Experiment: Date

K20/A1g/2 Page No.

ExPERIrIENT Nad

PIM: To deksine the slaeoqth ef Sorum Hydrovide (neh OH) and

Sakm Caxbenaë (Na,Co regven water 8ampe. iven gTandar
N/40 Sedn casbonate të ständaslge qven HCL Selfron

APPPRATUS INVOLVED:
Busette, pipette,Conical fHask, white papes, sland, busele clamp, bea kevs
meaiurinqcuodes, weghing bsttle.

REAENTS REGUIRED:
SeTun Casbenste (Na,co,)
HssechlaicAcid(HC)
Distlles Wates
Wafes 5ample containing Na0H 2n Na,co, mixtose.
NOICATORS AND THEIR ENO PoiNTS:
heno Phendphialen(Pink to Csleuales9)
MethylOsange (Yellaw te Pink)
THEORY
he feation is based upon the specifc_pH 3anqe fon each înSiat
he pheneptkalein inSicaton qives pink celoh in p 3ange 8:- j0.:0

while metht gnanqe qives pink Colsua io pH ranqe 4.4-30. hag

Oeen b3exve9 hat the p sesen et sodim hydxoxide an gedromn
Dae ptvide a pHgher than 3.2 to The elution. Ini tioll
alwayi
when tandaxg hySrncblonic oió u odMed, te Of ions a ist
DELTA
 Experiment : Date
2k20 /a18/1 Page No.

CenvesTe To H,O an9then Co ae CsnvesTed To HCo, when s t tue

Steps bkG| Cempleted the pH 3slohen becone les an 8:2 an8
1he pink cglo.a ohe phenslpttalein disappeaag. At kis_poiat, met
hange is addes ag a indista nd the Complete nestralization.
n 'a d8.hen ef fusther as,t HCO isns are cenvesTes t Co, ond
H,O.lmeans Step() a enplete.when all HC iens ase_use p
the pH 6 3elion becomes ess tton 44 instortaneeusl At tis_poit
methul onange Giveß_pink Celsu,

PROCEDURE:
Standaxdr2ation of qven Hc 58luton:
Take lo ot standdr8 Na,co tetelp e pipetfe ints a cenical tlask
Added -2 dscps e metbyl 0narge.
)Ron the acr seluhen oom the busette iste cCenicallask dsopure uit
Censtant shakinq egalution, Founs the en8po when lzti yellmu Cdeu
36ldign tuans pink. Nste8 the vslume o aas uted.Repest is Mep 4-5
Times 4 u get at least Tiue corncadast seadiogs(Tble 3-1D

2) Tation o qiven waks Sample wth HCl Sslution

6 Pipetesd loml sf qiven wates Sample ints a cenial flask. ASIeS
deps ophenelthalein Soßioton.TheSoluten Turos pink.
) Hci sslstion yen buzete ists the Con+cal slask ath cersTast
Addeg
shaking T te pink celesn disappead. NsTe the peadinq en tie buzetfe ()
hakin
HHfex diseels«sratien ads a dsogs methyt range into the islotion
Tate new again wTth 'agd Ell yell8 celesusted oliien Tosns
pink aqon, NeTe the valume of acid ugeð(V,). Repest The steps t get
Con cehdant seading.(Toble 3.2)
DELTA
 220|0132
STuctuse ans re Modfhes StaucTuxe oindicaton3
Resenahg Stuctuse o mehyl onange

-N=N-
Na Benzantid Sfructom yellsu in olan
3)

Ouinenid Strocfue Pnk in

N-Ñ soN t

2)stuTuse phenotskn

OH

oH Beng@nend StuTo se uinaneiS STsuTuse

Celoun less Pink în Stize celat
ExTsTs pre deniaiTly n ExisTs psederninantily în
Ocdic me diun Basic Medium

REACTONS INVOLVED
Chenical Reachens Tenic Re acti ens

HCL + Na0 Nacl +H,0 OH+H H,0

H No, Co NauCo+NaCl Co+H HCO

Na HCo+ HC N a C l +H,0 + (O
HCOtH H,o+co
 K2oja18/a
Obsexvstens
Table 3.
Buoette Reading Vs lurne of (onsndt
S.No Vs laone o
Na,Co (m) Taa Finol(m HCI ued) seadiog)
(only
O 86 86
10
86 86 .6
3. 5.8 86

Table 3.

S.No. Velume Buzete Readngs Vel. oHC used nt) Cen hdt
M
wates ampe
Trhal V)pV.)M Teadina)
taken (m *V-) -
O-070 2.3 0 53 P-Ho
346 .0 5.3
2. 2-3 19.3 M-5-3
3. 6 316 36-9 t0 53

Calculaticns:
Te Calculaie Ngaraly d qiven HCl 3eluion,apply nshnalty 4el.ies eraion

NHX cu Nce Na, Co

Nc aag Vna,co XI0= 0 0.29 N
86

NcL 0.029 N
l e okJste NosnslitySodim hydromde (NaOH) and Sodium Coabenate (Nao
we waley ample.

Vvelome e Hclwhen uhale of Na0H and atf of

carbonasTe u neutaelized.
-[o3 lca]

Vs= velome aHCl ahen se4 hat df Ca sbenste nesTsalged

.3
Hence Vslume of Hcl dequized fn tke nesTaalastion L Na0n V-Vs= | 7
=

vslume e Hcl sequise8 the nesfxak7alidn Na,co v 3 10-6m

and Sadium (arbsne

Ts Calc ste Nosmaly oSedivm hydraxide (Naor)
(Naco) em ven wstes Sample

CNsnmsl e NaOH in givn4elutfien (Na0H) -[Nncx (V-Vs)|O.029xl.+

= O.005 N

G0 Nhmalit ef Na ( in give selyfon (Na,ca) [Nacx Ns]-O.0Ax 10-6

=0-03N

C) 515ength Na0H in gwen 30luien= Npon x Eq,. t . oNa0H

0.Oo5 x40 g/
O.a9/t
in given oltfon= a,(o,x Eq, T. a No, co
)STserngth No,(o - O.03x 53 9/2
1.599/
 Experiment Date
Kao/ASa Page No.

RESULTS:
Strenthet Na0H in qjiven Relfion 0.2 g/2
Sfrenth Na,Co in qiven &olution 59 g/
PRECAUTIONS
Bene stasinq e expesieoeit,the gla65 appaatos mut be pasfetly
eleane&.
C Fon each tifsahon,tre nitísl eading busete ghoulb alayg be the

CKi)Aluay 3tal ewey meniscoR o 8oldienevel in burette

Neas #e nd_peint, ads oad elution drep wíse Gnd ater aen
adtion each dsep See the Colou agoinst whte bockgseund.
) De ngt blea last drep of s9lufien foem _pipette.Just ap the
Co pipete T the walls o the lask.

DELTA
-