Poge

Dale

Chaht-4
CHEMCAL KINGTICS

Bomch thimADU UM Auhich ue dsals about

LAP

at t-0 CRI,=10mel (P1,=Omol

at. t50AAC LR 6mol

JASrt tmML

urt time

Od UactLÒn -[RI-[RJo =[P)-[P].

t 2 - bi
t2-ti

Ad uadior I-Lo =_-0

50-O 50

50 50

Rade acluom = -ARI =_ALP

t
- 8 numdiNAlTs dULLas imCoC o Riactant

Camlin
 rue
Dote

a a balameu dhunmical equotuon

alA) +bLe cC do

b t

Nt Ha 2ZRD aNH3
90t o m -AlN=LALH2]=4 OWM)
3

-A LN23 = docuuaseim comcnloalu0n oRN2

06 r t tinme

AH _dicaas CoMcimoaluon Ha

A LNHaJ McMaae in_ Comcunaludn aK NH3-

Camlin
 Dote

ol a l A Uaston

A D Kat

ReaiuD Abanniu kat

o edoumUms Raa owm ut any nJant

s u n t u m a a l

-LAL(2-4)»25
At 10-5

LRJ2
Sonc d

2
[Ku Hai n "d [R
dt

S 1

wms

Camiin
 Pepe
Dote

FaoTauu a4elin satu nlacion

Comelnlaaltow m
Tombualue
atlyAt
SuntacL auma quadlamE

8ebendamL oncnalion Kau Rn

Conandu a uatu a sun
aA +b@ c C +0LD

Accodunats Jaus mass Octuoru

POdL L um a "LAJA O
OtL M dihnds om conc 0 AardB
witw home s0me pouuo. Ti
may_nt ba eauouL to Hho poU ay 0L
Stoichiomaoul
CuyioienË n bolomecud Chemial
equaiuom

Radu onJumb
Wn
ConALnuation y each Iiu i Takvm
PO Conümt.

Camlin
 CambeO
Cam be eAactUmal

Molcdauty
a A +bB> cC * dD
sTLchiomebue cuiuonE
Tu sAum i t o n lirontary
0 alancd chimidl
Aactamt um
HUOctonis callud Mollcuiauity
atba molulauty
Camnotbio_
CaMn e aactwnal

MOlLeulauity
sum stiicaicmiLC CLLLeLnt

uacant nalaane
COcimttalintAM
chumialelemmentaay ex

OMndt beo
Cambs0 amet b aclUI
am bl eocuonaL CLLNd ThieuTAs
oumd puumunlaily
applicable to
pbluable tp elumenlaciy

Camlin
 Pago:
Dote

Unt g RalLconatomt

Mat= k LA]
wb
mOl

Rato [A]_
mella K{{mol L:)

Acomd, 0ud uanum

Raur K LA]A
mlLA K(mlL")

AOK LAJ"
mol L"8k LmoluJ"
moLh's =K

C a m l i n
 Doto

Irlopual

-d[R
db

-oCA
dk

R k dt
-LRJ= bt+C
fn LA=Ro_
Wh t0S

-Ro KA 0+ C

Putuna alun 04 C m
- = Kt-[RJ

[R-LR -t

dt
On duneating bofn hw Jid
d = ELR
dt

Camlin
t
A O *ON10 mel/
0nun
60000 R3O 3 O0

80 ld L2 NIO)
60 Lo'aONIO*

303 eg

O 038 Cag 6*2

 Dote:
L

Half a sam
The duwauon un ulnih unuual Cvunluoliei
PUolant becoms hal4

wAnt hCRF [R),

2

Haly lt 0 0dla

Ro-R) Kt
A-R)
2
Kbla

UCA
803xlog Ro
Ro2
blp03
K
_loq l2

/2 :644
K

Camiin
 ahond
dhcwbralsow wUadon
aranal s ume Pap

Fo Zeau udu
SLom-K
KeLI.-
W--yt TLo
Cwo
m

tmo l&)
On hot

m LA.ln LR] =_Kt

mctC

2-B03 !og_LR= kt+ 2-303 AOq LR)u

Log IR) E K t t La LRJ
2.303
m C- C

toyLk
a 303

Camlin
CamiT
 d u uuclior

CedOCMC
SgancanL

satu
ehwndanoe omb on

AnULaLLNA Ch bu
Rax comaOnt muasly QUls doubld On

a ww
 Actnalioncomplo)
A Dcte

PotenTaL

Azt62
A-6

UaKiom cooda

eothuoumuc

A unmsdiati ivaluornOgpla)

A-B

£A
0ludiwok
eraohumo

Camlin
 Data

Activl eniy

sacduon

Aalamt

owmcRasN omm Aon 0Moleulshaumna ulliuent

ackiwluoM yAa mcnaul.

AChivaluon_oogy_
AaaruUAeaualum p0
GaRT
K_Ae

AAuhnlu lacto
Ea AcMali tnuugly

TTem*.
side
o putura lngaultonOm b0ln H

LnK) n Ag Ga
RT
at Temp T
ln lK) = nA- Ea

30

n Ko =_ LnA Ga
RT2
Camlin
 Poge
Dote

)fom_ lü)
substutmg

nha AnK
RT1

in K2
K

:303R T 2

20 Loq4 2 9 813,
2 -303x8314
a 313 -93)
0 6Xa 30X8.314
13318

X 303x8-314 X293x313 E a
10

0-3X 30 X8 3/4 X91704

JO

0 8x19 lx 91109
5 43
3 X109
0

52 5yq2+

52 5 412 KI Mo
Camin
 Page-
Date

Piot qEapn blur nk amd

TI
Lnk z
lnA - Ea 2-308 ogk z2303!ogA Ea. 1
RE T R
MC Roq loq A-6a
2:303R T

AnA

--Ecu
slnk R 303R
oqA

amlin
 Dote

Uet Calalypt en sai

ANuttuout cangig uaalilatuidy

KCtolalyst
pecolt alllounat pattu aettta actiualuwu

Pcluned -MM MACimMIw

Mo (alalyst

M CO0aivaluon
| T peuamel o atalyst dos not a l t o t a

Calalyst dots not altu uu poun equuu biuiwm

Camlinn
 ate

/'olsco MgPAChumuitat (al Ktaél

l Jo u MDOL ww.k 0duct tw madant

COlide dth ea o l
Colla0n Queney

D sUCOd pemat Lolwwe u (allid

CORQion uauemey

F peop foumalon Puaduci UOtant

COdu uutto
1e CQl
l atu othw
otekdo MLOome h a peuep OLuenlalo

CH B + OH

H B + OA No badut
IwpeuobL
CO'suom

C-er +OH OH

p&op COLÄLO

3Sutcwt actuualtoi u
Camlin
 Page
Date

RT
Rata ZAG e
CollisO ougueney
e Factuon MOtLA hauung, ulhiuents
acualwv Bngy

10

Mwwmuwrv enuymudd
1 buak bonds"ondAD
onv vnud bonds