Chapter4

hamical kinetia
it
mechanm

tiu nLachon

Rat o a Raciom
R podut

Rat tmo
Ratu - ALRJ
At Seactmt

Rat +oLPJ Ratu in tma f

produtE

Mol
Unit f Ratu (ons AXS
mol
time

atu
taston
1. Nate of åactomt 1:Suntaa aea
2 Conc.
3
Catalot
Iemporstre
5.

S mlvat
 EyreN nat f (elleuiny
at

Rali
CHLI

Ratu has
hyilentatn
Katu law

Rat aa CRI
Ral

aA + bR
Kali
k A x C&J
Rale

nate Cnotamt
 yssyHL+
ma called
C bne
takl rLacion h
can ReCmlex
n
HI 2 + H
Keacta tlmontay
1
RHE
Ral
law Aate
did mm
 AenilcAl

Maleculanty
CAlle mlulariay

Wimocul a -
in i t

H2 + I QHI

NO + 02 2N02

Nole- Moleulasity above3

3isis not
simltanouo collisiom
 Rypertn ce 6/4 Grder md Molulaily
Grder moleulanity

Chemical ua ccon.
#Is a heantical amd
RAactieal guanteby ment a ruacton

rlica n bo
6ohlh elemensey

Valueo nll , 2 3

NGl: g0 aa complax neactin (indud mony typo)

lintt af Rat Cnot onc (h)

Coide u eacion

Rat kate Rati

CAJxcBJ [eone] atb

(ml )"
mol S

mol s
wssp
 S

hleqratd Ratu gualion

Zovo rdor

RP
Kate -4CR]

--5 t t +c

t o, CRJ =[Ro] hiha comc

Sloyllk
LRI=-ht t [Ro]

Slep
t
TUacti on.
 dt

dlRJE-kX dt
Ce]

Jnagralny on tolh ideo

CRI

lnce

t=o
C

y
-Kt lale) - lhce]
t
Ths is
 inütial Conc

t CR]-Ce7

Grder Reain

K
 2-303 Lko

t R303 24

t 2-So? X o3ol0
K

nalaval dllg

Snflena f Heat on kate sf kiactio

tmp aikd by ot,
thu atu Conotomt

kelation blw Ratu Conotamby nd Jempratue (r)

Arrbniue iuatien
kz A. EYeT

Rate Conotom
A Anhenio lonolmt
Ea
Universal ha Cama tan 3314)
Jemp Racan:
 Activation Energy
chimical eaion mollln
Collisiom
HI
H
H

H
H..
H
astiyatd
Complce
Achvnd

H2+LL

RLactim Codrolaat

Catalyt
Auduiy
uih cakatyt

Rehcten
 Ae

taking

t lue

toseT
A

RT

-Za
RT

Canaider a lactn at TT temperale

RTI

tr the Same acttmt at difercnk

CUntmt k
- Ea t lu A
RT2
 RT2 RTI

RTI

2-303 log 52

Numemcalo
Yhe dLmpoaltion a etomt procluct bave
at activdti

3
bccome 5oS

TI(oc
 leg

2 563
2455

31

o2

Rate f lacton becme douse whw he

Lenp chonye fom 3 /3 6 Cin Ea

T-TI
Ti T2

Ka 273
314 X25
have
6"30|o
91109
3
S 74lo Ea

abDd
 to3 Lag
eataako
Calalata
feCoNy

93
Cartow

LRu)
O63/K
Seientskom

3465x9

Kati A
alculat l

COnat
onnt

mig o

803 n

693
 303 t t t

2:303

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