(Please wrtte your Ecan Roll No.) cam Roll No.

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END TERM EXAMINATION
FRST SISTER B. TECE.| DIECEIBER 2016
Paper Code: ETCH-113 Subject: Applled Chemistry |
Time: 3 Hours acium Marks:75
Note: Attempt any fve questions including Q no.1 whlch is compulsory.
Select one question from each unit
Define HCV and GCv. (2.5)
(b) Define order and molecularity of a reaction with suitable example. (2.5
(C What is biodiesel?
(d) State Gibb's phase rule. (2.5)
(2.5)
e what is Piling-Bed-Worth rule?
(2.5)
what is an eutecticmixture?
(g Explain what is (2.5)
happening at the triple point of water. How many phases are
there in the system at
What is synthetic
this pointr. (2.5)
(h) petrol?
() Name the catalyst used for the following (2.5)
(a FischerTropsch process reactions/processc )
(b) Contact Process
c Zeigler Natta Polymerisation
(d) Haber's Process
(e) Homogeneous hydrogenation oipjugaad.com
reaction
UNIT-I
Q2 (a) Differentiate the following
Chemical fuel and nuclear fuel (2.54-10)
() High temperature and low temperature carbonizationa
ii) Ficed and
Fluidized bed
catalytic cracking
(iv) Octane and cetane number
(b) What is sweetening of petrol?
(2.5)
Q3 (a) Explain how the calorific valye of a kuel be deterimined by.
calorimeter with the help of a neat diagran.
can
Bomb's
(b) Calculate GCV and NCV of a gaseous fuel from the
rom calorimeter experiment. following data obtained
Volume of gaseous fuel burnt at STP -
0.08m3
Temperature of inlet water 26°C
Temperature of outlet water 32°C
Weight of water produced by steam Condensation 0.01 kg.
Late heat of steam 587 Kcal/kg (6)
UIT-I
Q4 (a) What is "degree of freedom" of a system? Calculate degrees of freedom of the
folowing systema:
() Water (liquid) > water vapour at 1 atm. (10)

() An aqueous solutdon of glucose

iv) Pure crystals of Cu804.5H0
(b) What are cooling curves?
(2.5)
Q5 (a) Explain Langmuir Hinsheh od
(b) How does á mechanism
of catalysis in detail.
(
catalystincrease the rate of reaction by
pathway wil it aiect the rate of backward reaction inaffecting
the reaction
case of a reversible
reaction? Also describe auto
catalyais
with suitable exampes. (6.5)

P.T.O.
ETCH-13

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 UNIT-IM
(a) Describe the principle and theory of EDTA method for determination of
hardness of water. 6.5)
(b) 1g of CacOs was dissolved in dil.HCI and soutiondilite to 1 litre. 50 mi of
this solution required 42 ml of EDTA sohution while 50 ml of sample wateer
required 15 ml of EDTA. On the other hand when 50 ml of boiled water
sample-titrated aganst EDTA consumed 9 ml of soution. Calculate total,
permancnt and temporary hardness of water in ppm. (6)
Explain the following
a Carbonate and phosphate conditioning (6)
(b) Lime soda proces8s (6.5)
UNIT-V
(a) Define the factors affecting the corrosion rate. 6.6)
(b} Explain with reasons- (6)
( Stainless steel is resistant to atmospheric conversion
(ü) Iron in contact with copper corrodes more rapicly than lead
(i) Cr anodes are not used in chromium plating

(a) Describe the "Electrochemical theory of corrosion".

Q9 (b) Write short note on soil corrosion and its control
ad.co
IPJ.

ETCH-1W3
Plgae wrtts your Exam Rol
No.) eam Rou No **** ***********

END TERM EXAMINATIOON

FIRST 8EESTIER B.TBCH] DECEMBER 2017
Paper Code: ETCH-105 Subfect: Applted Chemistry-I.|
Time: 3 Hours_ Macdmum Marks: 775
Note: Attenmpt any five questions.
Q1 (a) How caustic, embitterment occurs and give the chemical reactions
involved in it. (7.5)
(b) How the exhausted ion exchangers are regenerated and give the
method of their regeneration. (7.5)
Q2 Write short notes on: (3x5-15)
(a Reverse Osmosis
6 Phosphate conditioning
(c) Disinfection
(d) Aeration
(e) Scale & shudge

Q3
jugaad.com
(a) What is the difference between Petrol, Kerosene oil & diesel oil. How
would you convert Kerosene or Diesel oil to petrol (7.5)
(b) Draw &s explain Boy's Gas Calorimeter. (7.5)

Q4 (a) A solid fuel coal containing 80% carbon, 10% hydrogen, 2% sulphur,
3% nitrogen, 1% oxygen and ash 4%, then calculate the high & low
caloriic valueof that solid fue.
(b) Explain the following terms: (4x-8)
( Cracking
i) Octane number
(iijCetane numberT
(iv)Reforming
Q5 Explain the following: (5x3 15)
a Dry corTOsion
(b) Wet corrosion
(c Ideal& non ideal soution

Q6 Write ahort notes on: (3x3-18)

(a) Composting
(b) Radioactive waste
(c) Pollutants
(d) Acid Rain
() Smog
Q7 a Explain the Nernst distribution law. (7.5)
(b) Explain the soil polution. (7.5)

P
 (Please write your Exam Roll
No.
Exam Roll No. .
END TERM EXAMINATIQON
FIRST SEMESTER [B.TECH
Paper Code: ETCH 113 NoVEMBER-DECEMBER 2018
Time : 3 Hours Subject: Applied Chemistry
Note: Maximum Marks :75
Attempt any five questions including Q. No. 1 which is
Select one
question from each unit. compulsory.
Q1.a). What is a fuel? State the features
of a good fuel. (5x5-25)
b} Draw the phase diagram of water.
and triple point. Explain the terms-critical
point
c) What is a
catalyst? Describe its characteristics features.
d) Describe what is water softening by internal treatment.
e) Discuss in detail the factors
influencing corrosion.

2. Unit-
a)What is cracking? Differentiate
crackin8 between thermal & catalytic
b) Explain
Ojucdaa.COT65)
knocking and anti knocking agents. What is cetane and
octane number of afuel?
Q3. a) Draw a Labelled
diagram and explain the working of
by-product oven
for the Otto-Hoffmann's
manufacturing of metallurgical coke. (6.5)
b) The composition by weight of a coal
6%, N=S-1%, sample is C-82% H= 6%, O=
2% and ash=3%. ,

Calculate the minimum air required for complete combustion of

ol coal. 1kg
(6)

Q4. a) State Gibb's Phase rule. Unit-

Also, find the
following systems: degree of freedom of the

i) NH« Cl(s) NH3(g)+HCl(g)

i) Aquous solution of NaCI and
Na2CO3.
ii) Water (liquid) water
(vapour).
(6)
b} Draw the cooling curve of a
eutectic point in it. pure substance and clearly identify the
(6.5)
Q5 a) Differentiate between
congruent and Incongruent melting compound
by giving suiable examples.
(6)
b) Draw and explain the phase diagram of Lead-Silver System.
(6.5)

P.T.O.
ETCH-U3
 Unit-1I

Q6. a) Describe in detail the EDTA method of determining the hardness of

water. (6.5)
the use in [ndustrialy Give
b)Explain ofcatalyst important processes.
examples.
Q7. a) Discuss the lime-soda process used for external treatment for water
softening. (6.5)
b) A water sample has the following dissolved salts (mg/L). :Calculate
its temporary and permanent hardness in ppm, of CaCO3.
Mg(HCOs)2= 80, MgSO= 110, CaSO4-85, Mg Cla-94, CaCl2=84,
NaCl-50. (6)
Unit-IV
Q8 a Explain what is Soilprevented?
Cotrosion? HoW iis afeçting the fertility of
so12 Howitcan be (6.5)
b) Whatis Cathodic protection and sacrificial Anodic protection? (6)
Q9. What happens and why?
a) A piece of iron is kept in Saline water (3)
b A steel pipe is connected to copper plumbing. (3)
c) A zinc plate is fixed below the ship. 3)
d) Iron next/ washers/ valves are cleaned and packed with zinc dust
and rotated. (3.5)

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