Term1, Practice Test (2021-22)

CLASS- XI1
SUBICT CHEMISTRY (043)

MM-35
NENA INNTRU O N S :

Nmd ihe Rthminy instmwtiomns earelully.

h an 12 quevtivms in this question paper with internal choice.

marks cach.
N TR ON A - O. No. I to 3 ane very short answer questions carrying 2
N. 4 to Il are short answerquestions carrying 3 marks cach.
4. N DN(Q No. 12 is ease based question earrying 5 marks.
.Al estims are vommmlsory.
o.se otog tadles and caleulators is not allowed
SECTION A

Questim Questions Marks

Show that in a first order reaction, time required for completion of 2

99,0% is 10 times of half-life (tu2) of the reaction.

Account for the following: 1+1
i)Aldehydes are more reactive than Ketones towards Nucleophilic
addition reaction.
()There are two - NH group in semi carbazide however only one is

involvod in the formation of semi carbazones.

Give a ehemical test to distinguish between following pair of organic 1+1

compounds
)Acetophenone and Benzophenone
i)Methanoic acid and Ethanoic acid
SECTION B
(i) What is the sign of AH & AS when a gas is adsorbed by an | 1+1+1
adsorbent.
i) Explain what is observed when Electric current is passed through
a colloidal sol.
(ii)Most eflective electrolyte causing the coagulation of
FeyO,l1,0/Fe" is
a) MgCl b)KCI ¢)K4[Fe{CN)%] d)AICl)
Give Reasons for the following: 1+1+1

OC
SHOT ON UICU
 for
much more positive than that
(i) E"value for the Mn "/Mn couple
Cr/CorFet/Fe2*.
is a liquid.
Chromium is a typical hard metal while mercury
(ii)
moment of a divalent ion in aqueous
iii)Caleulate the magnetic
solution if its at.no is 25.
1+1+1
6. (a) Account for the following:

(i)Aromatic primary amines cannot be prepared by Gabriel

phthalimide synthesis.
butanamine boils at
(ii) N-cthylethanamine boils at 329.3K and

350.8K, although both are isomeric in nature.

order of
(b) Arrange the following in increasing
C2HsNH2 CoHsNHCH3, (C2Hs) 2NH, CoHsNH2(basic strength)
OR
Convert the following:
i)Ethanoic acid into methanamine

(ii) Aniline to chlorobenzene

(ii) Methanamine into ethanamine
7. i ) Write the formula of the following compound: 1+1+1

tetraammineaquachloridocobalt(II) chloride

Gi)Fe(H,O) ]*" isstrongly paramagnetic while [Fe(CN)]*" is

weakly paramagnetic.
(ii)Co is easily oxidised to Co" in the presence of a strong ligand.
OR

Draw diagram to show splitting ofd- orbital in octahedral crystal

field. Explain the two patterns of filling d in octahedral crystal Field.

8 What is Lanthanoid contraction? Give its cause. What are its 1+1+1

Consequences. (any two)

OR

Among Elements of 3d transition series are given as:

Element Sc TiVCr Mn Fe Co Ni Cu Zn
Answer the following:

i)Write the element which shows maximum number of oxidation

states.
() Write the element which can show an oxidation state of +1.

11) Write the element which is not regarded as transition element.

 Why?
() Name the following compounds according to IUPAC system of 1+1+1
nomenclature:

CH3CH-CHCHO
(ii)State the following:
(a)Canizzaro Reaction
(b)Hell Volhard Zelinsky Reaction
OR
An organic compound A with molecular formula CsH16O2 was

hydrolysed with sulphuric acid to give a carboxylic acid B and alcohol

c. Oxidation of C with chromic acid produced B. C on dehydration

gives but-1-cne. Write reactions involved.

10. For a chemical reaction A +2B 2C+D. 1+1+1
The experimentally obtained information is given below.
Experiment [A]o [B]0 Initial rate

0.30 0.30 0.096

0.60 0.30 0.384

0.30 0.60 0.192

4 0.60 0.60 0.768

(i)Derive the order of reaction w.r.t. both the reactants A and B.

(ii) Write the rate law.

(ii) Calculate the value of rate constant k.

11. Ci) How will youdifferentiate between primary, secondary and tertiary1atlia |

amines.

Complete the following:

(i) CH CoOH A-NaOHBBCHCL, +Alc-.KOHc

SECTION C
12. Read the passage given below and answer the questions that follow:
Galvanic or voltaic cells involve spontaneous electrochemical
reactions in which the half-reactions are separated (Figure2) so that
current can flow through an external wire. The beaker on the left side
of the figure is called a half-cell, and contains a 1 M solution of

SlieT olN M LOU

 metal partially
[Cu(NO1)2] with
a piece of copper
copper(11) nitrate
electrode. The
The copper
metal is an
the solution.
submerged in
is
oxidation; therefore, the copper electrode
copper is undergoing
and the
voltmeter with a wire
the anode. The anode is connected to a

other terminal of the voltmeter is connected to a silver electrode by a

the silver electrode

wire. The silver is undergoing reduction; therefore,
is the cathode. The half-cell on the right side of the figure consists of
the silver electrode in a 1 M solution ofsilver nitrate (AgNO;). At this
point, no current flows-that is, no significant movement of electrons
through the wire occurs because the circuit is open. The circuit is
closed using a salt
bridge, which transmits the current with moving
ions. The salt bridge consists of a
concentrated, nonreactive,
electrolyte solution such as the sodium nitrate
in this
(NaNO,) solution used
example. As electrons flow from left to
electrode and wire, nitrate ions
right through the
on the left into
(anions) pass through the porous plug
the copper(II) nitrate
solution. This keeps the beaker
the left on
electrically neutral by neutralizing the
ions that are charge on the copper(II)
produced in the solution as the
At the same copper metal is oxidized.
time, the nitrate ions are
moving to the left, sodium ions
(cations) move to the right,
through the porous plug, and into the
nitrate solution on the silver
right. These added cations
ions that
removed from the solution
are "'replace" the silver
metal, keeping the beaker on
as
they were reduced to silver
the right
salt
bridge, the electrically neutral. Without the
compartments would not remain
and no
significant current would flow. electrically neutral
compartments are in direct contact, salt However, if the two
instant the circuit is bridge is not necessary. The
a

called the cell

completed, the voltmeter reads +0.46
V, this is
potential. The cell potential is
dissimilar metals are created when the two
unit
connected, and is a measure of the
charge available from the energy per
In this
equation, A is the currentoxidation-reduction
in
reaction.
coulombs. Note that volts amperes and C the charge in
must be
coulombs (C) to obtain the multiplied by the charge in
energy in joules (J).
 IOw t annon
OH6u Eow ot ontiona
Cuante NOJ Na Au antlhote

Sall bridcje (NaNOJ)

cu Porous Ag
pug
NOa
1 M solution ot 1 M solutton oof
copper (10) nitrate siver nitrate
(Cu(NOs)) (AgNOa

Figure 2. In this standard galvanic cell, the half-cells are separated;

electrons can flow through an external wire and become available to

do electrical work.
When the electrochemical cell is constructed in this fashion, a positive

cell potential indicates a spontaneous reaction and that the electrons

are flowing from the left to the right.

l
() Why is a saltbridge necessary in galvanic cells?
i) From the information provided, use cell notation to describe the 1
following system: One half-cell consists of a silyer electrode in a I M

AgNO solution, and in the other half-cell, a copper electrode in 1 M

Cu(NOs)2 is oxidized.
The standard cell potential for Daniell cell is 1.1 V. Calculate the
(iii)
standard Gibbs energy for the cell reaction.
(F 96,500 C mol')
Calculate the emf of the cell at 25 C in which the following reaction 2
iv)
takes place:

Ni(s) +2Ag' (0.002 M) ->Ni* (0.160 M) +2Ag(s)

Given that E (cel)= 1.05 V.(Log4=0.6020)
OR

Calculate the emf of the following cell at 25°C

Cu (10 m) | Cus) || Ag (10" M) |Ags)
Eeoll=+0.46 V and log 10" n.
=

Given