Professional Documents
Culture Documents
1.2. Relevant identified uses of the substance or mixture and uses advised against
Supplier
Gulf Oil Middle East Limited
P.O.BOX NO 17068
JEBEL ALI
DUBAI –UAE
PHONE NUMBER +971-4-8870803, FAX NUMBER +971-4-8870801
email : SDS@gulfoilltd.com”.
Poison Information Center (IE) +353 (0)1 809 2166 (08:00 - 22:00), (IS) +354 543 2222
telephone number
Contains Benzene, polypropene derivatives, sulfonated, calcium salts May produce an allergic reaction.
Signal word
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None
Hazard statements
EUH208 - Contains Benzene, polypropene derivatives, sulfonated, calcium salts May produce an allergic reaction.
Product containing mineral oil with less than 3% DMSO extract as measured by IP 346. The highly refined base oil may be
described by one or more of the following generic CAS identifiers: 64742-54-7, 64742-65-0, 64742-52-5, 64742-53-6, 64742-62-7,
64742-57-0, 64742-01-4, 64741-88-4, 64742-96-4, 64741-97-5, 64742-55-8, 64742-56-9, 64741-89-5, 8042-47-5. See Section 15
for additional information on base oils.
General advice May produce an allergic reaction. When symptoms persist or in all cases of doubt seek
medical advice.
Skin contact Wash off immediately with plenty of water for at least 15 minutes. Remove and wash
contaminated clothing before re-use. May cause an allergic skin reaction. If symptoms
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persist, call a physician.
Eye contact Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide open while
rinsing.
Ingestion Clean mouth with water. Drink plenty of water. Do not induce vomiting without medical
advice.
Protection of First-aiders Use personal protective equipment. Avoid contact with skin, eyes and clothing.
4.2. Most important symptoms and effects, both acute and delayed
Special Hazard
Thermal decomposition can lead to release of irritating gases and vapors. Carbon monoxide, carbon dioxide and unburned
hydrocarbons (smoke). In the event of fire and/or explosion do not breathe fumes. This material creates a fire hazard because it
floats on water. Combustible material.
Remove all sources of ignition. Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and
clothing.
Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.
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Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Dike to collect large liquid spills.
Ensure adequate ventilation. Do not eat, drink or smoke when using this product. Handle in accordance with good industrial
hygiene and safety practice. Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Remove and wash
contaminated clothing before re-use.
Incompatible materials
Oxidizing agent
Exposure limits
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(Viscosity >20.5 cSt @40°C) TWA: 5 mg/m3
(Mist)
Highly refined, low viscosity STEL: 10 mg/m3
mineral oils/hydrocarbons TWA: 5 mg/m3
(Viscosity >7 - <20.5 cSt (Mist)
@40°C)
Ireland 2016 Code of Practice for the Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001.
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bendrieji reikalavimai".
Chemical name Long term - Oral Long term - Long term - Short term - Oral Short term - Short term -
exposure Dermal exposure Inhalation Exposure Dermal exposure Inhalation
exposure exposure
Zinc 4.17 mg/kg 7.34 mg/m³ 299 mg/kg 617.8 mg/m³
bis[bis(tetrapropylenephenyl)]
bis(hydrogen dithiophosphate)
Phenol, dodecyl-, branched 0.25 mg/kg 1.7621 mg/m³ 166 mg/kg 44.18 mg/m³
Not determined
Chemical name Long term - Oral Long term - Long term - Short term - Oral Short term - Short term -
exposure Dermal exposure Inhalation Exposure Dermal exposure Inhalation
exposure exposure
Zinc 0.21 mg/kg 2.1 mg/kg 1.81 mg/m³ 43.8 mg/kg 149.5 mg/kg 152.3 mg/m³
bis[bis(tetrapropylenephenyl)]
bis(hydrogen dithiophosphate)
Phenol, dodecyl-, branched 0.075 mg/kg 0.075 mg/kg 0.79 mg/m³ 1.26 mg/kg 50 mg/kg 13.26 mg/m³
Not determined
Chemical name Fresh water Sea water Fresh water sediment Sea sediment Soil
Zinc 75 µg/L 7.5 µg/L 0.06 mg/kg 0.006 mg/kg 0.02 mg/kg
bis[bis(tetrapropylenephenyl)
] bis(hydrogen
dithiophosphate)
Phenol, dodecyl-, branched 0.074 µg/L 0.0074 µg/L 0.226 mg/kg 0.0266 mg/kg 0.118 mg/kg
Engineering Measures
Ensure adequate ventilation, especially in confined areas.
Engineering controls should be considered as the first line of protection against adverse exposure to harmful substances.
Administrative controls and PPE should be used in the absence of engineering controls or as supplemental controls where
engineering controls are insufficient in reducing specific exposures to an acceptable level.
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Eye Protection
Safety glasses with side-shields.
Hand Protection
The following glove type may be suitable for handling this product:. Protective gloves complying with EN 374.
Nitrile rubber Glove thickness => 0.38 mm Break through time => 480 min
Butyl rubber Glove thickness => 0.64 mm Break through time => 480 min
Glove material suitability will vary depending on specific use conditions. Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under
which the product is used, such as the danger of cuts, abrasion. Consideration should be given to variables such as operational
characteristics, anticipated contact time, task requirements and other factors relevant to the selection of PPE. Any specific glove
information provided is based on published literature and glove manufacturer data. Gloves should be replaced regularly and if there
is any sign of damage to the glove material.
Respiratory protection
No special protective equipment required. In case of mist, spray or aerosol exposure wear suitable personal respiratory protection
and protective suit.
This information is based on the state in which the specific product is delivered and on the intended use specified within this SDS. This
information is provided based on literature reference, manufacturer specifications and recommendations and/or derived by analogy with
similar substances. The level of protection and types of exposure controls will vary depending on potential exposure conditions.
Hygiene measures
Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before
re-use. Handle in accordance with good industrial hygiene and safety practice.
Thermal hazards
None under normal use conditions
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Kinematic viscosity 49.86 cSt @ 40 °C ASTM D 445
Explosive properties Not applicable
Oxidizing Properties Not applicable
Keep away from open flames, hot surfaces and sources of ignition, Extremes of temperature and direct sunlight
Oxidizing agent
Incomplete combustion and thermolysis produces potentially toxic gases such as carbon monoxide and carbon dioxide.
Skin contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons
Product does not present an acute toxicity hazard based on known or supplied information.
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>20.5 cSt @40°C)
Highly refined, low viscosity mineral >2000 mg/kg >2000 mg/kg
oils/hydrocarbons (Viscosity >7 -
<20.5 cSt @40°C)
Phenol, dodecyl-, branched ~2100 mg/kg ( Rat ) >5000 mg/kg ( Rabbit )
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation Based on available data, the classification criteria are not met.
Sensitization
Respiratory Sensitization Based on available data, the classification criteria are not met.
Skin sensitization Repeated contact may cause allergic reactions in very susceptible persons.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ systemic Based on available data, the classification criteria are not met
toxicity (single exposure)
Specific target organ systemic Based on available data, the classification criteria are not met
toxicity (repeated exposure)
Aspiration hazard Based on available data, the classification criteria are not met.
The product is not readily biodegradable, but it can be degraded by micro-organisms, it is regarded as being inherently
biodegradable.
No information available
12.4. Mobility
This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This preparation contains no
substance considered to be very persistent nor very bioaccumulating (vPvB).
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None known
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal. Observe all label precautions until container is cleaned, reconditioned or
destroyed.
Other Data According to the European Waste Catalog, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used.
Not regulated
Not regulated
Not regulated
Not regulated
None
None
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
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EU legislation
The Classification, Labeling and Packaging of Substances and Mixtures (CLP) Regulation (EC 1272/2008)
Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)
European Agreement concerning the International Carriage of Dangerous Goods by Road
Safety Data Sheet according to Regulation EC 1907/2006 (REACh) with its amendment regulation EC 2015/830
European Agreement concerning the International Carriage of Dangerous Goods by Road/ Regulations concerning the
International Carriage of Dangerous Goods by Rail
International Civil Aviation Organization / International Air Transport Association Dangerous Goods Regulation
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59).
This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII). This
product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV).
National regulations
International Regulations
International Inventories
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
All ingredients are on the inventory or exempt from listing
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KECL - Korean Existing and Evaluated Chemical Substances
All ingredients are on the inventory or exempt from listing
Other Information
The highly refined base oil (Viscosity >20.5 cSt @40°C) contains one or more substance with the following CAS/EC
numbers/REACH registration numbers:
The highly refined, low viscosity mineral oils/hydrocarbons (Viscosity >7 - <20.5 cSt @40°C) contains one or more
substance with the following CAS/EC numbers/REACH registration numbers:
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Distillates (petroleum), solvent-refined light naphthenic 64741-97-5 265-098-1 01-2119480374-36-xxxx
Residual oils (petroleum), solvent-refined 64742-01-4 265-101-6 01-2119488707-21-xxxx
Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 265-155-0 01-2119467170-45-xxxx
Distillates (petroleum), hydrotreated light naphthenic 64742-53-6 265-156-6 01-2119480375-34-xxxx
Distillates (petroleum), hydrotreated light paraffinic 64742-55-8 265-158-7 01-2119487077-29-xxxx
Distillates (petroleum), solvent-dewaxed light paraffinic 64742-56-9 265-159-2 01-2119480132-48-xxxx
Residual oils (petroleum), hydrotreated 64742-57-0 265-160-8 01-2119489287-22-xxxx
Lubricating oils (petroleum), hydrotreated spent 64742-58-1 265-161-3
Residual oils (petroleum), solvent-dewaxed 64742-62-7 265-166-0 01-2119480472-38-xxxx
Distillates (petroleum), solvent-dewaxed heavy paraffinic 64742-65-0 265-169-7 01-2119471299-27-xxxx
Paraffin oils (petroleum), catalytic dewaxed light 64742-71-8 265-176-5 01-2119485040-48-xxxx
Dec-1-ene, homopolymer, hydrogenated 68037-01-4 500-183-1 01-2119486452-34-xxxx
Lubricating oils (petroleum), C>25, hydrotreated bright 72623-83-7 276-735-8
stock-based
Lubricating oils (petroleum), C20-50, hydrotreated neutral 72623-85-9 276-736-3 01-2119555262-43-xxxx
oil-based, high-viscosity
Lubricating oils (petroleum), C15-30, hydrotreated neutral 72623-86-0 276-737-9 01-2119474878-16-xxxx
oil-based
Lubricating oils (petroleum), C20-50, hydrotreated neutral 72623-87-1 276-738-4 01-2119474889-13-xxxx
oil-based
Lubricating oils 74869-22-0 278-012-2 01-2119495601-36-xxxx
A chemical safety assessment according to regulation (EC) No. 1907/2006 is not required
Repr.-Reproduction toxicity
Asp. Tox. - Aspiration Toxicity
Acute Tox. - Acute Toxicity
Aquatic Acute - Acute Aquatic Toxicity
Aquatic Chronic - Chronic Aquatic Toxicity
Eye Dam. - Eye Damage
Eye Irrit. - Eye Irritation
Skin Corr. - Skin Corrosion
Skin Irrit. - Skin Irritation
Skin Sens. - Skin Sensitizer
Resp. Sens. - Respiratory Sensitizer
STOT SE - Specific target organ systemic toxicity (Single exposure)
STOT RE - Specific target organ systemic toxicity (repeated exposure)
VOC - Volatile organic compounds
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•H224-Ex t
remel yfl
ammabl el iquidandvapor •H341-Suspect edofcausi nggenet i
cdef ects
•H225-Hi ghlyflammabl el iqui dandvapor •H350-Maycausecancer
•H226-Fl ammabl eliquidandvapor •H351-Suspect edofcausi ngcancer
•H270-Maycauseori ntensi fyf i
re;ox i
dizer •H360-Maydamagef ert
il
ityort heunbor nchi l
d
•H271-Maycausef i
reorex plosion;strongoxi
dizer •H361-Suspect edofdamagi ngf er t
il
it
yort heunbor nchil
d
•H272-Mayi ntensifyf i
re;ox idizer •H362-Maycausehar mt obr east -fedchi ldren
•H290-Maybecor r
osi vet omet als •H370-Causesdamaget oor gans
•H300-Fat alifswallowed •H371-Maycausedamaget oor gans
•H301-Tox icifswal l
owed •H372-Causesdamaget oor ganst hroughpr olongedorr epeated
•H302-Har mf ulifswal l
owed exposure
•H304-Maybef at
alifswal lowedandent er
sai
rways •H373-Maycausedamaget oor ganst hroughpr olongedorr epeat
ed
•H310-Fat alincont actwi t
hski n exposure
•H311-Tox icincont actwi thski n •H400-Ver yt
ox i
ct oaquaticlif
e
•H312-Har mf ulincont actwi thski n •H410-Ver yt
ox i
ct oaquaticlif
ewi thlongl astingef f
ect
s
•H314-Causessever eski nbur nsandeyedamage •H411-Tox i
ctoaquat i
clifewi thlongl astingef fect s
•H315-Causesski nir r
it
at i
on •H412-Har mfultoaquaticlif
ewi thl ongl ast i
ngef fects
•H317-Maycauseanal l
er gicski nreacti
on •H413-Maycausel onglast i
nghar mfuleffectst oaquat i
clif
e
•H318-Causesser i
ouseyedamage •H360Df-Maydamaget heunbor nchi l
d.Suspect edofdamagi ngfert
il
i
ty
•H319-Causesser i
ouseyei rr
itati
on •H360D-Maydamaget heunbor nchi ld
•H330-Fat alifinhaled •H360FD-Maydamagef erti
l
ity.Maydamaget heunbor nchild
•H331-Tox icifinhaled •H360F-Maydamagef erti
lit
y
•H332-Har mf ulifi
nhal ed •H361d-Suspect edofdamagi ngt heunbor nchi l
d
•H334-Maycauseal lergyorast hmasympt omsorbr eat
hingdi
ff
icul
ti
es •H361f d-Suspect edofdamagi ngf ertil
i
ty.Suspect edofdamagi ngthe
if inhaled unborn child
•H335-Maycauser espi rator yirrit
ati
on •H361f-Suspect edofdamagi ngf erti
li
ty
•H336-Maycausedr owsi nessordi zzi
ness •EUH066-Repeat edexposur emaycauseski ndr ynessorcr acki
ng
•H340-Maycausegenet i
cdef ect s •EUH210-Saf etydatasheetavai l
abl eonr equest
•EUH208-Maypr oduceanal lergicr eaction
Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 [CLP]
Revision Note This SDS has been revised in the following section(s), 3, 8, 10, 15, 16.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
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