Question Paper [CODE - 16578]

V-star_Quiz-07
13th JEE (M+A) - Phase 1
KOTA

Duration: 3 Hours Max Marks: 210

 MATHS

1. 4. n
n−1 n−1

If for any n∈N and

tanα+2 tan 2α+4 tan 4α......+2 tan 2 α −1 nπ
If n
= 1, ∑
r=1
sin αr =
2
cotα+2
n r
p = ∏
r=1
(αr ) .
n ∈ N then general solution of α is
1/4
1/3
⎧ x −(3−2x)

(A) α = 2n(nπ +
π
, x ≠ p
4
)
if f(x) = ⎨ x −x
2
is continuous
⎩
π
k, x = p
(B) α = 2−n(nπ − 4
)

at x = p, then find the value of 6(k + p).

π

(C) α = 2-n(nπ + 4
)
(A) 6

(D) None of these (B) 12

2.
2
ln(sec(ex) sec(e x)... sec(e
50
x)) (C) 11
The value of lim
2 2 cosx
is
e −e
x→0
5. The smallest radius of circle which orthogonally
equal to: intersects the circles x2 + y2 = 4 and (x – 6)2 +
e
100
−1
y2 = 2, is
(A) 2
( e −1 )
√119

100
(A) 6
e −1
(B) 2
2 ( e −1 )
√217
(B) 6
50
2(e −1 )
(C) 2
√223
e −1
(C) 6
2 100
e (e −1 )
(D) √131
(D)
2
2 ( e −1 )

3. If
2
⎧ (p − 1)({x} + 2[x]) − 2, − 2 < x ≤ −1

f (x)=⎨ x −x
⎩ e +e ∣ ∣
q( )+ p (x − 1), − 1 < x < 2
2 ∣ ∣

p, q ∈ R is continuous in (–2, 2) then

is:
−1
f (f (f ( )))
2

(Where {*} and [*] represents fractional part

and greatest integer function respectively)

(A) – 2

(B) – 1

(C) 0

(D) not defined

 MATHS

6. In the given figure AO (O being origin) is the 8. Which of the following statement(s) is/are True?
median through the vertex A of the triangle
ABC. Also, given the two upward parabolas P1 (A) P(n): n2 – n + 41 is prime for every n ∈ N.
and P2. ∞ n
1 + 2 n
(B) is rational.
P1 : y = x2 + 2px + q(p, q ∈R) is passing
∑ (ln 2)
n!
through A and has its vertex at B. n=1

P2 : y = ax2 + 2bx + 1 (a, b ∈R) is passing (C) ln ( 1

+
1
+
1
+..........∞ )
1.3 1.2.3.5 1.2.3.4.5.7

through A and has its vertes at C. simplifies to an integer.

Which of the following is'/are correct (D) Coefficient of x5 in (1 – x)–6 is 10
C6
20 20
9. If (2x – 1) – (ax + b) = (x + px + q)10 2

holds true ∀ x ∈ R where a, b, p and q are real

numbers, then which of the following is/are
true?

(A) 2p + 3q = 1

(B) a + 2b = 0
2
(A) the sum of all the roots of the equation (x (C) a = √2
20
20
− 1
+ 2px + q) (ax2 + 2bx + 1) = 0 is zero.
(D) 4q + p = 0
(B) ab > 0
10. Let y = f (x) = in [0, ].
x
2 Limit π
(C) p2 – 1 = q – .
2
b 1+(4 sin x)
n
n→ ∞
a
Which of the following statement(s) is/are
(D) ap + b = 0. correct?

7. Consider the function f: R →A given by f(x) = x (A) f(x) is discontinuous at one value of x in [0,
+ [x] where [x] denotes greatest integer less π].

than or equal to x and A is the range of the

function. Then which of the following is/are (B) f(x) is discontinuous at two value of x in
[0, π]
correct?
(C) Derivative of tan–1x w.r.t. f (x) at x = 1
is
(A) f–1(x) exists and is given by f–1(x) = x –
[x]
2

.
2 4

x A
∀ ∈ 5

(B) f–1(x) exists and is given by f–1(x) = x – [x] (D) y'( π6 ) =

1

2
∀x ∈ A

(C) f(x) is an continuous function.

(D) f–1(x) is a continuous function.

 MATHS

Passage: Passage:

Let P(x) = x5 – 9x4 + px3 – 27x2 + qx + r (p, Let Vr = (xr, yr) is the vertex of the parabola Pr
q, r ∈ R) be divisible by x2 and α, β and γ
:y= .
1 r 2 1
2
(2 x − 2x +( r + 2))
P(x) 2 2
are the positive roots of the equation 2
= 0.
x
13. Let L is the line passing through V3 and
11. If α – 1, β + 3 and γ + 7 are the first three perpendicular to the line joining V1 and V10. If
terms of a sequence whose sum of first n terms intercepts made by L on co-ordinate axes are a
∞
is given by Sn then ∑n=2 1
is equal to and b, then 16(a + b) is equal to
√ Sn ⋅ Sn−1

(A) 20
(A) 1
(B) 15
(B) 1

4
(C) 1
(C) 1

(D) 25
2

(D) 2 14. Equation of the tangent to the circle at its point

∞ ∞
origin whose centre is (∑r=1 xr , ∑r=1 yr ), is
12. The value of
1 1 1
⎛ p+q+r
+ 2
p +q +r
2 2
+ 3 3
p +q +r
3 ⎞ (A) x + 2y = 0
lim is equal
n→∞ ⎝ +.... +
n
p +q +r
1
n n
⎠ (B) 2x + y = 0
to: (C) 4x + y = 0
(A) 1
(D) x + 4y = 0
26

(B) 1

27

(C)
25

26

(D)
26

27
 MATHS

15. Colulmn - I
Colulmn
- II
⎧ sinx, x ≤ 0
⎪
⎪
⎪
⎪
tanx, 0 < x < 2π
Let f(x) = ⎨ , then number
cosx, 2π ≤ x < 3π
(A) ⎪
⎪
⎪
⎩
⎪
(P) 1
−1 x = 3π

of points where f(x) is discontinuous in [0, 3π] ,

is
f(x) = f (x)=

2
⎧ x
⎪
⎪2( 2
+ 2
) + k, x ≠ 1, 2, 3
⎪
⎪
x −3x+2 x −5x+6
⎪
⎪
⎪
⎪
⎪ 5, x = 1
⎪
⎪

⎨
(B) lim (
π
), x = 2
(Q) 3
⎪ n
⎪
⎪ −1
tany

⎪ y→0 sec ( )
⎪
⎪
y

⎪
⎪
⎪
n→∞
⎪
⎩
⎪
10, x = 3

If f(x) is continuous at x = 2, then the

value of k, is

Let f(x) = x – 2, then the number of points

(C) (R) 5
where tan–1(|f(|x|)|) is non-differentiable, is
(S) 8

(A) A-Q; B-S; C-Q

(B) A-S; B-R; C-P

(C) A-Q; B-S; C-P

(D) A-S; B-P; C-Q

 MATHS

16. If [.] denotes the greatest integer function and 18. Let ∑
n r
4

=
n
3

+
n
2

+
5n
+
f (n)

let f be a function defined on the set of all non- r=1 (2r−1)(2r+1) A B C D

negative integers and taking values in the same (A, B, C, D ∈ N) , where f(n) is the ratio of
set. Given that − two linear polynomials such that lim f (n) =
1
.
2
x→∞

(A) x − f(x) = 20[ 20 ]−10[

x
f (x)
] for all non Find the value of (A – B).
10

negative integers 19. If α , β and γ be three distinct real values such

sinα+sinβ+sinγ cosα+cosβ+cosγ
that = = 2 and
(B) 2008 < f(2010) < 2012 sin ( α+β+γ ) cos ( α+β+γ )

cos(α + β) + cos(β + γ) + cos(γ + α)= a ,

then find the sum of all possible distinct values √x −a
2 2

f (2010) then find the value of lim

of
1
[ ] x→∞ √x−a+√x−√a
10 100

20. A cirlce of radius 1 unit touches the positive X-

17. Let A(at21 , 2 at1 ) ; B(at22 , 2 at2 ); C(at23 , 2 at3 ) be
three points on the parabola y2 = 4ax. If the
orthocentre of the triangle ABC is at the focus,
then find
| t 1 + t 2 + t 3 + t 1 t 2 t 3 + t 1 t 2 + t 2 t 3 + t 3 t 1 |.
axis and positive X-axis and positive Y-axis at P
and Q respectively. A variable line L passing
through the origin intersects the circle in two
points M and N. If m is the slope of the line L for
which the area of the triangle MNQ is maximum,
then find the value of 201 (m2).
 PHYSICS

1. An infinite no of bricks are placed one over the
others as shown in the figure. Each succeeding
brick having half the length and breadth of its
preceding brick and the mass of each
succeeding bricks being 1/4th of the preceding
one, take ‘O’ as the origin, the centre of mass of
the system of bricks is at
3. A square of side L/2 is removed from one corner
of a square sandwich that has sides of length L.
The center of mass of the ramainder of the
sandwich moves from C to C'. The displacement
of the x-coordinate of the center of mass (from
C to C') is

√2
(A) 12
L

(B) 1

12
L
(A)
a
−
7
(C)
1
L
6
(B)
5a
−
7
√2
(D) L
(C)
3a 8
−
7

4. The gap between any two rails, each of

(D)
2a
−
7
length l laid on a railway track equals x at 27°C.
When the temperature rises to 40°C, the gap
2. Find the coordinates of centre of mass of a closes up. The co-efficient of linear expansion of
uniform semicircular closed wire frame with the material of the rail is α . The length l of a
respect to the origin which is at its centre. rail at 27° C will be
Radius of the circular portion is R

(A) x

26α

(B) 2x

13α

(C)
x

13α

(A) (
4R
, 0)
(D) none of these
3π

5. If a steel band were to fit snugly around the

(B) (
2R
, 0) Earth's equator at 25oC, but then was heated to
π+2
45oC, how high above the earth would the band
be (assume equal everywhere)?
(C)
2R
( , 0)
(Take : for steel to be 12 × 10-6/oC)
π
α

(D) (
R
, 0) (A) 1.028 km
π+2

(B) 1.536 km

(C) 2.062 km

(D) None of these

 PHYSICS

6. A cylindrical metal rod M stands on the table. 8. A smooth track in the form of a quarter circle of
Also standing on the table is a sylinder L radius 6 m lies in the vertical plane. A particle
containing a liquid. The cylinder L is made of a moves from P1 to P2 under the action of forces
glass called "invar", which does not expand or → → →

contract on change in temperature. Suppose the

F 1
, F 2 and F 1 is always toward P2 and is
→
temperature of the room is increased with always 20 N in magnitude. Force F always
2
corresponding unfirom increase in temperature acts horizontally and is always 30 N in
of both systems L and M. Both the metal and →
the liquid undergo expansion with increase in magnitude. Force F 3 always acts tangentially
temperature. to the track and is of magnitude 15 N. Select
the correct alternative(s)

→
(A) work done by F 1 is 120 J
→
(B) work done by F 2 is 180 J
(A) The pressure at the bottom of M will remain →
exactly same as the rod gets longer (C) work done by F 3 is 45 π

(B) The pressure at the bottom of M will →

decrease slightly as the rod expands (D) F 1 is conservative in nature

(C) The pressure at the bottom of the liquid in L
will increase as the temperature increases
(D) The pressure at the bottom of the liquid in L
will remain unchanged as the temperature
changes.
9. A ball of mass 'm' is rotating in a circle of radius
'r' with speed v inside a smooth cone as shown
in figure. Let N be the normal reaction on the
ball by the cone, then choose the correct option.

7. Which of the following are not dependent on the

intensity of the incident radiation in a
photoelectric experiment?

(A) Amount of photoelectric current

(B) Stopping potential to reduce the (A) N = mgcosθ

photoelectric current to zero
2

(B) gsinθ
v
= cosθ
(C) Work function of the surface r

(D) Maximum kinetic energy of photoelectrons (C) Nsinθ −

mv
= 0
r

(D) none of these

10. Ammonia is undergoing a thermodynamic
process ABC as shown by T-V indicator diagram
here.

(A) Step AB of the process is isobaric

(B) Work done by gas is positive in the entire

process

(C) Internal energy of the gas first increases

and then decreases during the process

(D) Internal energy of the gas decreases

continuously during the process
 PHYSICS

Passage: 12. What is the value of eV?

The circuit shown is placed in vacuum. Both the (A) E

capacitors are identical and they have the same
capacitance C. Light is incident on the left plate (B) E1
of the upper capacitor. When all the switches (C) E + E1
are open then the hf versus KEmax is shown by
the straight line (A). In all the cases, we are (D) none of these
measuring the KEmax when the electron reaches
the opposite plate. Passage:

A horizontal cylindrical container has adiabatic

walls. It is fitted with a conducting piston of
area A and thickness L. The coefficient of
thermal conductivity is K. The piston can move
without friction in the container. The enclosed
gas is Helium at a temperature of 400 K. The
surrounding is at 300 K and at atmospheric
pressure (105 Pa)
The system is allwed to cool. The initial length
of gas column is 4m.
When only S1 the switches and S2 are closed,
the graph becomes (B).

When only S3 and S4 are closed then the graph

becomes (C).

13. What is the final length of gas column?

(A) 3m

(B)
15
m
4

(C) 2.25 m

11. What is the work function of the cathode? (D) 5.25 m

(A) E 14. What is the temperature of gas as a function of

time?
(B) E1
− Kt

(A) 300 + 100e 2500L

(C) E + E1
− Kt

(D) none of these (B) 400 − 100e 2500L

− Kt

(C) 400 − 100e 1500L

Kt

(D) 300 + 100e 1500L

 PHYSICS

15. Column-I depicts certain situation where we

have a variable A. Comment on variable A in
each of situations.

Column-I Column-II
Force of 10t is applied. 'A' is normal
force applied by ground

A is
(A) (P)
constant

A is
increasing
with time
and then
A block of ice at -20oC is heated in a
(B) (Q) becomes
container. 'A' is its temperature.
constant
at least
for some
time.
The velocity-position graph of a
particle moving on a straight line is
shown here. 'A' is magnitude of its A is
acceleratio. decreasing
with time
and then
(C) (R) becomes
constant
at least
for some
time.

A is
constant
for some
time then
(D) (S)
increases
at least
for some
time.
A is
constant
for some
time, then
(T)
decreases
at least
for some
time.

(A) (A) R (B) Q, S (C) T (D) P

(B) (A) Q,S (B) R (C) T (D) P

(C) (A) R (B) T (C) Q,S (D) P

(D) (A) R (B) Q, S (C) P (D) T


16. A small particle slides from height H = 45 cm as
shown and then loops inside the vertical loop of
radius R from where a section of angle θ = 60o
has been removed. Find R (in cm) such that
after losing contact at A and flying through the
air, the aprticle will reach at the point B. Neglect
friction everywhere.
17. In the situation shown in the figure, three
lenses of focal lengths 20 cm, 30 cm and 36 cm
are held coaxial such that separation between
first and second lens is 12 cm and between
second and third lens is 10 cm. If the final imae
of an object at a distance of 30 cm from first
lens is at a distance 10x from the middle lens
then find the value of x.
18. A point object is placed in air at a distance d
from the pole of a refracting convesx surface on
its principal axis & it starts moving with speed v
perpendicular to its principle axis as shown in
figure. Find the speed of its image if the radius
velocity of
of the convex surface is d. Fill ∣
∣
velocity of
in OMR sheet.
PHYSICS
19. A ring of radius r made of wire of density ρ is
rotated about a stationary vertical axis passing
through its centre and perpendicular to the
plane of the ring as shown in figure. Find the
percentage change in tension for two percent
increase in angular velocity of rotation. Ignore
gravity.
20. Two swimmers P and Q start swimming from
different positions on the same bank as shown
inthe figure. The swimmer P swims at an angle
90o with respect to the river to reach point A.
He takes 120 second to cross the river of width
10 m. The swimmer Q also takes the same time
to reach the point A. The velocity component of
Q along x-axis with respect to ground is K/24.
Find the value of K.
image
∣
∣
object
 CHEMISTRY

1. Which of the following is correct order of – I ? 4. The vapour pressure of an aqueous solution is
found to be 750 torr at certain temperature 'T'.
(A) –F > – NO2 > – CN > Br If 'T' is the temperature at which pure water
boils under atmospheric pressure and same
(B) solution show elevation in boiling point ΔTb =
1.04 K, find the atmospheric pressure (Kb =
0.52 K kg mol–1 )
(C)
(A) 777
(D)
(B) 779
2. The equilibrium constant for the reaction CO(g)
+ H2O(g) → CO2(g) + H2(g) is 4. How many (C) 782
moles of CO2 must be added to 1 liter container
(D) 746
already containing 3 moles each of CO and H2O
to make equilibrium concentration of CO 2 5. How many geometrical isomers and
mole/L. stereoisomers are possible for
+

(A) 15 [Pt(NO2 )(NH3 )(NH2 OH)(Py)] and

[Pt(Br)(Cl)(I)(NO2 )(NH3 )(Py)] respectively
(B) 10
(A) 3 and 15
(C) 5
(B) 3 and 30
(D) 20
(C) 4 and 15
3. Dimethyl glyoxime forms a square planar
complex with Ni2+. This complex should be : (D) 4 and 30

(A) diamagnetic

(B) paramagnetic having 1 unpaired electron

(C) paramagnetic having 2 unpaired electrons

(D) ferromagnetic
 CHEMISTRY
6. Select the correct order among the following:
(A) Order of heat of hydrogenation
(B) Order of heat of combustion
(C) Order of resonance energy
(D) Order of basic strength
7.
True about this compound is
(A) Most acidic H is at b
(B) Most basic part is g
(C) Number of functional group other than
alkane is 5
(D) Principle functional group is amide.
8. A cubical crystal is such that the corners atoms
are occupied by P atoms, face centers are
occupied by Q atoms, alternate tetrahedral
voids are occupied by R atoms and edge centers
are occupied by S atoms. Based on this info
identify the correct option.
(A) If there are no defects in the crystal then
the formula should be PQ3R4S3.
(B) If all the atoms lying on one of the body
diagonal are missing then formula should be
PQ4R8/3S4
(C) If all the atoms lying on a line passing
connecting edge centers are missing then
formula should be P2Q5R8S5
(D) If all the atoms lying on a line passing
through body center & connecting opposite face
centers are missing then formula will be
PQ2R4S3.
9. Which of the following complexes are
diamagnetic:
−
(A) [AuCI4 ]
3+
(B) [Co (H2 O) ]
6
(C) [CoF6 ]
3−
−
(D) [Co (CO) ]
4
10. Which of the following statements is/are
correct?
(A) In Fe2(CO)9 all CO bond length are not
equal
(B) In Fe2(CO)9 ,3 CO bond length are larger
rest of six are smaller than these three.
(C) Suppose bond length of CO is 1.128Å and In
Fe2(CO)9 all CO bond length are larger than
1.128Å.
(D) Fe2(CO)9 is an organo metallic compound.
 CHEMISTRY

Passage: Passage:

10 moles of pure PCl5 gas is put into a closed

container of volume 'V' and temperature 'T' and
allowed to come at equilibrium, at an
equilibrium pressure 20 atm. The pure PCl5 is
found to be 50% dissociated at equilibrium.
PCl5(g) ⇌ PCl3 (g) + Cl2(g)
11. Kp for the above the reaction is

(A)
20

(B) 100
13. Correct order of basic strength
(C)
10

3
(A) e > g > f > h
(D)
20

6 (B) e > g > h > f

12. The partial pressure of PCl5 , if equilibrium is (C) g > e > f > h
restablished at new equilibrium pressure 35 atm
by changing volume, is (D) g > e > h > f

(A) 10 atm 14. Correct order of C–H bond energy.

(B) 15 atm (A) k < i < j < a

(C) 18 atm (B) k < a < i < j

(D) 12 atm (C) a < k < i < j

(D) i < k < a < j

 CHEMISTRY

15. Column I Column II

Geometrical
(A) [Pt(NO2)2(NH3)2] (P)
isomerism
[Pt(NH3)4] Linkage
(B) (Q)
[Pt(CN)4] isomerism
Coordination
(C) [Pt(NO2)2(CN)2] (R)
isomerism
More then 4
(D) [Pt(SCN)4]2– (S) linkage
isomers
Select the correct option

(A) (A) P, Q, R (B) Q, R, (C) Q, S (D) P, R

(B) (A) P, Q, S (B) Q, R, S (C) P, Q, S (D) Q, S

(C) (A) Q, S, R (B) R, S (C) P, Q (D) P, S

(D) (A) P, Q, R, S (B) P, Q, R (C) Q, S (D) P, Q

 CHEMISTRY
16. Consider following compounds & give number of
compounds which have HOH higher than
17. The reaction A(aq)→ B (aq) + C (aq) is
monitered by measuring optical rotation of
reaction mixture at different time interval. The
species A, B and C are optically active with
specific rotations 20°, 30° and – 40°
respectively. Starting with pure A if the value of
optical rotation was found to be 2.5° after 6.93
minutes and optical rotation was –5° after
infinite time. Find the rate constant for first
order conversion of A into B and C.
[Divide your answer by 10]
18. Number of planar species showing fractional
bond order of either of X – O / O – O / X – X (X
= central atom) is CO3 , PO4 , SO4 ,
−2 −3 −2
, , ,
Θ Θ
CH3 COO C 6 H6 H2 PO2 O3
19. Number of compounds in which orbitals used for
overlapping by cnetral atom is equal to orbitals
used by central atom for hybridisation.
PCl5 , XeO4 , H2 SO4 , POCl3 , IF5 , XeO ,
−4
6
Θ
ClO3
20. If X, Y and Z are the coordination number of Al
/ Be in solid AlCl3 , fused AlCl3 and solid BeCl2 ,
find the value of (X + Y + Z).
ROUGH-WORK
ROUGH-WORK
ROUGH-WORK