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Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
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JEE-MAIN-2022 (25th July-First Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. If momentum [P], area [A] and time [T] are taken as fundamental quantities, then the dimensional
formula for coefficient of viscosity is :
(A) P A 1 T 0 (B) P A T 1
(C) P A 1 T (D) P A 1 T 1
Q2. Which of the following physical quantities have the same dimensions ?
(A) Electric displacement D and surface charge density
(B) Displacement current and electric filed
(C) Current density and surface charge density
(D) Electric potential and energy
Q4.
A body of mass 0.5 kg travels on straight line path velocity u 3x3 4 m / s. The net work done
by the force during its displacement from x 0 to x 2m is :
(A) 64 J (B) 60 J
(C) 120 J (D) 128 J
Q5. A solid cylinder and a solid sphere, having same mass M and radius R, roll down the same
inclined plane from top without slipping. They start from rest. The ratio of velocity of the solid
cylinder to that of the solid sphere, with which they the ground, will be :
5 4
(A) (B)
3 5
3 14
(C) (D)
5 15
Q6. Three identical particles A,B and C of mass 100 kg each are placed in a straight line with
AB BC 13m. The gravitational force on a fourth particle P of the same mass is F, when placed
at a distance 13 m from the particle B on the perpendicular bisector of the line AC. The value of F
will be approximately :
(A) 21 G (B) 100 G
(C) 59 G (D) 42 G
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JEE-MAIN-2022 (25th July-First Shift)-PCM-3
Q7. A certain amount of gas of volume V at 27 C temperature and pressure 2 107 Nm2 expands
isothermally until its volume gets doubled. Later it expands adiabatically until its volume gets
redoubled. The final pressure of the gas will be
(Use 1.5 ) :
(A) 3.536 105 Pa (B) 3.536 106 Pa
(C) 1.25 106 Pa (D) 1.25 105 Pa
Q10. A condenser of 2 F capacitance is charged steadily from 0 to 5 C. Which of the following graph
represents correctly the variation of potential difference (V) across it’s plates with respect to the
charge (Q) on the condenser?
5 5
6
V(x10 V) V(x106 V)
(A) 2.5 (B) 2.5
0 0 5
5 Q(C) Q(C)
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JEE-MAIN-2022 (25th July-First Shift)-PCM-4
5 5
6 6
V(x10 V) V(x10 V)
(C) 2.5 (D) 2.5
0 5 0 5
Q(C) Q(C)
Q11. Two charged particles, having same kinetic energy, are allowed to pass through a uniform
magnetic field perpendicular to the direction of motion. If the ratio of radii of their circular paths is
6 : 5 and their respective masses ratio is 9 : 4. Then, the ratio of their charges will be :
(A) 8 : 5 (B) 5 : 4
(C) 5 : 3 (D) 8 : 7
Q14. The rms value of conduction current in a parallel plate capacitor is 6.9 A. The capacity of this
capacitor, if it is connected to 203 V ac supply with an angular frequency of 600 rad / s, will be:
(A) 5 pF (B) 50 pF
(C) 100 pF (D) 200 pF
Q16. Time taken by light to travel in two different materials A and B refractive indices A and B of
same thickness is t1 and t 2 respectively. If t 2 t1 5 1010 s and the ratio of A to B is 1 : 2.
Then, the thickness of material, in meter is : (Given A and B are velocities of light in A and B
materials respectively.)
(A) 5 1010 A m (B) 5 1010 m
(C) 1.5 10 10 m (D) 5 1010 B m
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JEE-MAIN-2022 (25th July-First Shift)-PCM-5
Q17. A metal exposed to light of wavelength 800 nm and and emits photoelectrons with a certain
kinetic energy. The maximum kinetic energy of photo-electron doubles when light of wavelength
500 nm is used. The work function of the metal is : (Take hc = 1230 eV -nm).
(A) 1.537 eV (B) 2.46 eV
(C) 0.615 eV (D) 1.23 eV
th
Q18. The momentum of an electron revolving in n orbit is given by :
(Symbols have their usual meanings)
nh nh
(A) (B)
2r 2r
nh 2r
(C) (D)
2 nh
Q19. The magnetic moment of an electron (e) revolving in an orbit around nucleus with an orbital
angular momentum is given by :
eL eL
(A) L (B) L
2m m
eL 2 eL
(C) (D)
m m
5V
V=0
A B Y A B Y
0 0 0 0 0 0
1 0 0 1 0 1
(A) (B)
0 1 0 0 1 1
1 1 1 1 1 1
A B Y A B Y
0 0 0 0 0 1
(C) 1 0 0 (D) 1 0 1
0 1 0 0 1 1
1 1 0 1 1 0
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JEE-MAIN-2022 (25th July-First Shift)-PCM-6
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. A car is moving with speed of 150 km/h and after applying the break it will move 27m before it
stops. If the same car is moving with a speed of one third the reported speed then it will stop after
travelling __________ m distance.
45 45
45
P F1
90
F2
Q3. A wire of length L and radius r is clamped rigidly at one end. When the other end of the wire is
pulled by a force F, its length increases by 5cm. Another wire of the same material of length 4L
and radius 4r pulled by a force 4F under same conditions. The increase in length of this wire is
_________ cm.
Q4. A unit scale is to be prepared whose length does not change with temperature and remains
20cm, using a bimetallic strip made of bass and iron each of different length. The length of both
components would change in such a way that difference between their length remains constant. If
length of brass is 40 cm and length of iron will be ________ cm.
( iron 1.2 105 K 1 and brass 1.8 105 K 1 ).
Q5. An observer is riding on a bicycle and moving towards a hill at 18 kmh-1. He hears a sound from a
source at some distance behind him directly as well as after its reflection from the hill. If the
original frequency of the sound as emitted by source is 640 Hz and velocity of the sound in air is
320 m/s, the beat frequency between the two sounds heard by observer will be _______ Hz.
Q6. The volume charge density of a sphere of radius 6m is 2 C cm 3 . The number of lines of force
per unit surface area coming out from the surface of the sphere is _________ 1010 NC1.
[Given : Permittivity of vacuum 0 8.85 1012 C2 N1 m2 ]
4V 1k
6V 1k
V0
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JEE-MAIN-2022 (25th July-First Shift)-PCM-7
Q8. Eight copper wire of length and diameter d are joined in parallel to from a single composite
conductor of resistance R. If a single copper wire of length 2 have the same resistance (R) then
its diameter will be ________d.
Q9. The energy band gap of semiconducting material to produce violet (wavelength 4000 A )
LED is _______ eV. (Round off to the nearest integer).
Q10. The required height of a TV tower which can cover the population of 6.03 lakh is h. If the average
population density is 100 per square km and the radius of earth is 6400 km, then the value of h
will be _________ m.
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JEE-MAIN-2022 (25th July-First Shift)-PCM-8
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. SO2Cl2 on reaction with excess of water results into acidic mixture
SO2Cl2 + 2H2O H2SO4 + 2HCl
16 moles of NaOH is required for the complete neutralisation of the resultant acidic mixture. The
number of moles of SO2Cl2 used is:
(A) 16 (B) 8
(C) 4 (D) 2
Q3. The depression in freezing point observed for a formic acid solution of concentration 0.5 mL L1 is
0.0405oC. Density of formic acid is 1.05 g mL1. The Van’t Hoff factor of the formic acid solution is
nearly: (Given for water Kf = 1.86 k kg mol1)
(A) 0.8 (B) 1.1
(C) 1.9 (D) 2.4
Q4. 20 mL of 0.1 M NH4OH is mixed with 40 mL of 0.05 M HCl. The pH of the mixture is nearest to:
(Given K b NH4 OH 1 10 5 ,log2 0.30,log3 0.48,log5 0.69,log7 0.84,log11 1.04
(A) 3.2 (B) 4.2
(C) 5.2 (D) 6.2
Q6. The IUPAC nomenclature of an element with electronic configuration [Rn] 5f146d17s2 is:
(A) Unnilbium (B) Unnilunium
(C) Unnilquandium (D) Unniltrium
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JEE-MAIN-2022 (25th July-First Shift)-PCM-9
Q7. The compound(s) that is (are) removed as slag during the extraction of copper is:
(A) CaO
(B) FeO
(C) Al2O3
(D) ZnO
(E) NiO
Choose the correct answer from the options given below.
(A) (C), (D) only (B) (A), (B), (E) only
(C) (A), (B) only (D) (B) only
Q8. The reaction of H2O2 with potassium permanganate in acidic medium leads to the formation of
mainly.
(A) Mn2+ (B) Mn4+
3+ 6+
(C) Mn (D) Mn
Q10. The geometry around boron in the product ‘B’ formed from the following reaction is
450K
BF3 NaH A NaF
A NMe3 B
(A) Trigonal planar (B) Tetrahedral
(C) Pyramidal (D) Square planar
Q11. The interhalogen compound formed from the reaction of bromine with excess of fluorine is:
(A) Hypohalite (B) Halate
(C) Perhalate (D) Halite
Q13. A compound ‘A’ on reaction ‘X’ and ‘Y’ produces the same major product but different by product
‘a’ and ‘b’. Oxidation of ‘a’ gives a substance produced by ants.
CH3 CH3
X
a + O C CH2 C CH3
CH3 CH3
CH3
H2C C CH2 C CH3
CH3 CH3
CH3 Y
b + O C CH2 C CH3
Compound 'A'
CH3
‘X’ and ‘Y’ respectively are
+ +
(A) KMnO4 / H and dil. KMnO4, 273 K (B) KMnO4 (dilute), 273 K and KMnO4 / H
+ +
(C) KMnO4 / H and O3, H2O / Zn (D) O3, H2O / Zn and KMnO4 / H
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JEE-MAIN-2022 (25th July-First Shift)-PCM-10
(A) (B)
CN CN
(C) (D)
Q15. Which one of the following reactions does not represent correct combination of substrate and
product under the given condition?
O
O
Cl
(A) H2 H
Pd. BaSO4
O
CN
(i) DIBAL-H
H
(B) (ii) H2O
O
CO 2C2H5
(i) AlH (iso Bu)2 H
(C) (ii) H2O
OH (i) NA2Cr2O7 H
(D)
(ii) H2SO4, H2O
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JEE-MAIN-2022 (25th July-First Shift)-PCM-11
Q16. An organic compound ‘A’ on reaction with NH3 followed by heating gives compound B. Which on
further strong heating gives compound C(C8H5NO2). Compound C on sequential reaction with
ethanolic KOH, alkyl chloride and hydrolysis with alkali gives a primary amine. The compound A
is:
CHO CHO
(A) (B)
CHO COOH
COOH CHO
(C) (D)
COOH OH
(A) N N (B) N N
NH2 NH2
H2N NH2 NH2
+ +
(C) (D) N
NH2 NH2
Q18. During the denaturation of proteins, which of these structure will remain intact?
(A) Primary (B) Secondary
(C) Tertiary (D) Quaternary
Q19. Drugs used to bind to receptors inhibiting its natural function and blocking a message are
called :
(A) Agonists (B) Antagonists
(C) Allosterists (D) Anti histaminists
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JEE-MAIN-2022 (25th July-First Shift)-PCM-12
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q2. The enthalpy of combustion of propane, graphite and dihydrogen at 298 K are -2220.0 kJ
mol1, 393.5kJ mol1 and 285.8kJ mol1 respectively. The magnitude of the enthalpy of
formation of propane C3H8 is __________ kJ mol1 (Nearest integer)
Q3. The pressure of a moist gas at 27oC is 4 atm. The volume of the container is doubled at the same
temperature. The new pressure of the moist gas is_____________101atm. (Nearest integer)
(Given: The vapour pressure of water at 27oC is 0.4 atm)
Q4. The cell potential for Zn| Zn2 (aq) || Snx | Sn is 0.801 V at 298 K. The reaction quotient of the
above reaction is 102. The number of electrons involved in the given electrochemical cell
reaction is___________________.
2.303RT
(Given: E oZn2 |Zn 0.763 V, E Sn
o
x
|Sn
0.008V and 0.06V )
F
Q5. The half life for the decomposition of gaseous compound A is 240s when the gaseous pressure
was 500 Torr initially, When the pressure was 250 Torr, the half life was found to be 4.0 min. The
order of the reaction is ____________. (Nearest integer)
Q7. Among Co3+, Ti2+, V2+ and Cr2+ ions, one if used as a reagent cannot liberate H2 from dilute
mineral acid solution, its spin-only magnetic moment in gaseous state is ___________B.M.
(Nearest integer)
Q8. While estimating the nitrogen present in an organic compound by Kjeldahl’s method, the
ammonia evolved from 0.25 g of the compound neutralized 2.5 mL of M H2SO4. The
percentage of nitrogen present in organic compound is____________.
Q9. The number of sp3 hybridised carbons in an acyclic neutral compound with molecular formula
C4H5N is__________________.
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JEE-MAIN-2022 (25th July-First Shift)-PCM-13
CH2 C CH3
O
(Where Et is C2H5)
The number of chiral carbon / s in product A is_____________.
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JEE-MAIN-2022 (25th July-First Shift)-PCM-14
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. The total number of functions, f : 1, 2, 3, 4 1, 2, 3, 4, 5, 6 such that f 1 f 2 f 3 , is equal
to :
(A) 60 (B) 90
(C) 108 (D) 126
Q2. If , , , are the roots of the equation x 4 x 3 x 2 x 1 0 , then 2021 2021 2021 2021 is
equal to :
(A) -4 (B) -1
(C) 1 (D) 4
n 1
Q3. For n N , let Sn z C : z 3 2i and Tn z C : z 2 3i . Then the number of
4 n
elements in the set n N : Sn Tn is :
(A) 0 (B) 2
(C) 3 (D) 4
Q5. If lim
n
n2 n 1 n 0 , then 8 is equal to :
(A) 4 (B) -8
(C) -4 (D) 8
4x 3
12x 2 180 x 31
Q6. If the absolute maximum value of the function f x x 2 2x 7 e in the interval
3, 0 is f , then :
(A) 0 (B) 3
(C) 1, 0 (D) 3, 1
Q7. The curve y x ax 3 bx 2 cx 5 touches the x-axis at the point P 2, 0 and cuts the y-axis
at the point Q, where y' is equal to 3. Then the local maximum value of y(x) is :
27 29
(A) (B)
4 4
37 9
(C) (D)
4 2
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JEE-MAIN-2022 (25th July-First Shift)-PCM-15
Q9. For any real number x, let [x] denote the largest integer less than equal to x. Let f be a real valued
x x , if x is odd
function defined on the interval 10, 10 by f x . Then the value of
1 x x, if x is even
10
2
f x cos x dx is :
10 10
(A) 4 (B) 2
(C) 1 (D) 0
2e2x 6e x 9
Q10. The slope of the tangent to a curve C : y y x at any point x,y on it is . If C
2 9e 2x
1 1 2
passes through the points 0, and , 2 e , then e is equal to :
2 2 2
3 2 3 3 2
(A) (B)
3 2 2 3 2
1 2 1 2 1
(C) (D)
2 2 1 2 1
Q11.
The general solution of the differential equation x y 2 dx y 5x y 2 dy 0 is :
4 3 4 3
(A) y 2 x
C y 2 2x
(B) y 2 2x
C y2 x
3 4 3 4
(C) y 2
x
C 2y2 x (D) y 2
2x
C 2y 2 x
Q12. A line, with the slope greater than one, passes through the point A(4, 3) and intersects the line x –
29
y – 2 = 0 at the point B. If the length of the line segment AB is , then B also lies on the line :
3
(A) 2x + y = 9 (B) 3x – 2y = 7
(C) x + 2y = 6 (D) 2x – 3y = 3
2
Q13. Let the locus of the centre , , 0 , of the circle which touches the circle x 2 y 1 1
externally and also touches the x-axis be L. Then the area bounded by L and the line y = 4 is :
32 2 40 2
(A) (B)
3 3
64 32
(C) (D)
3 3
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JEE-MAIN-2022 (25th July-First Shift)-PCM-16
(C) 10 3 1 m
(D) 10 2 3 1 m
Q20. Which of the following statements is a tautology?
(A) p q p (B) p p q
(C) p q q (D) q p q
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JEE-MAIN-2022 (25th July-First Shift)-PCM-17
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
2 1 1
3 i 1
Q1. Let A 1 0 1 and B A I . If , then the number of elements in the set
1 1 0 2
n 1,2,...,100 : A n n
B A B is equal to……..
Q2. The letters of the word ‘MANKIND’ are written in all possible orders and arranged in serial order
as in an English dictionary. Then the serial number of the word ‘MANKIND’ is………
1 15
1
Q3. If the maximum value of the term independent of t in the expansion of t 2 x 5
1 x 10
t ,x 0,
is K, then 8 K is equal to………….
Q4. Let a, b be two non-zero real numbers. If p and r are the roots of the equation
x 2 8ax 2a 0 and q and s are the roots of the equation x 2 12bx 6b 0 , such that
1 1 1 1
, , , are in A.P., then a 1 b1 is equal to……….
p q r s
15
Q5. Let a1 b1 1, an an 1 2 and bn an bn 1 for every natural number n 2 . Then a . b
n 1
n n is
equal to……….
4x 2 8x 5 , if 8x 2 6x 1 0
Q6. Let f x , where denotes the greatest integer less than or
2 2
4x 8x 5 , if 8x 6x 1 0
equal to . Then the number of points in R where f is not differentiable is………….
k 1
n 1 nk 1 nk 2 .... nk n
Q7. If lim
n nk 1
1
33 . lim k 1 . 1k 2k 3k .... nk , then the integral value of k is equal to…………
n n
Q8. Let the equation of two diameters of a circle x 2 y 2 2x 2fy 1 0 be 2px y 1 and
2x py 4p . Then the slope m 0, of the tangent to the hyperbola 3x 2 y 2 3 passing
through the centre of the circle is equal to……..
Q9. The sum of diameters of the circles that touch (i) the parabola 75x 2 64 5y 3 at the point
8 6
5 , 5 and (ii), the y-axis, is equal to……..
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JEE-MAIN-2022 (25th July-First Shift)-PCM-18
x 2 y 1 z x 3 y 5 z 1
Q10. The line of shortest distance between the lines and makes
0 1 1 2 2 1
2
an angle of cos 1 with the plane P : ax y z 0, a 0 . If the image of the point
27
1, 1, 5 in the plane P is ,, , then is equal to……….
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JEE-MAIN-2022 (25th July-First Shift)-PCM-19
FIITJEE
KEYS to JEE (Main)-2022
PART – A (PHYSICS)
SECTION - A
1. A 2. A 3. B 4. B
5. D 6. B 7. B 8. A
9. A 10. A 11. B 12. C
13. C 14. B 15. A 16. A
17. C 18. A 19. B 20. A
SECTION - B
1. 3 2. 3 3. 5 4. 60
5. 20 6. 45 7. 4 8. 4
9. 3 10. 150
PART – B (CHEMISTRY)
SECTION – A
1. C 2. C 3. C 4. C
5. C 6. D 7. D 8. A
9. A 10. B 11. B 12. C
13. D 14. B 15. D 16. C
17. A 18 A 19. B 20. C
SECTION - B
1. 2 2. 104 3. 22 4. 4
5. 1 6. 0 7. 5 8. 56
9. 1 10. 2
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JEE-MAIN-2022 (25th July-First Shift)-PCM-20
PART – C (MATHEMATICS)
SECTION - A
1. B 2. B 3. DROP 4. B
5. C 6. B 7. A 8. B
9. A 10. B 11. A 12. C
13. C 14. C 15. C 16. C
17. A 18. C 19. A 20. D
SECTION - B
1. 17 2. 1492 3. 6006 4. 38
5. 27560 6. 3 7. 5 8. 2
9. 10 10. DROP
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JEE-MAIN-2022 (25th July-First Shift)-PCM-21
FIITJEE
Solutions to JEE (Main)-2022
PART – A (PHYSICS)
SECTION - A
Sol1. Viscosity = Pascal .Second
P X A Y T Z M1 L1 T 1
x y Z
M1 L1 T 1 L2 T1 M1 L1 T 1
Mx Lx 2y T x z M1 L1 T 1
x 1 , x 2y 1, x z 1
y 1 , Z=0
Viscosity = P1A 1 T 0
D
Electric displacement ( D ) and surface change density
Sol3. d R
3
60 R
4
60 4 80
R m
3
Displacement = R 2 R2 2R2 cos135
2R2 2R2 0.7
3.4R2
2
80
3.4
4
47m
2
Sol4. v i 3 0 4 4m / s
vF 3 22 4 16m / s
1
k m v F2 v i2
2
1 240
0.5 162 42 60 J
2 4
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JEE-MAIN-2022 (25th July-First Shift)-PCM-22
2 gH
Sol5. v
1 k 2 / R2
VCylinedr 1 k 2
/ R2
Sphere
VSphere 1 k 2
/ R2
Cylinder
1 2 / 5 14
1 1/ 2 15
Sol7. P1 2 107 Pa
P1v1 P2 v 2
P1
Since v 2 2v1 Hence P2 (Isothermal Expansion)
2
P2 1 107 Pa
y y
P2 v 2 P3 2v 2
1 107
P3 3.536 106 Pa
21.5
3
Sol8. KEavg KT
2
1 2
P Vrms
3
3m
Sol9. T1 2
2k
m
T2 2
3k
3m
2
T1 2k 3
T2 m 2
2
3k
Sol10. Q = CV
Q
V
C
1
Straight line with slope
C
1 1
Slope = 5 105
C 2 10 6
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JEE-MAIN-2022 (25th July-First Shift)-PCM-23
2mk
Sol11. Radius of circular path R
qB
2mk
q
RB
q1 m1 R 2 9 5 5
q2 m2 R1 4 6 4
1
Sol12. f
2 LC
1
f
C
Another capacitor should be added in series with the first capacitor.
V
Sol14. Current in capacitor I
XC
I v c
I 6.9 106
C 50pF
v 230 600
A C / v A vB 1
Sol16.
B C / v B v A 2
Let the thickness is d
d d
5 10 10
vB v A
5 1010 v A v B
d
v A vB
As VA 2vB d 5 10 10 2vB
or, d 5 10 10 v A
1230
Sol17. K E1 - (i)
800
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JEE-MAIN-2022 (25th July-First Shift)-PCM-24
1230
K E 2 2K E1 -(ii)
500
from (i) & (2)
1230 1230
0
500 400
0.615 ev
nh
Sol18. mvr
2
nh
So momentum (mv)
2 r
e
Sol19. L
2m
Sol20. When both A and B have logical value ‘ I ’ both diode are revere bias and current will flow in
resistor hence output will be 5 volt i.e logical value ‘ 1 ’.
In all other case conduction will take place hence output will be zero value i.e logical value ‘o’.
So truth table is
A B Y
0 0 0
0 1 0 (AND gate)
1 0 0
1 1 1
SECTION - B
2
v
Sol1. Stopping distance d
2a
1
If speed is made rd
3
d 27
d1 , d1 3m
9 9
Braking Acceleration Remains same.
3
Sol2. F2 1cos 45 2cos 45 3cos 45 N 2N
1N
2
F1 1cos 45 2 sin 45 45 45
1 45 F1
F1 1sin 45 N
2
F1
1: 3
F2
x=3
F2
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JEE-MAIN-2022 (25th July-First Shift)-PCM-25
FL FL
Sol3. L1 2 5cm
AY r Y
4F 4L FL
L 2 2
2 5cm
16r Y r Y
Sol4. B 1 B T i 1 i T B i
B B i i
1.8 10 5 40 i 1.2 10 5
1.8 105 40 3 40
i 60
1.2 10 5 2
i 60cm
Sol5. v S 0, v Ob 5m / s Reflected
Sol6. No. of electric field line per unit area = electric field
r
E for r = R
3 0
R 26
E 0.45 1012 NC1
3 0 3 8.85 1012
E 45 1010 N / C
Sol7. K V L Loop 1 2v
6 I 1 I1 1 4 0 1k
I - I1 I – I1
2 I I1 - (i) Loop 2 I1
4v
K V L Loop 2 1k
I1 I
4 I1 1 I I1 1 2 0 Loop1
2 I1 I 0 A 1k v0
6v
2 2I1 I 0
I 2 2I1 - (ii)
from (i) & (ii)
2 2 2I1 I1 I 2A
3I1 0 VA 6 I 1 v 0
0 6 2 v0
I1 0 v0 4
4
Sol8. Each wile has resistance r
d2
Eight wire in parallel, then equivalent resistance is
r
8 2d2
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JEE-MAIN-2022 (25th July-First Shift)-PCM-26
hc 1242 1242
Sol9. Eg 3.105
nm 400
Sol10. d 2Rh
d 2 6400 h 103 (h in m)
Area = d2
2 6400 h 10 3 km2
6.03 100000 100 2 6400 10 3 h
6.03 105
h
10 128
h 150m
PART – B (CHEMISTRY)
SECTION – A
Sol1. SO2Cl2 + 2H2O H2SO4 + 2HCl
Let a moles of SO2Cl2 is taken
Then no. of moles of H2SO4 = a moles
No. of moles of HCl = 2a moles
No. of moles of NaOH required = 2a + 2a = 4a = 16
a = 4 moles
2 1
Sol4. NH4Cl 60 30 M
1 1
pH 7 PK b logC
2 2
5 1 1
7 log 5.24
2 2 30
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JEE-MAIN-2022 (25th July-First Shift)-PCM-27
Sol9. Density of metal a very specific and depends upon many factors.
Li 0.53 gm / cm3
0.97 gm / cm3
Na
K 0.86 gm / cm3
1.53 gm / cm3
Rb
Cs 1.90 gm / cm3
Sol14.
OH
OTs CN
TSCl NaCN
Pyridine DMF
Sol15.
O
CH2OH C OH
(I) Na2Cr2O7
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JEE-MAIN-2022 (25th July-First Shift)-PCM-28
Sol16.
O O O
C OH C C
NH3 KOH R X
NH NK
C OH C C
O O O
O O
C O Na C
NaOH
RNH2 N R
C
C O Na
O
O
Sol17. Melamine + formaldehyde Melamine formaldehyde polymer
(Melamac)
Sol18. During denaturation of protein, 1o structure remains the same, whereas 2o and 3o structure get
destroyed.
KHSO 4
Sol20. Glycerol Acrolein
Pungest,suffocating odour
SECTION - B
Sol1. In N2 & O22 no. of unpaired electron 0
In other species no. of unpaired electron 0
Cathode: Sn xe Sn 2
x
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JEE-MAIN-2022 (25th July-First Shift)-PCM-29
0 0.06
Ecell Ecell logQ
2x
0.06
0.801 0.771 log102
2x
x2
No. of electron involved = 4
1 n
t1/2 I P
Sol5. I n 1
t1/2 II PII
Sol6. Complex absorbing minimum wavelength of light means the value of for it is maximum.
3
That complex will be Co CN6
Co3 3d6 4s0 t 2 g6 eg0
No. of unpaired electron = 0
Sol7. Co3 will not get oxidized, so will not liberate H2 gas upon reaction with acidic solution.
3+ 6 0
Co 3d 4s
No. of unpaired electron = 4
Spin only magnetic moment = 4 4 2 BM 24 BM 5BM
5 1
Sol9. Degree of unsaturation = 4 1 3
2
CH 3 CH CH C N
3
sp hybridized only one carbon
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JEE-MAIN-2022 (25th July-First Shift)-PCM-30
PART – C (MATHEMATICS)
SECTION – A
Sol1. Case 1 : If f 3 3 then f 1 and f 2 take 1 OR 2
No. of ways = 2.6 = 12
Case 2 : If f 3 5 then f 1 and f 2 take 2 OR 3
OR 1 and 4
No. of ways = 2.6.2 = 24
Similarly for all other cases.
Total no. of ways 90.
Sol2. From properties of nth root of unity
12021 2021 2021 2021 2021 0
2021 2021 2021 2021 1
n
Sol3. Sn z C : z 3 2i
4
represents a circle with centre C1 3, 2 and radius
n
r1
4
Similarly Tn represents circle with centre C2 2, 3 and radius
1
r2
n
As Sn Tn
C1C2 r1 r2 OR C1C2 r1 r2
n 1
2
4 n
OR
n 1
2
4 n
n take infinite values.
3 sin3 1 1
Sol4. 3cos 2 4 3
6 7 7
3 sin3 28 21 21cos2 18 1 21cos2 24
21sin3 42cos 2 42
For no solution
sin3 2cos 2 2
sin3 4 sin3 4 sin2
sin 3 4 sin 4 sin2 0
1
sin 0 OR sin
2
5 13 17
, 2, 3, , , ,
6 6 6 6
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JEE-MAIN-2022 (25th July-First Shift)-PCM-31
Sol5. lim
n n2 n 1 n 0
1 1
lim n 1 2 0
n
n n n
1
Now,
1
1 1 2
lim n 1 2 1 0
n n
n n
1 1 1
1 2 .... 1
2 n n n
lim n 0
n 1
n
1
0
2
1
2
1
Now, 8 8 4
2
Sol6. Given,
4x 3
12 x2 180 x 31
f x x 2 2x 7 e
f
2 x
f1 x
f1 x x 2x 7
2
f1' x 2x 2
So f x is decreasing in 3, 0
and positive also
3
12x 2 180 x 31
f2 x e4 x
3
f2' x e4 x 12x 18 x 31
12x 2 24x 180
3
12x 2 180x 31
12 x 5 x 3 e 4 x
So, f2 x is also decreasing and positive in 3, 0
absolute maximum value of f x occurs at x = -3
3
Sol7. f x y ax 3 bx 2 cx 5 ………….(i)
dy
3ax 2 2bx c ………….(ii)
dx
Touches x-axis at P 2, 0
y x 2 0 8a 4b 2c 5 0 ………..(iii)
Touches x-axis at P 2, 0 also implies
dy
x 2 0 12a 4b c 0 …………(iv)
dx
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JEE-MAIN-2022 (25th July-First Shift)-PCM-32
Sol8. A x, y : x 2
y min x 2, 4 3x
y=4-3x
2
y=x+2 C y=x
1 5
A(-1,1) 2,2 B(1,1)
x 2 x dx 4 3x x dx
2 2
A
1 1
2
1
1
x2 x3 2 3x 2 x 3
2x 4x
2 3 2 3
1 1 1 1 3 1 3 1 17
1 2 4 2
8 24 2 3 2 3 8 24 6
x x if x is odd
Sol9. f x
1 x x, if x is even
Graph of f x
y
1
x
-2 -1 0 1 2 3
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JEE-MAIN-2022 (25th July-First Shift)-PCM-33
So,
10 1
2 2
f x cos dx 20 0 f x cos x dx
10 10 10
1
2 2 1 x cos x dx
0
1
sin x 1 cos x
22 1 x 4
0 2 0
dy 2e2x 6e x 9 2x 6e x
Sol10. e
dx 2 9e 2x 2 9e 2x
2x e z
dy e dx 3 3e x dx
1
2
put e x t
e2 x dt
3 2
2 3t
1
2
e2 x 3t
2 tan1 C
2 2
e 2x 3e x
y 2 tan1 C
2 2
It is given that the curve passes through
1
0,
2 2 2
1 1 3
2 tan1 C
2 2 2 2 2
3
C 2 tan1
2 2 2
1
Now if , e2
2
satisfies the curve, then
1 2 e 2 3e 3
e 2 tan1 2 tan1
2 2 2 2 2 2
3 1 3e 1
tan1 tan
2 2 2 2 2 4
3 3e
2 2
1
9
1 e
2
3 3 9
e e
2 2 2
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JEE-MAIN-2022 (25th July-First Shift)-PCM-34
9 3
2 2 3 3 2
e
3
1 2 3 2
2
Sol11. x y dx y 5x y dy 0
2 2
dy y2 x
y
dx 5x y 2
Let y 2 t
1 dt tx
2 dx 5x t
Now substitute, t vx
dt dv
vx
dx dx
1 dv v 1
v x
2 dx 5 v
dv 2v 2 3v v 2 2
x v
dx 5v 5v
5v dx
v 2 3v 2 dv x
4 3 dx
v 1 dv v 2 dv x
4In v 1 3In v 2 In x In C
4
v 1
C
3
v 2 x
4
y2
1
x C
3
y 2
x
2
x
4 3
y 2
x
C y 2 2x
Sol12.
y A (4,3)
x-y-2=0
B
x
(2,0)
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JEE-MAIN-2022 (25th July-First Shift)-PCM-35
Sol13.
S
S1 (,)
(0,1)
y=4
4
The area of shaded region = 2 2 ydy
0
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JEE-MAIN-2022 (25th July-First Shift)-PCM-36
4
3
y2
4
3
2 0
64
square units.
3
Sol15.
A
c b
B C
a
a b c 0 …….(i)
then
a c b
then
a c b b b
a b c b 0 ……….(ii)
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JEE-MAIN-2022 (25th July-First Shift)-PCM-37
Now S1 : a b c b c 6 2 2 1
a c b c 6 2 2 1
c 6 12 2 (not possible)
Hence (S1) is not correct
For
(S2) : from (i)
b c a
b b c b a b
12 12 6 2 2 3 cos ACB
2
cos ACB
3
2
ACB cos 1
3
S 2 is correct.
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JEE-MAIN-2022 (25th July-First Shift)-PCM-38
Sol18. Number of solutions of the equation cos x sin x for x 4, 4 will be equal to 4 times the
number of solutions of the same equation for x 0, 2 .
Graphs of y cos x and y sin x are as shown below.
y cos x
/2 3 / 2 2
y sin x
Sol19.
P
x
R
150
15
0
60 A
Q
y
From APQ
x 15
tan750 ……….(i)
y
From RQA
15
tan600 ………..(ii)
y
From (i) and (ii)
0
x 15 tan750 tan 45 30
0
3 1
15 tan 600 tan 600
3 1 3
On simplification,
x 10 3 cm
15 10 3 m
5 2 3 3 m
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JEE-MAIN-2022 (25th July-First Shift)-PCM-39
SECTION - B
Sol1. Here
2 1 1
A 1 0 1
1 1 0
We get A 2 A and similarly, for
1 1 1
B A I 1 1 1
1 1 1
We get B 2 B B3 B
n n
A n B A B for n N
For n to be unity n shall be multiple of 3 and for Bn to be B. n shell be 3,5,7,…9
n 3, 9, 15,....99
Number of elements = 17.
Sol2. Arranging letter in alphabetical order A D I K M N N for finding rank of MANKIND making
arrangements of dictionary we get
A............
6!
360
2!
D........... 360
I........... 360
K.......... 360
M A D.........
4!
12
2!
M A I........... 12
M A K............. 12
M A N D........... 3! 6
M A N I.............. 6
M A N K D........... 2
M A N K I D............ 1
M A N K I N D........... 1
Rank of MANKIND = 1440 + 36 + 12 + 2 + 2 = 1492.
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JEE-MAIN-2022 (25th July-First Shift)-PCM-40
Sol5. a1 b1 1
an an 1 2 for n 2 bn an bn1
a2 a1 2 1 2 3 b2 a2 b 1 3 1 4
a3 a2 2 3 2 5 b3 a3 b2 5 4 9
Similarly for others
11 15 15 15
n 1
anbn n 1 2n 1 n2 n 1 2n3 n 1n2
2
15 16 15 16 31
2 27560
2 6
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JEE-MAIN-2022 (25th July-First Shift)-PCM-41
4x 2 8x 5 ,
if 8x 2 6x 1 0
Sol6. f x 2
4x 8x 5 , if 8x 6x 1 0
2
1 1
4x 2 8x 5 if x , ,
, 4 2
2
4x 8x 5 , 1 1
if x ,
4 2
4x 2 8x 5 x , 1 1 ,
4 2
1 2 2
f x 3, x ,
4 2
2 2 1
2, x ,
2
2
1 2 2 1
4 2 2
Non-diff at
1 2 2 1
x , ,
4 2 2
k 1
n 1 1 n r
Sol7. limn
n
k n
n r 1
1
33 x k dx
0
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JEE-MAIN-2022 (25th July-First Shift)-PCM-42
1
for P 2
5P
1
2P2 2
f 3 for P 2
1
P ,2
2
1
Centre can be ,0 or 1, 3
2
1
2 ,0 will not satisfy
Tangent should pass through 2,3 for 3x 2 y 2 3
x2 y 2
1
1 3
y mx m2 3
Substitute 2, 3
3 m m2 3
m 2
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JEE-MAIN-2022 (25th July-First Shift)-PCM-43
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