PINNAACLE CLASSES

CH
3
CH
3 CuSO 4
| | 34. In kjeldahl’s method, acts as
H 3 C−C − Br+ KOH ( Aq . )→H 3 C−C − OH + KBr (a) Oxidising agent (b) Reducing agent
| |
CH CH
26. 3 3
(c) Hydrolysing agent (d) Catalytic agent
above reaction is
1 2
(a) SN (b) SN 35. Lassaigne’s test is used to detect
E1 (a) Nitrogen and halogens (b) Sodium and
(c) (d) Both (a) and (b)
halogens
(c) Halogens and sulphur (d) All of the above
27. The most common type of reaction in aromatic
compounds is
(a) Elimination reaction 36. In Lassaigne’s test the organic compound is fused
with Na followed by extraction with distilled water.
(b) Addition reaction
Which of the following is not the possible product
(c) Electrophilic substitution reaction of this fusion reaction
(d) Rearrangement reaction (a)NaX (b) NaCN
Na2 S
(c) NaNC (d)
AlCl
28. The function of 3 in Friedel-Craft’s reaction is

(a)To absorb HCl (b) To absorb water 37. The presence of halogen, in an organic
(c) To produce nucleophile(d) To produce compounds, is detected by
electrophile (a) Iodoform test (b) Silver nitrate test
(c) Beilstein’s test (d) Millon’s test
29. Which of the following can’t be used in Friedal
Craft’s reactions 38. p-nitrophenol and o-nitrophenol are separated by
FeCl 3 FeBr 2
(a) (b) (a) Crystallisation (b) Fractional
(c)
AlCl 3
(d) NaCl crystallisation
(c) Distillation (d) Steam distillation
30. Formation of ethylene from acetylene is an
example of 39. Nitrating mixture is
(a) Elimination reaction (b) Substitution reaction (a) Fuming nitric acid
(c) Addition reaction (d) Condensation H SO HNO 3
(b) Mixture of conc. 2 4 and conc.
reaction
(c) Mixture of nitric acid and anhydrous zinc
chloride
31. Bromination of alkanes involves
(d) None of these
(a) Carbanions (b) Carbocations
(c) Carbenes (d) Free radicals
40. The ammonia evolved from the treatment of 0.30 g
of an organic compound for the estimation of
32. In Carius method 0.099 g organic compound gave nitrogen was passed in 100 mL of 0.1 M sulphuric
0.287 g AgCl . The percentage of chlorine in the acid. The excess of acid required 20 mL of 0.5 M
compound will be sodium hydroxide solution for complete
(a) 28.6 (b) 71.7 neutralization. The organic compound is
(a) Urea (b) Benzamide
(c) 35.4 (d) 64.2
(c) Acetamide (d) Thiourea

33. 0.2595g of an organic substance in a quantitative

analysis yielded 0.35 g of the barium sulphate. The 41. The best method for the separation of naphthalene
percentage of sulphur in the substance is and benzoic acid from their mixture is
(a)18.52g (b) 182.2 g (a) Chromatography (b) Crystallisation
(c) 17. 5 g (d) 175.2g (c) Distillation (d) Sublimation

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 PINNAACLE CLASSES

42. In Kjeldahl’s method of estimation of N,CuSO 4 acts 48. A gas mixture contains 50% helium and 50%
as methane by volume. What is the percent by weight
(a)Oxidising agent (b) Reducing agent of methane in the mixture
(c) Catalytic agent (d) Hydrolysis agent

43. In Duma’s method for estimation of nitrogen, 0.25

49. 0.5 g of hydrocarbon gave 0.9 g water on
of an organic compound gave 40 of combustion. The percentage of carbon in
hydrocarbon is
nitrogen collected at 300 temperature and 725
mm pressure. If the aqueous tension at 300 Kis 25
N
mm, the percentage of nitrogen in the compound is H 2 SO 4
50. 58 ml of 5 are used to neutralize ammonia
(a) 16.76 (b) 15.76 given by 1 g of organic compound. Percentage of
(c) 17.36 (d) 18.20 nitrogen in the compound is
(2015, Cancelled)

44. In Dumas’ method of estimation of nitrogen 0.35

of an organic compound gave 55 of nitrogen

collected at 300 temperature and 715 mm

pressure. The percentage composition of nitrogen
in the compound would be (aqueous tension at 300

mm).
(a) 15.45 (b) 16.45
(c) 17.45 (d) 14.45 (2011)

45. The Lassaigne’s extract is boiled with conc.

while testing for halogens. By doing so it (a)

decomposes and NaCN, formed

(b) helps in the precipitation of

(c) increases the solubility product of

(d) increases the concentration of ions (2011)

46. 116 mg of a compound on vaporisation in a Victor

Meyer’s apparatus displaces 44 .8 ml of air
measured at S.T.P. The molecular weight of the
compounds is

47. If 0.228 g of silver salt of dibasic acid gave a

residue of 0.162g of silver on ignition then
molecular weight of the acid is

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