Safety data sheet

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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

1. Substance/preparation and manufacturer/supplier identification

Product name:
Lutensol® TO 5

Use: Raw material for the chemical-technical industry

Manufacturer/supplier:
BASF Vietnam Co. Ltd.
Floor 11, Saigon Trade Center, 37 Ton Duc Thang Street,
Ben Nghe Ward, District 1, Ho Chi Minh City, VIETNAM
Telephone: +84 28 3824 3833
Telefax number: +84 28 3824 3832
E-mail address: minh-triet.thieu@basf.com

Emergency information:
18001703 (Vietnam)
Telefax number: +84 28 3824 3832
International emergency number:
Telephone: +49 180 2273-112

2. Hazard identification

Classification of the substance and mixture:

Skin corrosion/irritation: Cat.3
Serious eye damage/eye irritation: Cat.2B
Hazardous to the aquatic environment - acute: Cat.2
Hazardous to the aquatic environment - chronic: Cat.3

Label elements and precautionary statement:

Signal Word:
Warning

Hazard Statement:
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

H320 Causes eye irritation.

H316 Causes mild skin irritation.
H412 Harmful to aquatic life with long lasting effects.
H401 Toxic to aquatic life.

Precautionary Statements (Prevention):

P273 Avoid release to the environment.
P264 Wash contaminated body parts thoroughly after handling.

Precautionary Statements (Response):

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention.
P332 + P313 If skin irritation occurs: Get medical attention.

Precautionary Statements (Disposal):

P501 Dispose of contents and container to hazardous or special waste
collection point.

Other hazards which do not result in classification:

No specific dangers known, if the regulations/notes for storage and handling are considered.

This classification is based on the current CESIO recommendations. This surfactant complies with
the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to
support this assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them at their direct request or at the request of a detergent manufacturer.

3. Composition/information on ingredients
Chemical nature

Substance nature: Substance

Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-, branched

CAS Number: 69011-36-5

4. First-Aid Measures
General advice:
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Note to physician:
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures
Suitable extinguishing media:
water spray, dry powder, foam

Unsuitable extinguishing media for safety reasons:

water jet

Specific hazards:
harmful vapours, carbon oxides
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations.

6. Accidental Release Measures

Personal precautions:
Use personal protective clothing.Information regarding personal protective measures, see section 8.

Environmental precautions:
Contain contaminated water/firefighting water.Do not discharge into drains/surface
waters/groundwater.

Methods for cleaning up or taking up:

For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material.
Dispose of absorbed material in accordance with regulations.

Additional information: High risk of slipping due to leakage/spillage of product. Forms slippery
surfaces with water.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

7. Handling and Storage

Handling
Protect against moisture. Shut containers immediately after taking product because product takes up
the humidity of air. No special measures necessary provided product is used correctly.

Protection against fire and explosion:

No special precautions necessary.

Storage

Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene
(LDPE), Stainless steel 1.4301 (V2), Stainless steel 1.4306 (V2A), Stainless steel 1.4361, Stainless
steel 1.4401, Stainless steel 1.4439, Stainless steel 1.4539, Stainless steel 1.4541, Stainless steel
1.4571, Stove-lacquer RDL 50
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:
Storage temperature: <= 70 °C

The packed product is not damaged by low temperatures or by frost. Bulk must be protected from
solidification.
Protect from temperatures above: 70 °C
Properties of the product change irreversibly on exceeding the limit temperature.

8. Exposure controls and personal protection

Components with occupational exposure limits

No substance specific occupational exposure limits known.

Personal protective equipment

Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: (Combination filter EN
14387 A-P2)

Hand protection:
Chemical resistant protective gloves
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN ISO 374-1):
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures:

Wearing of closed work clothing is required additionally to the stated personal protection equipment.
No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good
industrial hygiene and safety practice.

9. Physical and Chemical Properties

Form: liquid
Colour: colourless
Odour: product specific
Odour threshold: not determined

pH value: approx. 7 (DIN EN 1262)

(50 g/l, 20 °C)

Freezing point: < 5 °C (DIN ISO 2207)

Boiling point: > 250 °C (estimated)

Flash point: approx. 175 °C (ISO 2592)

Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.

Flammability (solid/gas): not self-igniting

Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: > 300 °C (other)

Thermal decomposition: > 350 °C (DTA)

Self ignition: not self-igniting

Self heating ability: It is not a substance capable of

spontaneous heating according to
UN transport regulations class 4.2.

Explosion hazard: not explosive

Fire promoting properties: not fire-propagating

Vapour pressure: < 0.1 hPa (estimated)

(20 °C)
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

Density: approx. 0.96 g/cm3 (DIN 51757)

(20 °C)
approx. 0.93 g/cm3 (DIN 51757)
(70 °C)
Relative density:
No data available.
Relative vapour density (air):
not determined

Solubility in water: insoluble

Miscibility with water:
partly miscible
Hygroscopy: hygroscopic
Solubility (qualitative) solvent(s): Ethanol
soluble
Partitioning coefficient n-octanol/water (log Pow):
not applicable
Surface tension: approx. 27 mN/m (other)
(20 °C; 1 g/l)

Viscosity, dynamic: < 20 mPa.s (DIN EN 12092)

(60 °C)
approx. 80 mPa.s (DIN EN 12092)
(23 °C)

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Conditions to avoid:
See SDS section 7 - Handling and storage.

Thermal decomposition: > 350 °C (DTA)

Substances to avoid:
caustics, halogens, Alkalines, acids, reactive chemicals

Corrosion to metals: Corrosive effects to metal are not anticipated.

Hazardous reactions:
No hazardous reactions when stored and handled according to instructions.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

Chemical stability:
The product is stable if stored and handled as prescribed/indicated.

Reactivity:
No hazardous reactions if stored and handled as prescribed/indicated.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

11. Toxicological Information

Routes of exposure
Acute oral toxicity
Experimental/calculated data:
LD50rat (oral): > 5,000 mg/kg (BASF-Test)
Literature data.
Acute dermal toxicity
LD50 rat (dermal): > 5,000 mg/kg (OECD Guideline 402)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition. Literature data.
Symptoms
Information, i.e. additional information on symptoms and effects may be included in the GHS labeling
phrases available in Section 2 and in the Toxicological assessments available in Section 11.
(Further) symptoms and / or effects are not known so far

Irritation

Experimental/calculated data:
Skin corrosion/irritation rabbit: Slightly irritating. (OECD Guideline 404)

Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405)

Literature data.

Respiratory/Skin sensitization

Assessment of sensitization:
Based on the structure, there is no suspicion of a skin-sensitizing potential.

Germ cell mutagenicity

Assessment of mutagenicity:
Based on the structure, there is no suspicion of a mutagenic effect.

Carcinogenicity

Assessment of carcinogenicity:
Based on the structure there is no suspicion of a carcinogenic effect.

Reproductive toxicity

Assessment of reproduction toxicity:

Based on the ingredients, there is no suspicion of a toxic effect on reproduction.

Developmental toxicity

Assessment of teratogenicity:
Based on the ingredients, there is no suspicion of a teratogenic effect.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

Specific target organ toxicity (single exposure)

Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The information available on the product provides no indication of toxicity on target organs after
repeated exposure.

Aspiration hazard

No aspiration hazard expected.

12. Ecological Information

Ecotoxicity

Toxicity to fish:
LC50 (96 h) > 1 - 10 mg/l, Leuciscus idus (DIN 38412 Part 15)
Literature data.

Aquatic invertebrates:
EC50 (48 h) > 1 - 10 mg/l, Daphnia magna (DIN 38412 Part 11)
Literature data.

Aquatic plants:
EC50 (72 h) > 1 - 10 mg/l (growth rate), Scenedesmus subspicatus (DIN 38412 Part 9)
acute Effect Literature data.

EC10 (72 h) > 0.1 - 1 mg/l (growth rate), Skeletonema costatum (ISO/DIS 10253)
long-term effect The product has not been tested. The statement has been derived from
substances/products of a similar structure or composition. Literature data.

Microorganisms/Effect on activated sludge:

EC10 (17 h) > 2,500 mg/l (DIN 38412 Part 8)

Chronic toxicity to fish:

No observed effect concentration > 1 mg/l, Fish
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition. Literature data.

Chronic toxicity to aquatic invertebrates:

No observed effect concentration, > 1 mg/l, Daphnia magna
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition. Literature data.

Assessment of terrestrial toxicity:

No data available concerning terrestrial toxicity.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

Mobility

Assessment transport between environmental compartments:

The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is possible.

Persistence and degradability

Assessment biodegradation and elimination (H2O):

Readily biodegradable (according to OECD criteria).

Elimination information:
> 60 % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EWG,
C.4-C) Readily biodegradable (according to OECD criteria).

Sum parameter

Chemical oxygen demand (COD): 2,438 mg/g

Bioaccumulation potential

Assessment bioaccumulation potential:

Accumulation in organisms is not to be expected.

Additional information

Add. remarks environm. fate & pathway:

Treatment in biological waste water treatment plants has to be performed according to local and
administrative regulations.

Other ecotoxicological advice:

Inhibition of degradation activity in activated sludge is not to be anticipated during correct
introduction of low concentrations. Do not release untreated into natural waters.

13. Disposal Considerations

Information on disposal regulations: Must comply with regulations on hazardous waste such as:

- Decree No. 08/2022/ND-CP of the Government: detailing a number of articles of the Law on
Environmental Protection.

- Circular No. 02/2022/TT-BTNMT of the Ministry of Natural Resources and Environment: detailing a
number of articles of the Law on Environmental Protection.

Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

14. Transport Information

Domestic transport:
Not classified as a dangerous good under transport regulations
UN number or ID number Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number or ID number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Marine pollutant: no
Special precautions for None known
user

Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number or ID number Not applicable
Proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

15. Regulatory Information

Other regulations
The SDS is composed based on the Global Harmonization Globally Harmonized System of
Classification and Labeling of Chemicals and applicable local chemical regulations as following:
- The Chemical Law 06/2007/QH12 issued on 21/11/2007.
- The decree No. 113/2017/ND-CP specifying and providing guidelines for implementation of certain
articles of the law on chemicals.
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BASF Safety data sheet
Date / Revised: 02.01.2024 Version: 7.1
Product: Lutensol® TO 5
(30044057/SDS_GEN_VN/EN)
Date of print: 19.03.2024

- The decree No. 82/2022/ND-CP Amendments to some articles of government's decree

no.113/2017/ND-CP dated October 09, 2017 specifying and providing guidelines for implementation
of certain articles of the law on chemicals.
- Circular 17/2022/TT-BCT Amendments to some articles of circular no. 32/2017/TT-BCT dated
December 28, 2017 of the Minister Of Industry And Trade on elaboration and provision of guidelines
for implementation of certain articles of the law on chemicals and the government's decree no.
113/2017/ ND-CP dated October 09, 2017 on elaboration and provision of guidelines for
implementation of certain articles of the law on chemicals.
- The decree No. 17/2020/ND-CP Amendments to some articles of decrees related to necessary
business conditions in fields under the management of the Ministry Of Industry and Trade.
- The decree No. 42/2020/ND-CP on list of dangerous goods, transport of dangerous goods by land
motor vehicles and transport of dangerous goods by inland waterways.
- The Circular 32/2017/TT-BCT specifying and providing guidelines for implementation of certain
articles of the law on chemicals and the government's decree no. 113/2017/ND-CP dated October
09, 2017 specifying and providing guidelines for implementation of certain articles of the law on
chemicals.

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. Other Information

Information on intended use:This product is of industrial quality and unless otherwise specified or
agreed intended exclusively for industrial use.This includes the mentioned and recommended
usage.Any other intended applications should be discussed with the manufacturer.In particular this
concerns the application for products that are the object of special standards and regulations.

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.