoate(53988-05-9)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China).
Not Listed on China Catalog of Hazardous chemicals 2015.
Listed on NZIoC (New Zealand Inventory of Chemicals).
Not Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances).
Listed on the Vietnam National Chemical inventory.
Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of
Chemicals).

 EU-Regulations.

Calcium Octoate(53988-05-9)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical
Substances).

 Chemical safety assessment

No chemical safety assessment has been carried out.

16. OTHER INFORMATION:

 Further Information:
Refer to product specification for actual metal content.

 History:

Date of issue/revision: 23/08/2022.

Date of previous issue/revision: 28/01/2021.

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CALCIUM OCTOATE 10% (OPT-Ca-10)

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Revision: 22/08/2022

 Abbreviations and acronyms:

OSHA: Occupational Safety & Health Administration.
IMDG: International maritime dangerous goods code.
IATA: International Air Transport Association.
DOT: Department of Transportation.
ADR: International Carriage of Dangerous Goods by Road.
RID: International Carriage of Dangerous Goods by Rail.
ICAO: International Civil Aviation Organization.
OECD: Organization for Economic Co-operation and Development.
IARC: International Agency for Research on Cancer.
GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
UN: United Nations.
SCBA: Self-Contained Breathing Apparatus.
TWA: Time Weighted Average.
CAS: Chemical Abstracts Service.

 Disclaimer of Expressed and Implied Warranties:

The information contained in this leaflet is intended to be of assistance to users, but is without
warranty of merchantability, fitness for any particular purpose or any other warranty is expressed
or is to be implied regarding the accuracy or completeness of this information, the results to be
obtained from the use of this information or the product, the safety of this product, or the
hazards related to its use. This information and product are furnished on the condition that the
person receiving them shall make his own determination as to the suitability of the product for
his particular purpose and on the condition that he assumes the risk of his use thereof.

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