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TIME:3:00 HOURS
INSTRUCTIONS
1. This paper consists of sections A, B and C.
2. Answer all questions in sections A and B and choose one (1) question from section C.
3. The following constants may be used.
✓ Atomic masses:
[H = 1, C = 12, N = 14, O = 16, Na = 23, Mg = 24, S = 32, K = 39, Ca = 40, Cl = 35.5,
Mn = 55, Fe = 56, Cu = 64, Zn = 65, Pb = 207]
✓ Avogadro’s constant = 6.022 x 1023
✓ Molar Volume at STP = 22.4 dm3
✓ 1 litre = 1000cm3 = 1 dm3
✓ 1Faraday = 96500coulombs
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SECTION B: (70 Marks)
3. (a) Give the meaning of the following:
(i) Empirical Formula
(ii) Molecular Formula
(b) Compound Z has 8.32g of lead (Pb), 1.28g sulphur (S) and 2.56g of Oxygen (O).
What is the simplest formula and molecular formula of Z if molecular weight of
compound Z is 303g/mol?
6. When zinc granules and diluted sulphuric acid are reacted together, a gas M is
produced. The gas produced is collected by downward displacement of water.
Use this information to answer the questions below;
(i) Name the gas M produced
(ii) How is the gas tested?
(iii) Why is the gas collected by downward displacement of water?
(iv) List six apparatus used in the preparation of gas M
(v) Write one use of gas M
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(b) Write down the formulae of the simplest compounds formed when:
(i) A and B combine chemically
(ii) C and D combine chemically
(c) Draw the electronic diagram of compound formed when atoms of element B
react with each other.
10. (a) A solution of metal carbonate was made by dissolving 2.12g in water to make
250cm3 solution. 25cm3 of metal carbonate(X 2 CO3) solution was titrated with 0.25
M HCl by using methyl orange indicator. The following results were obtained.
Volume Pilot 1 2 3
reading cm 3
Volume used
cm3
Questions
(i) Find the average volume used.
(ii) Write balanced chemical equation for the reaction
(iii) Calculate the number of moles of acid used in the reaction
(iv) Number of moles of base used in the reaction
(v) Calculate molarity of base(mol/dm3)
(vi) Calculate concentration of base in g/dm3)
(vii) Calculate molecular mass of metal carbonate.
(viii) Calculate relative atomic mass of X
(ix) Name the metal X
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(i) H2(g) + O2(g) H2O(l)
(ii) NaCl(aq) + H2SO4(l)
(iii) Pb(NO3)2(aq) + Na2SO4(aq)
12. (a) State the first law of Electrolysis.
(b) An element X has relative atomic mass 88. When an electric current of 0.5A was
passed through a fused chloride of X for 32 minutes and 10 seconds, 0.44g of X
was deposited at the cathode.
(i) Calculate the charge in Faradays needed to liberate one mole of X.
(ii) Write the formula of the hydroxide of X.
(iii) Mention any three industrial application of electrolysis.
14. Describe four stages for the extraction of metals. Does extraction of gold follow all
four stages? Give reasons.
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