Paper: Chemistry Class: 2nd Year Round: III Chap: 3,4,6,8 Marks: 50 Time

Allowed: 2 Hrs

Q.No.1: Four possible Answers are given . Encircle the correct one (18×1=18)
1. HBO2 is the formula of:
(a) Orthboric acid (b) Metaboric acid (c) Tetraboric acid (d) Pyroboric acid
2. Boron is an:
(a) Metal (b) None metal (c) Semi metal (d) None of these
3. Which of the following is not present abundantly in earth crest?
(a) Silicon (b) Aluminium (c) Sodium (d) Oxygen
4. Which metal is used in the thermite process because of its activity?
(a) Iron (b) copper (c) Aluminium (d) Zinc
5. Aluminium gives ____ gas with hot conc. H2SO4.
(a) SO2 (b) SO3 (c) CO (d) CO2
6. Oxygen shows which behavior?
(a) Paramagnetic (b) Diamagnetic (c) Ferromagnetic (d) None of these
7. Gold and Silver dissolve in:
(a) Aqua regia (b) Nitric acid (c) Sulfuric acid (d) HCl
8. TNT is prepared from:
(a) Benzene (b) Toluene (c) Pyridine (d) Thiophine
9. Laughing gas is chemically:
(a) NO (b) N2O (c) NO2 (d) N2O4
10. Which of the following species has maximum number of electron?
(a) O2 (b) O2+ (c) O2- (d) O22-
11. Elements having unpaired electrons are:
(a) Paramagnetic (b) Diamagnetic (c) Ferromagnetic (d) None
12. The oxidation state of Mn in KMnO4 is:
(a) +3 (b) +4 (c) +5 (d) +7
13. Complexes having d2 sp3 hybridization show _____ geometry.
(a) Tetrahedral (b) Octahedral (c) Square planer (d) Linear
14. Which of the following is non-typical transition element?
(a) Cr (b) Mn (c) Zn (d) Fe
15.Alkanes due to little chemical reactivity are also called
(a)Olefins (b) Paraffins (c) Grignard’s reagent (d) None of these
16.The most recent report of IUPAC was proposed in:
(a) 1939 (b) 1949 (c) 1969 (d) 1979.
17.Clemmensen reduction is used for the preparation of:
(a) Alkane (b) Alkene (c) Alkyne (d) Unsaturated hydrocarbons
18.Dehydration of alcohols gives:
(a) Alcohols (b) Carboxylic acids (c) Aldehydes (d) ketones

Q.No.2: Write Short Answers to any FOUR questions (4×02=08)

1. Write four uses of borax.
2. Write reaction of aluminum with NaOH and H2SO4.
3. Explain with the help of equations that what happened when boric acid is heated?
4. Explain peculiar behavior of Boron
5. Write properties of silicon dioxide?
6. Why orthoboric acid (H3BO3) is called mono basic acid?

Q.No.3: Write Short Answers to any FOUR questions (4×02=08)

1. How nitrous acid is react with NaOH and HI?

2. Write some uses of nitric acid.
3. What is aqua regia? What is its importance?
4. Why HNO3 acid act as oxidizing agent?
5. H2SO4 is known as king of chemicals why?
6. Complete and balance the following equation:

♦ H3PO3 + [H] ♦ Mg + HNO3

Q.No.4: Write Short Answers to any FOUR questions (4×02=08)

1. What are non-typical transition elements?

2. Write three properties of transition elements.
3. How transition elements give color in there compounds?
4. What is co-ordination number?
5. How wrought iron differs from steel?
6. Define corrosion. What is its disadvantage?
7. What is chromyl chloride test?

Q.No.5: Write Short Answers to any FOUR questions (4×02=08)

1. What Is Meant By Inertness Of Sigma (ơ) Bond?

2. Write Three Uses Of Methane.
3.How Alkenes Are Prepared By Dehydration Of Alcohol?
4. How Ethyne Is Prepared From Calcium Carbide?
5. Prepare Oxalic Acid From Acetylene.
6. How Will You Convert Methane Into Ethane And Nitromethane?
7. What Is Baeyer’s Test? Give Its Use