Test chemistry 12th class, chapters 7 to 12

Q1: Select the correct answer.

1. In which compound benzene rings are isolated? (a) Naphthalene (b) anthracene (c) phenanthrene (d)
diphenyl methane
2. How many resonance structures of benzene are known? (a) 3 (b) 4 (c) 5 (d) 6
3. Total number of π-electrons in benzene are; (a) 3 (b) 6 (c) 9 (d) 12
4. Preparation of vegetable ghee involves; (a) Halogenation (b) hydrogenation (c) hydroxylation (d)
dehydrogenation
5. The presence of double bond in a compound is the sign of; (a) Saturation (b) unsaturation (c)
substitution (d) none
6. Β-β-dichloroethyl sulphide is commonly known as; (a) laughing gas (b) mustard gas(c) phosgene gas
(d) bio-gas
7. Mostly mixture of silica and --------- is used as catalyst in catalytic cracking; (a) V 2O5 (b) iron (c) lime
(d) alumina
8. Which set of hybrid orbitals has planar triangular shape? (a) Sp3 (b) sp2 (c) sp (d) dsp2
9. Ethers show the phenomenon of; (a) position isomerism (b) functional group isomerism (c)
Metamerism (d) cis-trans isomerism
10. SN2 mechanism involves; (a) first order (b) second order (c) third order (d) none
11. In secondary alkyl halide, halogen atom is attached with: (a) primary carbon (b) secondary carbon (c)
tertiary carbon (d) none
12. For which mechanism, the first step involved is the same; (a) E1 & E2 (b) E2 & SN2 (c) E1 & SN1
(d) E2 & SN1
13. Which compound shows hydrogen bonding; (a) C2H6 (b) C2H5Cl (c) CH3-O-CH3 (d) C2H5OH
14. Which compound will have the maximum repulsion with H2O? (a) C6H6 (b) C2H5OH (c) CH3-O-CH3
(d) none
15. Which enzyme is not involved in fermentation of starch? (a) Diastase (b) zymase (c) urease (d)
invertase
16. Which of the following reagents will react with both aldehydes and ketones? (a) Grignard reagent (b)
tollen’s reagent (c) Fehling’s reagent (d) benedict’s reagent
17. Acetone reacts with HCN to form a cyanohydrin.it is an example of; (a) electrophilic addition (b)
electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution
18. Formalin is: (a) 10% solution of formaldehyde in water (b) 20% solution of formaldehyde in water (c)
40% solution of formaldehyde in water (d) 60% solution of formaldehyde in water

Short questions…
Q2: Write the answers of following short questions.
1. What is difference between metamerism and tautomerism?
2. Explain the type of bonds and shapes of formaldehyde and methyl chloride.
3. Write flow sheet of coal formation from wood.
4. Write modern definition of organic compound.
5. Define alicyclic and aromatic compounds.
6. Explain ozonolysis of alkene with one example.
7. Write three uses of methane.
8. How alkenes react with hypohalous acid.
9. What is Sabatier-Sendern’s reaction?
10. How alkanes are prepared by decarboxylation of monocarboxylic acids?
11. How benzoic acid is prepared from toluene?
12. Compare the reactivity of alkene and benzene.
13. How maleic acid is prepared from benzene?
14. Write the results of X-ray studies of benzene structure.
15. How benzene is converted into glyoxal by ozonolysis?
16. What is difference between nucleophile and electrophile?
17. What is difference between substrate and leaving group?
18. How will you prepare tetramethyl lead and tetraethyl lead from alkyl halide?
19. Write three types of alkyl halides.
20. How Grignard reagent is prepared?
21. Why absolute alcohol cannot be prepared by fermentation process?
22. Write down any four uses of ethanol.
23. How ethanol is prepared from molasses?
24. Write structural formulas of lactic acid and tartaric acid.
25. Write a test which shows distinction between methanol and ethanol.
26. Write the formulas of 2-propanone and acetophenone.
27. Give industrial preparation of acetaldehyde.
28. What is formalin?
29. How acetone is prepared from calcium acetate?
30. Define haloform reaction with one example.
Long questions….
Q3: (a) Write some important features of organic compounds. (b) Straight chain structure for benzene is
ruled out, explain it.
Q4: (a) Explain free radical mechanism for the reaction of chlorine with methane in presence of sunlight.
(b) How primary, secondary and tertiary alcohols are prepared by Grignard reagent?
Q5: (a) What is aldol condensation? Write two examples and mechanism of aldol condensation. (b) Write
five characteristics of SN1 reactions.
Best of luck….