Battery R and D Di UNS New

PENGEMBANGAN BATERAI LITHIUM ION
UNIVERSITAS SEBELAS MARET

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
www.puibaterai.uns.ac.id
BEVs PHEVs
Plug-in
Battery
Hybrid
Electric
Electric
Vehicles
Vehicles
HEVs
Hybrid
Electric
Vehicles
www.irishtimes.com
Battery Capacity: 53.2 kWh, Range:410.0 kM
BYD focuses mostly on the production of
prismatic LiFePO4 battery cells
“The largest market for
lithium-ion batteries LIB is and
will remain electric vehicles,
mainly cars, from 2020-2030.”
-idtechex Forecast
Image Source: Avicenne Energy

Active
Raw Li Ion Battery
Materials
Materials Cell Assembly
Processing
Cell Pack Product
https://ec.europa.eu/jrc/sites/jrcsh/files/jrc105010_161214_li-ion_battery_value_chain_jrc105010.pdf
Low Cost High Low Cost
materials Performance Battery
RESEARCH SCOPE
SINTESA AKTIF MATERIAL
❑ Nickel-rich cathode material (NCA) (LiNixCoyAlzO2) batteries have superior performance and
lower price compared to commercially established LCO batteries
❑ Develop process of Solid-state and Co-Precipitation using technical grade material
❑ Comparable with commercial material
NCA-Solid State and Co-Precipitation

❑ As-prepared NCA samples exhibit a layered -NaFeO2-like hexagonal structure (space group: R_3m).
❑ Highly crystalline peaks are in good agreement JCPDS card no. 87-1562, with no observable impurities phase.
❑ The peak splits of 006/102 and 018/110 could be clearly observed in both samples, hence it could be
concluded that the NCA-PC and NCA-SS have a well-ordered layered structure
❑ All samples have nano-sized to submicron-sized primary particles which agglomerate to form larger spherical
secondary particles.
❑ NCA-SS secondary particles show a smoother morphology and denser sphere compared to NCA-CP particles
due to the morphology of raw materials, especially Ni(OH)2, which also has a spherical shape.
❑ The tapped density of NCA-CP is 1.93 g/cm3, while the tapped density of NCA-SS is 2.17 g/cm3.
❑ In the formation phase, the coulombic
eficiency of NCA-CP, NCA-SS, and NCA-
Commercial is 69.36%, 69.19%, and
72.97%, respectively.
❑ About 30% capacity loss is attributed to
solid electrolyte interphase (SEI) formation
on both the cathode and anode side. The
dierence of NCA-CP and NCA-SS
coulombic eciency is insignificant;
however, the value is slightly lower than
the commercial NCA.
❑ The initial specific discharge capacity of
NCA-SS and NCA-CP is similar; however,
the value is also slightly lower than the
commercial NCA.
❑ Sample NCA-SS and NCA-CP have a similar rate performance behavior and are relatively comparable to
commercial NCA. Surprisingly, at a higher rate, NCA-SS and NCA-CP are superior compared to commercial
NCA.
❑ NCA-CP and NCA-SS have similar cycling behaviors for 100 cycles at 1 C’ rates and have a capacity
retention of 84.4% and 86.3%, respectively. Overall, the cycle performance of NCA-CP and NCA-SS is
comparable to the commercial NCA.
- Purwanto A., Yudha C.S., Ubaidillah U., Widiyandari H., Ogi T., Haerudin H. Materials Research Express 5, 2018, art no 122001
- Yudha, C.S., Muzayanha, S.U, Widiyandari, H., Iskandar, F., Sutopo, W., Purwanto, A., Energies 12(10), 2019 pages 1886.1-14
❑ Simple Equipment
❑ Fast
❑ Continuous
❑ Produce material with good
characteristics
NCA-Flame Spray Pyrolisis

❑ After 20 cycles, all samples exhibit good coloumbic efficiencies
❑ NCA9 has the most stable capacity with capacity retention of 89% while NCA3, NCA6
and NCA12 sample capacity retention is 63%, 71% and 76% respectively.
❑ Recycling of Li-Ion battery waste
❑ Fast, efficient and easy processing
❑ High specific discharge capacity of recycled NCA
❑ Reuse for active materials
Muzayanha S.U., Yudha C.S., Nur A., Widiyandari H., Haerudin H., Nilasary H., Fathoni F., Purwanto A., Metals 9, 2019, 615
NCA-Recycling Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
❑ Low cost of raw materials (technical grade)
❑ High specific capacity of NMC
❑ Comparable with commercial material
NMC-Co Precipitation Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
IMPROVING CATHODE PERFORMANCE
❑ Internal resistance plays important role
❑ Controlling internal resistance enhance battery performance
❑ Densification, additive addition and welding configuration
Purwanto, A.,Jumari, A., Nizam, M., Widiyandari, H., Mohamad, A. A., Materials Research Express Volume 5 Issue 4, April
2018, Art no. 045512
❑Improving zero strain anode material via additive
❑Lifecycle for more than 20 years
❑Fast charging (6 min)
❑High power density (10C)
LTO-ENHANCING BATTERY LIFE CYCLES

Proses Assemby Baterai Li-Ion
Fasilitas Pilot Plant
❑ Mencampur material
aktif, binder, bahan
konduktif dan bahan
tambahan lain
❑ Untuk bahan anoda dan

katoda
❑ Proses mixing pada

kondisi vaccum
(menghilangkan gas
buble yang akan
mempengaruhi film)
Unit Mixing
❑ Digunakan untuk coating
slurry dari unit mixer
❑ Parameter yang perlu

diperhatikan: temperature,
coating speed, panjang
coating per sell
Unit Coating
❑ Digunakan untuk
memadatkan elektroda

diperhatikan: roller gap,
speed
Unit Press
❑ Digunakan untuk membuat
jelly roll

diperhatikan: Ketepatan
feeding, kebersihan dari
debris, kecepatan
Unit Winding
❑ Digunakan untuk mengisi
elektrolit

diperhatikan: jumlah
elektrolit, kondisi chamber
Unit Pengisian Elektrolit

❑ Formation dan grading
digunakan untuk
mengaktifkan dan memilah
baterai

diperhatikan: kondisi
parameter formation dan
grading, waktu aging
Unit Formation dan Grading

Aplikasi Baterai Li-Ion
Motor • Hub motor
Listrik • 350Watt
• LiFePO4
Baterai
• 36V 7,2Ah
Jarak • 45km (Pedal Assist)

tempuh • 30km (full Throotle)
Sepeda Listrik Uns Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
Unjuk kerja
baterai NMC
Rangkaian baterai NMC 10s2p dan BMS

kendaraan listrik Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret
KESIMPULAN
 Fabrikasi sel baterai lithium terdiri dari penyiapan bahan baku, coating,
calendaring, slitting, electrolyte filling serta formation dan grading.
 Sintesa Material aktif dengan berbagai metode dapat dikembangkan dengan
menggunakan material teknis → Low Cost and High Performance.
 Baterai yang telah dikembangkan telah diaplikasikan pada kendaraan listrik
dan sistem penyimpan energi listrik.
PUI PT TEKNOLOGI PENYIMPANAN ENERGI LISTRIK UNS
2013- MOLINA Project 2015-Modul/Pack 2017- Pilot Plant
2014-Sel
❑ Pada 2 Januari 2020 ditetapkan PUI Baterai Lithium

UNS (SK Rektor No 27 A/UN27/KP/2020)
❑ Fasilitas: Gedung 3 Lantai di Pusbangis UNS
Purwosari
❑ Alamat: Jalan Slamet Riyadi No.435, Purwosari,
Laweyan, Pajang, Kec. Laweyan, Kota Surakarta, Jawa
Tengah 57146
❑ https://puibaterai.uns.ac.id/
2020- PUI Baterai Lithium
PUI PT TPEL UNS

No Teknologi Sarana dan Prasarana
1 sel, modul dan pack Mini plant sel dengan kapasitas
1500 sel per hari
2 Material aktif, Mini plant material dengan
elektrolit dan kapasitas sampai dengan 10
Separator kg/hari dan alat karakterisasi
material: XRD, PSA, dan EIS
3 Baterai Testing Peralatan charge-discharge
untuk uji kapasitas dan lifetime
4 Monitoring system, Peralatan Pengujian elektronika
safety, dan komunikasi BMS, Safety dan Komunikasi
5 Bangunan PUI Bangunan 3 Lantai (~2000 m2)
yang khusus diperuntukkan
untuk kegiatan PUI Baterai
Lithium
6 Sel coin Satu line peralatan lab untuk
baterai lithium untuk coin cell
7 Charging station 3 charging station terpasang di
FT terhubung PV dan LPPM
terhubung grid
SARANA PRASARANA PUI PT TPEL UNS

TERIMAKASIH

Battery R and D Di UNS New

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PENGEMBANGAN BATERAI LITHIUM ION

UNIVERSITAS SEBELAS MARET

Image Source: Avicenne Energy

Cell Pack Product

❑ Develop process of Solid-state and Co-Precipitation using technical grade material

❑ Comparable with commercial material

NCA-Solid State and Co-Precipitation

NCA-Flame Spray Pyrolisis

LTO-ENHANCING BATTERY LIFE CYCLES

❑ Untuk bahan anoda dan

❑ Proses mixing pada

❑ Parameter yang perlu

❑ Parameter yang perlu

❑ Parameter yang perlu

❑ Parameter yang perlu

Unit Pengisian Elektrolit

❑ Parameter yang perlu

Unit Formation dan Grading

Jarak • 45km (Pedal Assist)

Rangkaian baterai NMC 10s2p dan BMS

❑ Pada 2 Januari 2020 ditetapkan PUI Baterai Lithium

2020- PUI Baterai Lithium

PUI PT TPEL UNS

SARANA PRASARANA PUI PT TPEL UNS

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