Alcenes

îupAC Nomenclaiture oh allecnðA bawe

alrods be Ltudied tn Prvioul dhopier..
UnCaturation.
O soletk begin witth
Digree oh Uncatuaion/ Doubb bord
Gquivalnt / Lodox of Hydrogen defiaeny
+ nNt
2Dc +2-MH -nx
IHD. =

+6 oxiason nunber +4'oxid?

no.

04 TH.D. = 0 ( Satuaed)
Wcatroted TPple bond
Toppla

O General foomula i Gotbn

D.U./THD = 2e+2-nnx tnyt4n,

= 2(7+2- 8 -0+0 +4()

D.U. 4
ao naic.
 'fer aion oh alkones
Dehyaratg
aqent

Foom
Varcut dehyrating agen Delydrason
() Conc. H,SOy C0-180C) AlcoholS
Hroy (hto k ) add .
ats as euos
(3) Al0a (38oc) (phocpngvow
. Hratng with Pa a oo PAOp
Hoain w'th Pods + Ruridine
kHSoy.
Heothg
Geruraly qúds doydraig asgot.
Mechaniyi- (wt be taugat i9 clax ro0w)
CNOe doon during cian).
Stabiwy o, alkne:
C=
R
R

-R H ciS .
Trans

Qubstued alicone fc mose

’ More
Aade due to Hyper cojugau
mechanicy 4eat
we enou) byto
AS
foomed during dehydraion
Carboaton ic delydraio9 o
Procos teerafoe ease
aJcohols: (3i1)'
271
M
Me
Me. Me o4
(2)
> KoH > (esoran

(6.2.)
(Roayershrein
 Dely deo
Dahydeo haloyanaion o; Aleyl helide
+ H0
He-cHy +
Rare

Various Baet can be used for te deydro

habgenaon ollkal wo«l!
4|chole hydroxide ot
and O
g NaR, KoH liqwd
Alkali m4tel aides in
NanH, kNH ad
NH2 Such al
CsNH
alikal' mtal to
tn alcoholc
2) Alkoxide oB diaocyclononene CDBN)

O(cyoNa oo cayok) +citoy.

with

Mehaniey
Base H .
Cot) H
X
tured allkeneis fomed
MOre s ubSH eatly
RI>RBYRel>RF
 6)
Dehalogeraton
Zndurt
Geminal C11-ihalogen) + o Alkene.
Yicinal C,2-dilalogen)
kT+aton
Me
3
Me
Me
14-pichlo0-2metyl > Me
propane CGem) kT+ Acetone +(enea)
kel+îel)
3 Me

Me
to rememter)
(Not
Mechanie
 Me Me
tor
tNa -Me

Me HCTrane)
Special eaction
o Net eter) Ccic)
Bi molealar (ornbi nason ) Me e
Me

Hydroborakon ot alaynea
CFrom & cs alkene)
)BHA + ethen
I3
THE borane .
Trialery!
But-t-yne (Poenaa Coc
His reochon 7
Moreaboud
alkene

cion 4 alyne
Redu R CH= CH
Rc=Ct 200200C
ardem veducion)
Sabatier
()Pyoysis
Alkenet H.
 Amonie alyl hydvoxide
9At NH,OH.

Mechanisy:

8 Kolbes slechoysis
RCH C-0k + Ha0’ RCH=CH-R
Ho + 2kt
+
RcH
+ 2c0

Medantmr
Mecheniny CHome oork)
 alkenes upto G are
Same ac alkanes, uquid end Geoncarde
qares, -Gy are
O
Tamperaiure.
solide at T00)

Boilng Carbon Content7

will be
BPt & Caron , mose
ot
mose no.
I boi ling point.
PolariHy| than
Pol ar
alonel are more
Bpt o allken
Af
alkanu,tteretore
ot to coreelpordig
'compored
ave higher
kane
Dueto more polariy in Gs fom.
’
>Trane Cioner
RPt oh jcisisomer

Muting Points
Like alkane, allcanes also chouy
altematon ettet.
M.Pt oTrans itomer arlomer)
close paccing in moe symntnal
due to
tranc fom.
More solid iae cloce packing ,highar
will be me ling point.