Sepeimento2 Pago No.

dim 8- la delect the_peasenck catin d anin

gsena satt.
-Requiernenf8- Tost tube , unknoasn sall, fest
tabe hode, Cheeal.
Chenicals t- comcH,SO4,AgNle NalH, NHdH
Messles's keagent ete

b2-)olaut Calswxless
dsuke leks
Chsersaton tablo
fest fo mm
S. Na erpekinent Cbset vaton rheence
o1) fake soid salt
dey test tabe t
dile Has4 absent

02.) Salid salt wn onothee ngent smell

est tebe +Cent. H,sQ peesent
03-)
salt and add l-2 cnfkme
AH¡0H
 Renclion fos onin t

C) NH Ca cs) +dil Hasly cag) ’ o bsex vation

O2) QNH4 lcs) + conc. H2s04 (aq)NH),S04 t Hd ‘

pangent rml
039 NHa cag) t AgNOg caq-) Agel tt NH; NO,
white pþt
 fest fot caion
S. No. Erpeim ent obsex oation safexence
fake solid salt mdeu Sael NHÆ Ma
fest tebet NaH ammona gas peesent
b2)Pata kod dipcd chilefamts NH may
peesent

8)aabase salutin adelPeddsa

Alessle Beace anhsemeol

Posult -
The gieL Salt Nitl it which catin
o) NHeCl cs t NalH caq) Nalls + ,OcNHg )

ohite kuenu

Necsler's Redalish btsn

reagent Ppt.
 Pace No
Cusly

T6 cletect tupreeuce
catim

RegiremeLt - Zeat tube, HNO, NH, 0t, aceic

acid
detattiun)6eyde
Palisseinay tett i
(4) Plyeical state selid
(2) Colew
dlees Ocleule
Obseswtion table i
Tet e Catieu
Expesinest dbresvaten
Tate salt iu testtube No tmellq zero grp
ammmenig ieabteut

2
NO pet
chseut

Pas HS to eluhen Black pet

prereut

4
Blackpgt dineluu lu Black colaus Cei,2t may
-prerut

Add exces NHaDH Peep bhue

caleus ereLeut
 Reaciens
Cusou cs) No ppt

2 dil- He No fet
dil Ha Cus L + HasOy
Cuso H,S
(Black ppt)
3Cus t &HNO, Cu CNe) + y HaO+3s
CRuiel baun)
 24
Abeue elutieu t il Chacakt
HCO0H + Potassiuno Brsun ppt ceuyirmed
tesiemide, selutien

Test

SNO. Eoperimeut obrerwatiou ayeae

Zake selt iu dy No obrewatiey dilgrop
test tube +dil Haloy auucu cbreu

Toke sadt u auueues

tet tube tLeuc HlOy

3
salt RaChselutie2 caupirmecd

Reult. Cu cation
 Rea cions aiou i

dil HesOy No otbseswatiou

2
CeesO + Coue HesO, No cbsewation

CusOs,oto Bacl (e)

 DateT
Pago No.:
Fe Cls

Aim :- o cletect tue preseuce q ue caton

aud

Reqiremeuti-Zeet tube, Ag NO saltcBL

HesO, dil tas0, dil Hy NHu Cl NHOH
-petatinm tiocyuide (keNS) , cac NalH
Pliriay test -
(2) pyical Cryttiike Eolid
(2) Bscus
()
Oles Pugeut
Obcewaion tabe -

Test catian
SNo.
Expesinet labsesuatien
JTake salt u dy test No ohsewation
tube tCene AalH lel abseut
2
Apuesus saluten salt
tdil HC abseut s)
IP cafion
aheue slution
kadolil
Sedid NH Ccg) exe
2NHuoH solutiu -fetoned. preseut
 Reaci cns caioui
Fe d3 cs + NalH No
obsewation

2.
Feds (s) t di Hcd (ag) No

Fe l3 (5) NO pet

(Re ddit 3NH;!

PPt)
 Disolue tu pp Pet clissue
past
(a)Ipast op stutien t
-petaun
6)
Bacd red Ft cafion
petasium fioyate Celeus

Tet e auics
S-No.
Expesineut bbsewation
Take salt is dsy agescuce
teet tube t HeSou sel 0beesuation
2
Take salf i tles Celesle4 gad
teet tube t Couc ta So preset
Tabe a rod dieed a wite sme
NH OH4m
weutle teet tebe

tite ppti
2-7

Rerulti Tae giieu salt cat 34

aud
 S. fe (OH) + HCI

Reactious
Fe l3 (s) + dil HsOy obsevation

2 2 Fe Cls cs t Couc HsOy Fel Soy) + 6 Hu

Puugetsmel
NHycl t NHy0H NH, Ces) + Ha0 + ume

Fels cog: t 3 Ag N0s Cagy

 to detect the presence
Aim

presence of
Rectingthe
nitrogen, sulphur and halogens in given
MaterialsRequired organic compound.
Ignitiontubes " China dish
" Funnel
Test tubes " Tripod
Glass rod
Wire gauze
" Test tubestanduoloeodl
holder
a
" Burner
" Tongs " Knife
e Sodium metal "Ferrous sulphate " Dropper
Sodium nitroprusside solution " Dil. sulphuric acid
e Lead acetate " Silver nitrate
" FeCl,, S, or CCI,, Cl,
, Given organic compound. water " Distilled water

Procedure
. Sodium fusion extract of the given organic compound is prepared as
discussed earlier.
Different tests are performed and observations are recorded.
S. No Experiment Inference
Observation
1. To 1 mL sodiumn extract a pinch of FeSO, is No deep blue colour Nitrogen absent
added. Then dil. H,SO, is added to dissolve the |observed
ppt. Then add 2-3 drops of FeCl,. No deep redcolour observed Nitrogen and sulphur
absent
2. 1mL sodium extract is added with 1 mL sodium No violet colour observed Sulphur absent
nitroprusside
3. 1mL sodium extract is acidified with dil. acetic No black ppt. formed Sulphur absent
acid and then 2 mL lead acetate solution is added
4. Bromine and iodine
2 mL sodium extract is acidified with dil. acetic|No colour formed in organic absent
acid and 1mL CCI, is added. Then CI, water is layer
added, slowly.
ppt. is observed Chlorine present
5. 1mL sodium extract is heated with conc. nitric|White
acid and after cooling silver nitrate is added

Result
chlorine as extra element.
Ine given organic compound contains
129
PRACTICAL SKILLS IN CHEMISTRY-11
 Halogens
(a) Testfor
|Observation
AgNO,
Chemistry the
follows:are as Silver
Solubility precipitate black extract.
the
mixture
Chemistry
precipitate
Colour of
presence
they Nitrate coloured Few
of in is is
give thammonium observed drops
of of
e boiled. Test: the
lead sulphur.
precipitate Test: of
2 Test:
and After mL sulphide
Sodium hydroOxide of
the (CH,CO0),Pb
Na,S + When
Nal NaBr t boiling,
AgNO,
NaCl + of is
silver precipitate sodium
combines formed. lead
+
, + the
extract
mixture acetate
AgNO, ’ halides. Curdy-white
Chloride
Soluble
is
with checked is
taken
is reacts
’ halides ’
cooled
for in with
its a Black
yellow
LightCurdy-white to clean2CH,COONaPbS +
AgBr AgCl give solubility and sodium
,Agl + Partially
solubleyellow silver test
sodium Light
Bromide tube.
NaNO, NaN0,
+ + in
nitrate sulphide,
halides. ammonium 1
mL
solution sodium
conc.
When
is
hydroxide HNO,
halide added acetate
Insoluble is
Iodide Yellow to is
ions solution. added g
it
eact Colowe to
Resik tm
with