Important questions from previous year question papers

Multiple Choice

Q.1 Cp - Cv =
a) G b) H c) E d) R
Q.2 ∆ Hc is
a) Heat of Formation b) Heat of Combustion c) Heat of dilution d) All of
these
Q.3 Expand PPM
a) parts per miles b) Parts per million c) Pound per meter d) Parts per meter
Q.4 Equivalent weight of CaCl2
a) 65.5 b) 55.5 c) 75.5 d) 85.5
Q.5 Formula of Pressure
a) Area/Force b) Force/ Area c) Work done/Area d) Area/work done
Q.6 Unit of Molarity of solution
a) moles/kg b) unitless c) moles/litre d) gram/ litre
Q.7 Name of term related to Ideal Gas equation.
a) universal gas constant b) Plank constant c) Steafan constant d) None of these
Q.8 Molecular weight of H2SO4
a) 49 b) 98 c) 73 d) 43
Q.9 Name SI unit of Pressure
a) Pascal b) Newton/ cm2 c) lbs/inch2 d) Bar
Q.10 Average molecular Weight of Air
a) 31.84 b) 29.84 c) 30.84 d) 28.84
Q.11 Heat capacity at Constant Pressure is devoted by
a) CV b) CP c) CT d) CH
Q.12 Unit of T in PV= nRT
a) C b) R c) K d) F
Q.13 Katoms of carbon which weighs 36kg
a) 3 b) 9 c) 6 d) 12
Q.14 How many k atoms of Na are present in 3k moles of Na2Co3
a) 6 b) 3 c) 9 d) 12
Q.15 Molecular weight of NaOH is
a) 80 b) 40 c) 70 d) 50
Q.16 Formula of potential Energy is
a) mgh b) 1/2 mv2 c) mg d) None of these
Q.17 For ideal gas mixture, pressure%=_____% =moles%
a) Temperature b) Volume c) mass d) Solids
Q.18 The product removed from top of the distillation column is
a) Distillate b) Bottoms c) underflow d) None of these
Q.19 K moles of K2 CO3 that will contain 117kg of k
a) 2.5 b) 3.5 c) 1.5 d) 4.5
Q.20 Which one represents Charles’ law.
a) v/t= constant b) p/v=constant c) pv= constant d) PV=nrt
Q.21 A reaction has reactants 1 moles of H2 O and 1 mole of NaCl, and products NaOH and HCl,
what are the total moles of product.
a) 1 b) 2 c) 3 d) 4
Q.22 25 gm can also be expressed as:
a) 2.500 kg b) 0.055 lb c) 55 lb d) 0.25 kg
Q.23 The quantity of matter present in an object is:
a) Mole b) Mass c) Molecular weight d) Molar mass
Q.24 Material balance equation can be applied to:
a) Total mass b) Moles of component c) Mass of component d) All the these
Q.25 Concept of material balance is based upon
a) Conservation of mass
b) Conservation of Energy
c) Conservation of momentum
d) Conservation of volume
Q.26 A reaction for which heat must be removed from the system is called as
a) Exothermic reaction
b) Endothermic reaction
c) Neutral reaction
d) None
Q.27 What is the molar concentration of a solution with 40 gram of NaOH in 1 liter Solution
a) 1 mol/lit b) 2 mol/lit c) 3 mol/lit d) 4 mol/lit
Q.28 Temperature for standard heat of formation is
a) 25K b) 300K c) 298K d) 273K
Q.29 The sum of partial pressures of the components of
gas mixture's is
a) Total absolute pressure
b) Total pressure exerted by a component of a gas.
c) Total pressure of a gas mixture.
d) None of these
Q.30 Which one of correct relation.
a) Cp+Cv=0 b) Cp =1+R/Cv c) 1=Cp/Cv d) Cp=Cv+R

Very Short Answer Type

Q.1 Define heat of formation.

Q.2 Material balance is based on the principle of _________.
Q.3 The product removed from top of the distillation column is called_____.
Q.4 Define Standard heat of combustion.
Q.5 Define Normality of solution.
Q.6 Define Molarity.
Q.7 Define Molality.
Q.8 Convert 125 Pascal into Dynes/ cm
Q.9 State boyle’s law
Q.10 Calculate k moles of NaoH in 160 gram NaOH.
Q.11 State Dalton’s Law.
Q.12 Define heat of combustion.
Q.13 Expand SI
Q.14 Define Mole fraction.
Q.15 Expand STP.
Q.16 Expand NTP.
Q.17 Write one example of unit operation.
Q.18 What is energy.
Q.19 Define calorific value.
Q.20 Define combustion.
Q.21 Expand MKS.
Q.22 Define Mass fraction.
Q.23 Define Mole fraction.
Q.24 State Charle’s law.
Q.25 Convert 375 Btu/ft of into J/m2 0C
Q.26 Calculate k moles of CaCO3 into 250 gram CaCO3 Q.17 State Amagat’s law Q.18 Expand NTP
Q.27 Define heat of formation
Q.28 Convert 125 0c into 0R.
Q.29 Write full from of CGS.
Q.30 Write names of Various scales for temperature measurement.
Q.31 State Amagat's law
Q.32 Normality=______x valency
Q.33 Write SI unit of gas constant(R)
Q.34 Convert 10 newton into______dyne
Q.35 Define sensible heat.
Q.36 Define latent heat.
Q.37 Write full from of FPS.
Q.38 Write SI Unit of Pressure.
Q.39 Define Heat.
Q.40 Write SI unit of energy.

Short Answer type

Q.1 Derive the relationship between Cp and Cv .

Q.2 Write Hess’s law of constant heat summation.
Q.3 Write the steps of procedure to carry out energy balance.
Q.4 Write the steps of procedure to carry out Material balance.
Q.5 Calculate value of universal gas consultant R in J/mole k.
Q.6 How many kg of sulphur are present in 64 kg So ?
Q.7 Define standard heat of reaction.
Q.8 Define weight fraction and weight percent.
Q.9 Define theoretical air.
Q.10 Discuss Charles’Law and Amagat’s Law of gases.
Q.11 Write short note on by pass Material Balance.
Q.12 Discuss about Combustion.
Q.13 How many kg of Sulphur are present in 196 kg H2SO4?
Q.14 Define Standard heat of combustion.
Q.15 Define Mole fraction and moles percent.
Q.16 Write short note on recycle Material Balance.
Q.17 Define Normality and Molality of solution .
Q.18 Convert 275 watt/ C into K Btu/hr 0F.
Q.19 Define theoretical oxygen requirement.
Q.20 How density of gas mixture is calculated?
Q.21 Define Boyle’s law and Dalton’s law of gases.
Q.22 Write Hess’s law of constant heat summation meter exes.
Q.23 Calculate the amount of HNO3 in grams needed to 3 prepare 2 litre of 3N HNO3 solution.
Q.24 Define heat of formation and heat of rection.
Q.25 An evaporator has capacity of processing 2000kg/day of solid caustic soda. Calculate the
amount of water evaporated if it concentrates weal liquor containing 5% NaOH to 40%NaOH (by
weight).
Q.24 Prove that mole%= pressure%
Q.25 A natural gas has following composition by volume CH4 =82%, C2 H6 =12% N2 =6, Calculate
composition by weight.
Q.26 Describe the concept of by-pass system with the help of diagram.
Q.27 70 gm of NaOH dissolved in water to prepare 500 ml of solution. Find out Nomality and
molarity of solution
Q.26 Describe the concept of purge system with the help of diagram.
Q.28 What do you understand by gm mole and gm atom, explain in detail
Q.29 A solid of 80 kg contains 37% moisture find cut the water present in solid on weight basis if
solid will be dried at 10% moisture.
Q.32 How can you express the concentration of solution with the help of terms molality and
molarity.
Q.33 Define theoretical air and excess air in combustion.
Q.35 Calculate the heat to be transferred to a liquid stream of ethanol at its normal boiling point to
generate 200kg/hr of saturated ethanol vapour.
Q.36 Discuss the term Normality.
Q.37 Discuss average molecular weight of gas mixture.
Q.38 Discuss standard heat of formation.

Long Answer type

Q.1 A single effect Evaporator is fed with 10000 kg/hr of weak liquor containing 15% caustic by
weight and is concentrated to get thick liquor containing 40% by weight caustic (NaOH) Calculate (a)
kg/hr of water evaporated (b) kg/hr of thick liquor obtained.

Q.2 2500kg of wet solids containing 70% solids by weight are fed to tray dryer. Where it is dried by
hot air. The product finally obtained is found to contain 1% moisture by weight calculate.
(i) Kg of water removed from wet solids.
(ii) Kg of product obtained.

Q.3 Write short note on

a) Hess Law of contant heat summation.
b) Recycle Material Balance.

Q.4 For-Ideal Gas mixture, Prove that Moles% = volume %= Pressure %

Q.5 10000 kg/hr of solution containing 20% methanol is continuously fed to distillation column.
Distillate is found to contain 98% methanol and waste solution from the column carrues 1%
methanol. All percentage are by weight.
Calculate
a) mass flow rates of disyllable and bottom product
b) percent loss of methyl alcohol.

Q.6 For ideal gase mixture, prove that pressure % Mole%= volume%

Q.7 A solution of NaoH contains 20% NaoH by weight takeing density of solution as 1.196 kg/l..
Calculate Normality, molarity and molality of solution.
Q.8 A single effect Evaporator is fed with 10000 kg/hr of weak liquor containing 15% caustic by
weight and is concentrated to get thick liquor containing 40% by weight caustic (NaOH)
Calculate
(a) kg/hr of water evaporated
(b) kg/hr of thick liquor obtained.

Q.9 An evaporator is fed with 15000kg/hr of a solution containing 10% NaCl.15% NaOH and rest
water. In the operation water is evaporated and NaCl is precipitated as crystals. The thick liquor
leaving the evaporator contains 45% NaOH, 2% NaCl and rest water,

Calculate: a) kg/hr water evaporated,

b) kg/hr salt precipitated,

c) kg/hr thick liquor.

Q.10 Discuss the concept of material balance and write steps of procedure to carry out material
balance.