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Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
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JEE-MAIN-2023 (10th April-First Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. The range of the projectile projected at an angle of 15 with horizontal is 50m. If the projectile is
projected with same velocity at an angle of 45 with horizontal, then its range will be
(A) 50 2 m (B) 100m
(C) 50m (D) 100 2 m
a2 b3
Q2. A physical quantity P is given as P The percentage error in the measurement of a, b, c and
c d
d are 1%, 2%, 3% and 4% respectively. The percentage error in the measurement of quantity P
will be
(A) 12% (B) 16%
(C) 14% (D) 13%
Q4. An object is placed at a distance of 12cm in front of a plane mirror. The virtual and erect image is
formed by the mirror. Now the mirror is moved by 4cm towards the stationary object. The distance
by which the position of image would be shifted, will be
(A) 4cm towards mirror (B) 8cm towards mirror
(C) 2cm towards mirror (D) 8cm away from mirror
Q5. Two satellites of masses m and 3m revolve around the earth in circular orbits of radii r & 3r
respectively. The ratio of orbital speeds of the satellites respectively is
(A) 1 : 1 (B) 9 : 1
(C) 3 : 1 (D) 3 : 1
Q7. A particle executes S.H.M. of amplitude A along x-axis. At t = 0, then position of the particle
A
is x and it moves along positive x-axis. The displacement of particle in time is
2
x A sin t , then the value will be
(A) (B)
2 3
(C) (D)
6 4
Q9. A particle of mass m moving with velocity collides with a stationary particle of mass 2m. After
collision, they stick together and continue to move together with velocity
(A) (B)
2
(C) (D)
4 3
O t
(A) A lives closer to the school (B) B lives closed to the school
(C) A takes leseer time to reach home (D) A travels faster than B
(E) B travels faster than A
Choose the correct answer from the options given below :
(A) (B) and (E) only (B) (A) and (E) only
(C) (A), (C) and (D) only (D) (A), (C) and (E) only
Q11. The de Broglie wavelength of a molecule in a gas at room temperature (300 K) is 1. If the
temperature of the gas increased to 600 K, Then the de Broglie wavelength of the same gas
molecule becomes
1
(A) 1 (B) 2 1
2
1
(C) 1 (D) 21
2
JEE-MAIN-2023 (10th April-First Shift)-PCM-4
Q13. Assuming the earth to be a sphere of uniform mass density, the weight of a body at a
R
depth d from the surface of earth, If its weight on the surface of earth is 200N, will be :
2
(Given R = radius of earth)
(A) 400 N (B) 300 N
(C) 500 N (D) 100 N
Q14. A carrier wave of amplitude by a sinusoidal base band signal of amplitude 3V. The ratio of
maximum amplitude to minimum amplitude in an amplitude modulated wave is
(A) 1 (B) 5
3
(C) (D) 2
2
Q15. The energy of an electromagnetic wave contained in a small volume oscillates with
(A) Zero frequency (B) the frequency of the wave
(C) half the frequency of the wave (D) double the frequency of the wave
Q16. The angular momentum for the electron in Bohr’s orbit is L. If electron is assumed to revolve in
second orbit of hydrogen atom, then the change in angular momentum will be
L
(A) 2 L (B)
2
(C) Zero (D) L
4 4
a b
16
Q19. Consider two containers A and B containing monoatomic gases at the same pressure (P),
1
Volume (V) and Temperature (T). The gas in A is compressed isothermally to of its original
8
1
volume while the gas in B is compressed adiabatically to of its original volume. The ratio of final
8
pressure of gas in B to that of gas in A is
3
(A) 8 2 (B) 4
1
(C) 8 (D)
8
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. Three concentric spherical metallic shells X, Y and Z of radius a, b and c respectively [a < b < c ]
have surface charge densities , and , respectively. The shells X and Z are at same potential.
If the radii of X & Y are 2cm and 3cm, respectively. The radius of shell Z is _________cm.
Q2. Unpolarised light of intensity 32 Wm2 passes through the combination of three polaroids such that
the pass axis of the last Polaroid is perpendicular to that pass axis of first polaroid. If intensity of
emerging light is 3 Wm2 , then the angle between pass axis of first two polaroids is
__________ .
1
Q3. If the earth suddenly shrinks to th of its original volume with its mass remaining the same, the
64
24
period of rotation of earth becomes h. The value of x is _________.
x
Q4. A closed circular tube of average radius 15cm, whose inner walls 1kg
are rough, is kept in vertical plane. A block of mass 1kg just fit
inside the tube. The speed of block is 22 m/s, when it is introduced -1
22ms
at the top of tube. After completing five oscillations, the block stops
at the bottom region of tube. The work done by the tube on the
30cm
block is __________J. (Given g = 10 m/s2).
Q5. Two wires each of radius 0.2cm and negligible mass, one made of
steel and the other made of brass are loaded as shown in the
figure. The elongation of the steel wire is_________ 10 6 m. [ 1.6m steel
Young’s modulus for steel 2 1011 Nm2 and g 10 ms 2 2kg
1m brass
1.14kg
Q6. A transverse harmonic wave on a string is given by y x,t 5 sin 6 0.003x where x and y are
in cm and t in sec. The wave velocity is +__________ms-1.
Q7. The decay constant for a radioactive nuclide is 1.5 105 8 1 . Atomic weight of the substance is
60 g mole 1, NA 6 10 23 . The activity of 1.0 g of the substance is________ 1010 Bq.
JEE-MAIN-2023 (10th April-First Shift)-PCM-7
Q9. 10 resistors each of resistance 10 can be connected in such as to get maximum and minimum
equivalent resistance. The ratio of maximum and minimum equivalent resistance will be
_________.
Q10. The current required to be passed through a solenoid of 15cm length and 60 turns in order to
demagnetise a bar magnet of magnetic intensity 2.4 103 Am1 is _________A.
JEE-MAIN-2023 (10th April-First Shift)-PCM-8
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. Prolonged heating is avoided during the preparation of ferrous ammonium sulphate to
(A) Prevent reduction (B) Prevent hydrolysis
(C) Prevent breaking (D) Prevent oxidation
Q3. The one that does not stabilize 2o and 3o structures of proteins is
(A) Vander Waals forces (B)-O-O- linkage
(C) –S-S-linkage (D) H- bonding
Q4. The octahedral diamagnetic low spin complex among the following is
3 3
(A) CoF6 (B) Co NH3 6
2 3
(C) NiCl4 (D) CoCl6
(A) (B)
COOH COOH
HO H COCH3
HO H
H
COOH
COOH
(C) (D)
COOH COOH
COOH
COOH
Q8. The pair from the following pairs having both compounds with net non- zero dipole moment is
(A) Benzene, anisidine
(B) cis-butene, trans- butane
(C) 1,4-Dichlorobenzene, 1,3-Dichlorobenzene
(D) CH2Cl2,CHCl3
Q9. Which of the following is used as a stabilizer during the concentration of sulphide ores?
(A) Pine oils (B) Cresols
(C) Fatty acids (D) Xanthates
Q11. The enthalpy change for the adsorption process and micelle formation respectively are
(A) Hads 0 and Hmic 0 (B) Hads 0 and Hmic 0
(C) Hads 0 and Hmic 0 (D) Hads 0 and Hmic 0
Q12. Given
(A) 2CO(g) O2 (g) 2CO2 (g) H10 xkJmol1
(B) C(graphite) O2 (g) CO2 (g) H02 y kJmol1
1
The H0 for the reaction C(graphite) O2 (g) CO(g) is
2
x 2y 2x y
(A) (B)
2 2
x 2y
(C) (D) 2y x
2
JEE-MAIN-2023 (10th April-First Shift)-PCM-10
Q13. Identify the correct order of reactivity for the following pairs towards the respective mechanism
Br
Br >
(A) SN 2
Br
Br
(B) SN 1 >
Cl Cl
NO 2
Br
Br
(D) Nucleophilic substitution <
NO 2
Choose the correct from the options given below:
(A) (A), (C) and (D) only (B) (A), (B) and (D) only
(C) (A), (B), (C) and (D) only (D) (B), (C) and (D) only
Q14. Iosmeric amines with molecular formula C8H11N give the following tests
Isomer (P) Can be prepared by Gabriel phthalimide synthesis.
Isomer (Q) Reacts with Hinsberg’s reagent to give solid insoluble in NaOH
Isomer (R) Reacts with HONO followed by - naphthol in NaOH to give red dye.
Isomer (P), (Q) and (R) respectively are
Q R
P
NH2 N CH3 NH2
(A) CH3
NH2
NHCH3 N H
(B)
H
CH3
H
NH2 NH2
N
(C)
NH2 NH2
N H
(D)
CH3
CH3
JEE-MAIN-2023 (10th April-First Shift)-PCM-11
Q15. Lime reacts exothermally with water to give ‘A’ which have low solubility in water. Aqueous
solution of ‘A’ is often used for the test of CO2 , a test in which insoluble B is formed. If B is further
reacted with CO2 then soluble compound is formed ‘A’ is
(A) Slaked lime (B) Quick lime
(C) White lime (D) Lime water
Q16. Given below are two reactions, involved in the commercial production of dihydrogen (H2). The two
reaction are carried out at temperature “T1” and “T2”, respectively
T1
C(s) H2O(g) CO(g) H2 (g)
T2
CO(g) H2 O(g)
Catalyst
CO2 (g) H2 (g)
(A) T1 T2 (B) T1 T2
(C) T1 100K, T2 1270K (D) T1 T2
Q17. The number of molecules and moles in 2.8375 litre of O2 at STP respectively
(A) 1.505 1023 and 0.250 mol (B) 7.527 1022 and 0.125 mol
23
(C) 7.527 10 and 0.125 mol (D) 7.527 1022 and 0.250 mol
Q20. Using column chromatography, mixture of compounds ‘A’ and ‘B’ was separated ‘A’ eluted first,
this indicates ‘B’ has
(A) low Rf , weaker adsorption (B) high Rf stronger adsorption
(C) low Rf , stronger adsorption (D) high Rf , weaker adsorption
JEE-MAIN-2023 (10th April-First Shift)-PCM-12
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. The number of bent- shaped molecule/s from the following is__________
N3 ,NO2 ,I3 ,O3 ,SO 2
Q3. The sum of lone pairs present on the central atom of the interhalogen IF5 and IF7 is_____
Q4. The number of incorrect statement/s about the black body from the following is________
(A) Emit or absorb energy in the form of electromagnetic radiation.
(B) Frequency distribution of the emitted radiation depends on temperature.
(C) At a given temperature, intensity vs frequency curve passes through a maximum
value.
(D) The maximum of the intensity vs frequency curve is at a higher frequency at higher
temperature compared to that at lower temperature.
Q5. At constant temperature, a gas is at a pressure of 940.3 mm Hg. The pressure at which its
volume decrease by 40% is _____mm Hg (Nearest integer)
Q6. In potassium ferrocyanide, there are ________ pairs of electrons in the t2g set of orbitals.
Q7. The number of correct Statement/s involving equilibria in physical process from the following
is______________
(A) Equilibrium is possible only in a closed system at a given temperature.
(B) Both the opposing processes occur at the same rate
(C) When equilibrium is attained at a given temperature, the value of all its parameters became
equal.
(D) For dissolution of solids in liquids, the solubility is constant at a given temperature.
Q8. In the following reactions, the total number of oxygen atoms in X and Y is________
Na2 O H2 O 2X
Cl2 O7 H2 O 2Y
Q9. If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3,
then the observed freezing point will be ________% higher than the expected / theoretical
freezing point (Neatest integer)
Q10. A molecule undergoes two independent first order reactions whose respective half lives are 12
min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of
the reactant is___________ min (Nearest integer)
JEE-MAIN-2023 (10th April-First Shift)-PCM-13
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. Let the first term a and the common ratio r of a geometric progression be positive integers. If the
sum of squares of its first three terms is 33033, then the sum of these three terms is equal to
(A) 210 (B) 241
(C) 220 (D) 231
3
3
1 3
(A) e 4 (B) e 4
2
1 34 3
(C) e (D) e 4
2
Q7. A line segment AB of length moves such that the points A and B remain on the periphery of a
circle of radius . Then the locus of the point, that divides the line segment AB in the ratio 2 : 3,
is a circle of radius
19 2
(A) (B)
5 3
3 19
(C) (D)
5 7
JEE-MAIN-2023 (10th April-First Shift)-PCM-14
Q8. A square piece of tin of side 30 cm is to be made into a box without top by cutting a square from
each corner and folding up the flaps to form a box. If the volume of the box is maximum, then its
surface area (in cm2) is equal to
Q9. An arc PQ of a circle subtends a right angle at its centre O. The mid point of the arc PQ is R. If
OP u, OR v and OQ u v , then , 2 are the roots o the equation
(A) x 2 x 2 0 (B) x 2 x 2 0
(C) 3x 2 2x 1 0 (D) 3x 2 2x 1 0
x 3 y 2 1 z
Q10. Let P be the point of intersection of the line and the plane x y z 2 . If the
3 1 2
distance of the point P from the plane 3x 4y 12z 32 is q, then q and 2q are the roots of the
equation
(A) x 2 18x 72 0 (B) x 2 18x 72 0
(C) x 2 18x 72 0 (D) x 2 18x 72 0
x2 y z5 x 4 y 1 z 3
Q11. The shortest distance between the lines and is
1 2 2 1 2 0
(A) 9 (B) 6
(C) 7 (D) 8
2z 3i
Q12. Let the complex number z x iy be such that is purely imaginary. If x y 2 0 , then
2z i
y 4 y 2 y is equal to
3 2
(A) (B)
2 3
4 3
(C) (D)
3 4
Q13. Let the ellipse E : x 2 9y 2 9 intersect the positive x and y axes at the points A and B
respectively. Let the major axis of E be a diameter of the circle C. Let the line passing through A
and B meet the circle C at the point P. If the area of the triangle with vertices A, P and the origin
m
O is , where m and n are coprime, then m n is equal to
n
(A) 18 (B) 15
(C) 16 (D) 17
Q14. Let two vertices of a triangle ABC be 2, 4, 6 and 0, 2, 5 , and its centroid be 2, 1, 1 . If the
image of the third vertex in the plane x 2y 4z 11 is , , , then is equal to
(A) 76 (B) 72
(C) 74 (D) 70
13 13
1 1
Q15. If the coefficient of x 7 in ax 2 and the coefficient of x 5 in ax 2 are equal, then
bx bx
a 4b4 is equal to :
(A) 33 (B) 22
(C) 44 (D) 11
JEE-MAIN-2023 (10th April-First Shift)-PCM-15
Q17. Let O be the origin and the position vector of the point P be ˆi 2ˆj 3kˆ . If the positive vectors of
the points A, B and C are 2iˆ ˆj 3k, ˆ 2iˆ 4ˆj 2kˆ and 4iˆ 2jˆ kˆ respectively, then the
projection of the vector OP on a vector perpendicular to the vectors AB and AC is
8
(A) 3 (B)
3
7 10
(C) (D)
3 3
Q18. Let N denote the sum of the numbers obtained when two dice are rolled. If the probability that
m
2N N! is , where m and n are coprime, then 4m 3n is equal to
n
(A) 6 (B) 10
(C) 8 (D) 12
2 4 8 16
Q19. 96cos cos cos cos cos is equal to
33 33 33 33 33
(A) 2 (B) 3
(C) 1 (D) 4
x2 y2
Q20. The slope of tangent at any point x, y on a curve y y x is , x 0 . If y 2 0 , then a
2xy
value of y 8 is
(A) 4 3 (B) 2 3
(C) 4 2 (D) 2 3
JEE-MAIN-2023 (10th April-First Shift)-PCM-16
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1.
The number of elements in the set n : n2 10n 19 is……….
2
Q2. Let a common tangent to the curves y 2 4x and x 4 y 2 16 touch the curves at the points
2
P and Q. Then PQ is equal to…………
Q3. Some couples participated in a mixed doubles badminton tournament. If the number of matches
played, so that no couple played in a match, is 840, then the total numbers of persons, who
participated in the tournament is………
loge loge b
Q4. Let a, b, c be three distinct positive real numbers such that 2a bc and bloge 2 aloge c .
Then 6a 5bc is equal to………..
Q5. The number of permutations, of the digits 1, 2, 3,….., 7 without repetition, which neither contain
the string 153 nor the string 2467, is………
10
Q6. The coefficient of x 7 in 1 x 2x3 is……..
x x , 2 x 0
f x
x 1 x , 0 x 2
where x denotes the greatest integer function. If m and n respectively are the number of points
in 2, 2 at which y f x is not continuous and not differentiable, then m + n is equal to……….
Q9. The sum of all those terms, of the arithmetic progression 3, 8, 13, …., 373, which are not divisible
by 3, is equal to………..
Q10. Let y p x be the parabola passing through the points 1, 0 , 0, 1 and 1, 0 . If the area of the
region x, y : x 1 2 2
y 1 1, y p x is A, then 12 4A is equal to……….
JEE-MAIN-2023 (10th April-First Shift)-PCM-17
SECTION – B
1. 5 2. 30.60 3. 16 4. 245
5. 20 6. 20 7. 15 8. 18
9. 100 10. 6
PART – B (CHEMISTRY)
SECTION - A
1. D 2. D 3. B 4. B
5. C 6. B 7. D 8. C
9. B 10. C 11. B 12. C
13. C 14. DROP 15. A 16. B
17. B 18 C 19. C 20. C
SECTION - B
1. 3 2. 1825 3. 1 4. 0
5. 1567 6. 3 7. 3 8. 5
9. 30 10. 2
JEE-MAIN-2023 (10th April-First Shift)-PCM-18
PART – C (MATHEMATICS)
SECTION - A
1. D 2. B 3. B 4. A
5. D 6. C 7. A 8. C
9. B 10. B 11. A 12. D
13. D 14. C 15. B 16. B
17. A 18 C 19. B 20. A
SECTION - B
1. 6 2. 32 3. 16 4. DROP
5. 4898 6. 960 7. 151 8. 4
9. 9525 10. 16
JEE-MAIN-2023 (10th April-First Shift)-PCM-19
a2 b3
Sol2. P
c d
dp da db dc 1 dd
100 2 100 3 100 1 100 100
p a b c 2 d
1
2 1 3 2 1 3 4
2
2b32
13%
C
JEE-MAIN-2023 (10th April-First Shift)-PCM-20
12cm
Sol6. Current sensitivity Number of turns in the coil & voltage sensitivity Number of turns in the coil
A +A
Sol7. A sin
2
1
sin
2 A
A
2
30
6
M.P
-A
h
Sol11.
mv
JEE-MAIN-2023 (10th April-First Shift)-PCM-21
v T
1
T
1 T1 x2 T2
1 300 2 600
1
2
2
Sol12. P VI
1.6 8I
I 0.2
I Rs 2
2
Rs 10
0.2
d
Sol13. g1 g 1
R
R
g1 g 1
2 R
g
g1
2
1 mg
mg
2
200
100N
2
Sol14. A max 15 3 18
A min 15 3 12
A max 18 3
A min 12 2
nh
Sol16. L
2
h
n 1, L1
2
2h
n 2 , L2
2
Change in Angular momentum = L
JEE-MAIN-2023 (10th April-First Shift)-PCM-22
1 1 1 1
Sol17.
R 8 8 16 4 4
1 2 21
R 16
4 4 I3
16
R 3.2 I3 4
5 I2 I2
a I1 16 b
I1
4
4
4
4
a b
16
83
=4
Sol20. P VI cos
At Resonance 0
then P = Pmax
And pure Resistor , 0
then, P = Pmax
JEE-MAIN-2023 (10th April-First Shift)-PCM-23
SECTION - B
k 4 a2 k 4 b k 4 c
2 2
Sol1. VX y z
a b c
k 4 a k 4 b k 4 c x
k 4 a 2
k 4 b 2
k 4 c 2
(2cm)a (3cm)
VZ
c c c b
2 2
a k 4 b
k4 k 4 c
c c
VX Vz
c
k 4 k 4 b k 4 c
a2 4b2
k4 k k 4c
c c
a2 b 2
k 4 a k 4 b k 4 k 4
c c
a2 b2
ab
c c
b a b
a
a b
c
c ab
c 2 3 5 cm
I0
Sol2. If cos2 cos2 90 I 32 w / m2 ?
2
32 2
3 sin cos2
2 I 3 w / m2
3 16 sin2 cos 2
3 2
2sin cos
4
3
sin2
2
30
Sol3. I1 1 I2 2
I1 2 I2 2
T1 T2
T2 I2 M2 R 22 R 22
- (i)
T1 I1 M1 R12 R12
4 1 4
R 23 R13
3 64 3
1 3
R32 R1
64
R
R2 1
4
JEE-MAIN-2023 (10th April-First Shift)-PCM-24
2
T2 R 2 1
T1 R1 16
T 24
T2 1 hr
16 x
24 16 24
x 16 16
T1 24
x 16
Sol4. w tube w mg k .E
w table k.E P.E
1
m v f2 v12 mg 30 102
2
1
m 0 22 22 mg 30 102
2
1
1 22 22 mg 10 30 10 2
2
11 22 3
242 3
239 J
FL 2 10 1.6
Sol5. L steel 2
Ay 0.2 102 2 1011
2 10 1.6 2 1.6
10 6
0.04 10 4 2 1011 0.04 2
12.738 10 6
Sol7. F IB
Bv
F B
R
0.15 0.15 1 1 4
F
5
0.03 0.15 4
18 103 N
JEE-MAIN-2023 (10th April-First Shift)-PCM-25
Sol8. Activity N
1 106
1.5 106 6 1023
60
15
1011
102
15 10 9 1.5 1010 Bq
Sol10. B n 0I
60
2.4 103 4 10 7 I
15 10 2
2.4 103 15 102
I
60 4 107
2.4 15
108 4774648.29
60 4
PART – B (CHEMISTRY)
SECTION – A
Sol1. Upon prolong heating, some of the ferrous ion (Fe2+) gets oxidized into ferric ion (Fe3+)
0
Sol2. EMn3
/Mn2
1.57 V E0Fe3 /Fe2 0.77 V
M3 / M2 reduction potential for Mn is greter than that of iron.
E0Cr3 /Cr 2 0.26 V (Reduction potential negative) for chromium +3 oxidation state is more
stable than +2 oxidation state.
Cr 2 H
H2 Cr 3
V2+ has 3 unpaired electrons.
Spin only magnetic moment 3 3 2 15 BM 3.87 B.M
Sol3. Secondary and tertiary structure of protein are stabilized by hydrogen bonding, disulphide
linkages, Vander Waal’s attractional force and electrostatics force of attraction.
3
Sol4. CoF6 - Paramagnetic, high spin and octahedral
3
Co NH3 6 - Diamagnetic, low spin and octahedral
2
NiCl4 - Paramagnetic, high spin and tetrahedral
3
COCl6 - Paramagnetic, High spin and octahedral
Sol5. Williamson’s synthesis of ether is example of SN2 reaction
JEE-MAIN-2023 (10th April-First Shift)-PCM-26
Sol7. KMnO4 is strong oxidizing agent and it oxides benzylic cabon [ having at least 1-H] to COOH.
Sol8.
Benzene [Non-polar]
OCH3 OCH3
NH2
Anisidine or (Polar)
NH2
Cl
Cl
Cl
Cl
Cl
CH2Cl 2 H
C -Polar
H Cl
Cl
CHCl 3 H
C -Polar
Cl Cl
Sol10. Sodium form oxide and peroxide upon reaction with oxygen. It does not form superoxide.
JEE-MAIN-2023 (10th April-First Shift)-PCM-27
Sol11. During adsorption, attraction force gets developed between adsorbate and adsorbent surface.
Therefore this process in exothermic in nature. Micelle formation is generally an endothermic
process.
Sol13. SN2 reativity involves backside attack of nucleophile. So its rates decreases with increase
in steric hindrance. SN1 reactivity increases with increase in stability of carbocation
(intermediate formed).
Presence of electron with drawing group decrease the rate of EAS reaction. Presence of strong
electron with drawing group like NO2 of para position to halogen in aryl halide will increase rate of
nucleophilic substitution reaction (SNAr)
Sol14. Gabriel pthalamide synthesis involves SN2 reaction as a step. Therefore it is used for
formation of alipthatic primary amines only, not aromatic amines. Secondary amine reacts
with Hinsberg’s reagent to produce a solid (insoluble in NaOH solution). Aromatic primary
amine reacts with HNO2 to form diazonium salt, which forms red dye with -napthol.
1270K
Sol16. C(s) H2O(g) CO(g) H2 (g)
673 K
CO(g) H2 O(g) CO2 (g) H2 (g)
2.8375
Sol17. Number of moles of O 2 0.125 moles
22.7
Number of molecules of O 2 0.125 NA 7.525 10 22
Sol19. Steel plants produces slag from blast furnace. Thermal power plants produce fly ash.
Fertilizer industry produces gypsum. Bio-degradable wastes are generated by paper mill.
SECTION – B
Sol1. N3 Linear
NO 2 Bent shape
I
3 Linear
JEE-MAIN-2023 (10th April-First Shift)-PCM-28
O3 Bent shape
SO2 Bent shape
T2 > T1
Intensity
T1
frequency
Sol7. At equilibrium established at certain temperature. The value of all parameters becomes
constant [ Not necessarity equal ]
Sol8. Na2 O H2 O
2NaOH
Cl2O7 H2O 2HClO 4
Sol10.
(I) K1
B
A
(II) K2
C
K = K 1 + K2
n2 n2 n2
t1/ 2 t1/2 I t1/2 II
1 1 1
t1/ 2 3 12
t1/ 2 2.4 min
2 min.
PART – C (MATHEMATICS)
SECTION – A
Sol1. Let series be a, ar, ar 2 ,.... ,
now a 2 a2r 2 a2r 4 33033
a 2 1 r 2 r 4 33 1001
a2 1 r 2
r4 11 3 91 here compare (a = 11)
2
r 4 r 2 1 273
r 4 r 2 272 0
r 2 17 r 2 16 0
r 2 16
Hence sum =
a 1 r r2
111 4 16 231
ax b
f x
cx d & a d 0 , then f x f x
1
Sol2. Use If
4
f f x x f f 4 / x x
So, ,
By A.M. & G.M.
4
x
x x 4 x 4 4
So, 2 x x
f x 1
d 2 4 c
x x
f x 1
2 3 C
x 3x
2
f 1 C 1
Use 3
f 3 1 80
1
Put x 3 , 9 81 81
80
f 3 18f 3 160
9
p q q r
Sol4.
Use De-Morgan’s Law
p q q r p q q r
q p r
KA Kn A
Sol5. Use
3adj 3A A 2 3n adj 3n A A 2
n 1
adjA A
Use
n 1
3n 3n 2 A 2
n 1
3n 2 3 n
n
A
2n 2
2 3
n2 2n 2
3 n 2n n
3n A
Put n = 3
33 18 26 24
321 210
311 610
e f x g' x f ' x dx e f x C
g x g x
Sol6. Use
2
I x esin x cos
x sin2x
sin x dx
f g'
f'
2
I x e sin x
cos x C
2 1 3 /4
x 0, I 1, c 0 I x esin x cos x e
2
JEE-MAIN-2023 (10th April-First Shift)-PCM-31
25 h2 k 2 4 9 12cos cos 2 , sin 2 cos 1, sin 1
2
1 2
25 h2 k 2 19 h 2
k2
19 2
2 25
Sol8. V 30 2a a
2 a a
a a
V 4a3 120a2 900a
V ' 12a2 240a 900
30 2a
12 a2 20a 75
V ' 12 a 15 a 5
for maximum or minimum, a = 5, 15 (not
possible)
2
S 30 2a 4 30 2a a
30 2a 30 2a 4a
2
30 2 2a
900 100 800
Sol9. OP OQ 0
P u R V Q
u u v 0
u u u v 0
Equal arc subtend equal at the
center
O
between u & v is .
4
2 r 2
r 0 0
2 2
OP u r v OQ
2 2 2
OQ r r 2 2 u v 2u v
1
r 2 r 2 2 2 2
2
2
1 2 2 2
JEE-MAIN-2023 (10th April-First Shift)-PCM-32
1 , 2
Now, , 2 1, 2 or 1, 2
So equation can be x 2 3x 2 0 or
x 3 y 2
z 1
Sol10. Let
3 1 2
General pt. 3 3, 2, 2 1
It satisfies plane 3 3 2 2 1 2
3
18 4 60 32
Pt 6, 1, 5 q 6
13
So, equation with 6 & 12 is x 2 18x 72 0
cd
Sol11. Shortest distance = a2 a1
cd
a 2 a1 6iˆ ˆj 8kˆ
ˆi ˆj kˆ
c d 1 2 0 ˆi 4 ˆj 2 kˆ 4 4iˆ 2ˆj 4kˆ
1 2 2
c d 16 4 16 6
a2 a1 c d 54
So, shortest distance = 9
Sol12. 2z 3i i 2z 3i 2z i i 1
2z i 2z 3i 2z i i 1
4z 2i i 1
4i i 1
zi/ 2 i 1
i i 1
2
1
x2 y 1
2
1
x y 2 y 4 y 2 y 1
Put 4
3
y 4 y2 y
4
JEE-MAIN-2023 (10th April-First Shift)-PCM-33
x y
Sol13. Equation of AP 1
3 1
Solve with x 2 y 2 9 P
12 9 B
x ,y
5 5
A
1 9
area of OAP 3 O
2 5
m 27
n 10
So, m n 17
13
1 a13 r r
Sol15. General term of ax x 2 is Tr 1 13
Cr 1 x13 3r
b br
13 a11
For x 7 Put r 2 , so coefficient = C2
b2
13
1 2 13 a13 r 13 3r
ax x , Tr 1 Cr x
b br
13
C6 a7
For x 5 Put r = 6, so coefficient =
b6
13
C2 a11 13 C6 a7
Now,
b2 b6
13
C
a4 b4 13 6 22
C2
2 1 3
3 2 1 2 2 5 1 3 4 3 15 8 7 5
4 5
Sol16.
For infinite solution or no solution 5
5, 4, 5, 5 2, 1, 3 m 3,2, 1
4 2 3m m 2, 1
5 2m
So, 1 5 2 7 9
So, 5, 9 , infinite solution
9 , no solution
Sol17. Let n AB AC
JEE-MAIN-2023 (10th April-First Shift)-PCM-34
ˆi ˆj kˆ
AB 4iˆ 3ˆj kˆ
; n 4 3 1 5iˆ 10ˆj 10kˆ
AC 2iˆ ˆj 2kˆ 2 1 2
n 15
required OP nˆ
20 20 10
10
15 3
Sol19. Let
33
sin32 sin 33 1
cos cos 2 cos 4 cos 8 cos16
5
2 sin 32sin 32
cos cos2 cos 4 cos8 cos16
So, 96 3
33 33 33 33 33
x 2 y 2 dy
Sol20. Homogeneous form
2xy dx
dy dv
Put y v x vx
dx dx
2
1 v dv dv 1 v 2 2v 2
vx x
2v dx dx 2v
2v dv dx
1 v2 x
y2
n 1 v 2 nx n C n 1 2 n cx
x
1
x = 2, y = 0 c
2
JEE-MAIN-2023 (10th April-First Shift)-PCM-35
y2 x
n 1 2 n
x 2
1 x 2x 2 x
2
2
y 2 x y2 2
1 2
x
x 8 4 64 8 64 y 2
2
y 32 y 4 3
SECTION – B
Sol1. n2 10n 19 6
2 2
n 5 6 6 6 n 5 6 6
2
0 n 5 12
Case I n 5 Case II
2 3 n 5 2 3
52 3 n52 3
1 4 n 8 4
n 2, 3, 4, 6, 7, 8
So, number of elements = 6
1
Sol2. Let tangent for parabola be y mx m2 x my 1 0
m
4m2 1 1
Its tangent for circle also, 4 m2
2
m m 4 8
a 2a
Pt. of contact on parabola, at 2 , 2at 2 ,
m m
8, 4 2
For PQ S1 , with respect to circle
2
8 4
2
4 2 16
PQ 2 32
n
Sol3. C 2 n 2 C 2 2 84
n n 1 n 2 n 3 2 840
2 2
n n 1 n 2 n 3 1680 5 6 7 8
n8
n
C2 select two gents from n men
From remaining n – 2 couples, select 2 ladies, they can be arranged in two ways.
So, total person’s participated = 16
JEE-MAIN-2023 (10th April-First Shift)-PCM-36
109e a 109e b
2a bc bloge 2 aloge c
Sol4. na n2 na nb nb nc ........(i) n2 nb nc na........(ii)
2 2
na nb nb nc na n2
2
n2 nb
na n2
na
2 2
n2 nb na
na nb na nb
na
n2
1
na
1
na 2 1 a
2
1
In equation put a , n2 nb nc n2
2
n bc 0
bc 1
b c
2 5 3 15 x 25 5 35 4 45
Sol7. 28
14 x
x6
2
fi xi2 fi xi
Now variance =
fi fi
fi xi2
282
20
fi x i2 2 52 3 15 2 6 25 2 5 35 2 4 45 2
JEE-MAIN-2023 (10th April-First Shift)-PCM-37
2x ; 2 x 1
x ; 1 x 0
Sol8. f x
0 ; 0 x 1
x 1; 1 x 2
Discontinuous, m = 1
non differentiability, n = 3
Sol9. Series = 3, 8, 13, 18, 23, 28, 33, 38, 43
Terms, 373 3 n 1 5 n 75 ,
So 50 terms are not divisible by 3
So, sum of terms not divisible by 3
8 13
23 28
38 43 .....
25
21 51 81 ..... 2 21 25 1 30 9525
2
1 1 1
sin 1
3 2
1
A
3 4
1
Now, 12 4A 12 48 16
3 4