I

-
-

1) find g of an in 1
km sea water
·
We known density of sea water 1.039/cm
=

2,205 Ib
kg
1
=

1000m3 19 x2.205Ib
-*1m-
3
3
7003 CM
-
1km~ * *
1,035 x

1km I Cm3
~ I ng
1000

1 md An
"
x ~ 4167x10 atoms
Itoux - An 196,979An
-An*
6.02x102atoms
x
2000 Eb 1 tou
-
1 mol -
AU

1,735x10gAn
=

2) find am of seawater would have to

be processed to
obtain the required amountof gold.
I
21.25$
1 0z
+
x20zx2,205Ib1kg 0.56$x
x

-
1g 1 1000gA4 19
Ib
*
=

* Au

1km3 sea water 2.95x10km* Ans

T
19AK
of
=
(88.8x10%~
SIx X = ->
-

0.565 1.735x105gAn
 + AgNOz AgNOy +

(s)
-
a)

A -

a)
ACkag,*1 AgN,agi
1 1
kNUsag! AgCles
-

1LcCzag+ 2AgNOz,
ap
1
(oNNO,Izag,2Ag4less
1 KClay 3 AgNOzsag,
+ +
1CaCzag -> 1
kNOzsag1 + 1 [a(NO,Izag,
3
+

AgClis,

b) give cadz x
=

mol, KCI y mol =

① -molCaCl 2
x molAgC axmolAgCI
=

1 molcack

ymolKC x1MolAg2) YMOlAgCl

=

1 molkCI

② find
grams of AgCI;
2x+ymolAgCIx143,5gAgC 143.5(2x
=

y)gAgC
+

ImolAgCI

of Agcl
③ We known precipitate yield
108 143.5(2x
y)
+

%.
=

2x y
+
108
=
-

⑪
143.5

I
xmolCaCl2 2 x
=
11x g(aCz Miture
1MolCaCl2 50g
xmolkCl 74.5gKC1 x
74.5ygK2
=

1 mol KCI

... 11x 74.54

+
50
=

-
0 11;222x 111y 83,54
x +
=
-

8
8 x2;222x 149y
+
100
=
-

O
4

...4 -8;38y 16.46

=

36.269
k2x445944
E
y 0.433mol
=

149(8.4337 100
= =

findx; 222x +

=
x 0.16
X 0.16 Mol
=

Cach Mg(aC 17.76

=

gCaCle
xemol CaCle
17.76g(aCl2 x 100 35.52% Answer
=

·: Y (aCz
=

509