HYDRO CARBONS

anatusates Ayotiocauony = Recluc bion, Ov) Hydhajenaton

a Fem PEAlane, Nickel use any ong
CHz-CH
CH=CH tl, (H, =cH, P7CH-CH
Pt os Pos’ y tempeatune
Eaney Ni-s32 (Sebatiex Siholeun, raoluctibr
From alk halidas
Ws tz vea ctiDn

H, Z-Hcl
means HI

Propyl chloriele
Wuytz Tea ctibn

TeaLb'on
 -ct-cH3

cH-CH
Cita

CH3
2i5 dnahyl
Limiba bion s
We cannot prepao albaney widh odd no. of Caubon
a fony
P res t ina mixhone o products hichs va
dithiclt te Sepuzate
Tetiay alkyl haltoe oill form alkeney wi t sane ano. ok
Carbon a ton and hence can t uengo Weste recch.

Fromsalt ofatboxyl'csll

Desaboxylation Rolbo's elecholytit relcttom

)a caukoxylation
Rtc-o-Naf Soda
natR-tt
Jime
Na o
 Sode wm acabate

Stollam bezoate
Sfepping doon deaction ; Roduct hay ess Caubon
tuan eactant
Kolbe's electvolytte Yoolacti

Mechansmi
CHooNactgo0 +Nat
At Ancate
2ctycoo 2CH, (oo422
20H3-coo" ’2CH 42(0

At cat.ode H,o4.
Nqt 4ot>NaOt
2H+2e tt
 Roucior
Frem alkyl kalade

Decsbeylatron
VELbe's ecbdg
reduckion

Aethane ant be pto gorecl by dolbe's electro'y te

ruouc bion a3 Sesum formmateC HCoOH) ill ony Itbeate

) Aha nOn polaa and oluble in jatey

attrackton

B) h boilind pot o al kanes incr oa1swiba tncseae in

and waa molecde adso iner Gnses
4) Goiling point branchad khydocabony ae lowe tan
straigkt chain bccaue on branchig, tasace are deuxeaic
and te molecadas attairna mere spheica skae
 more biceliny doe S.A.,ept

Chemi cal propeaties

it is Calo substitution reaction
halgo ton
Akaney veadily (ombiae coith halageny
Sulight to form a huanbes h prod ucts which proceos b
froe raclics
nechannmkl
CH, 14hir.
HC
makhylone chlorrde
Chlovoborn
(abon tetacklarde

are explos tve

Yeachion wth Todtna es yey sos Qao revesible
Hence, an oxidising agent ite HNo or Todi acd (HO, )
fS aSel to fecilfate fee reactton to mmove nte boruad
Jkeectto n

6 HT+ HTO 3I,+3H, o

Free rad ica subs titu tioa rectlon
Stepl

Teminaton; 2hroe radieals shoto

SBepll:
Conbins to foxom produc

forneal on chlorig tio o6

ehane can dao be
2-methgl bree ralicaly Combins
Aedhane as
to fovm eteae