01. What is the sign of (AH) for an ideal solution?

SECTION-A
BYJUS [1
Q2. What are elementary reactions?
1
Q3. What is the oxidation state of chromium in Cr203 [1
Q4. Write the lUPAC name of the given compound

-CH-CH [1

Q5. Explain why chloroform is kept in a dark coloured bottle rather than in the ordinary bottle.
Q6. Name the cathode used in dry cell.

SECTION-B
Q7. Calculate the magnetic moment of Mn2* ion.
Q8. For
CH3CHO(g) CH(g) +CO(g); Rate k[CHCHO]3. =

Determine the order of the reaction and unit of rate constant.

Q9. Write the formulae for the
following coordination compounds
(a) Tetraammineaquachloridocobalt(l) chloride
(b) Dichloridobis(ethane-1, 2-diamine) cobalt(l1) ion
(1)
One Year Medical-2023 Subjective Test-04 Code-B
Q10. 1.0 g of a non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benz
0.40 K. The freezing point depression constant of benzene is 5.12 K kg mol-. Find the molar maco
solute. [21
Q11. Account for the following:
amines takes place more readily than benzene,
(a) Electrophilic substitution in case of aromatic [11
soluble in water.
(b) Ethylamine is soluble in water whereas aniline is not
OR

(a) Aniline readily reacts with bromine to give 2, 4, 6-tribromoaniline.

(b) Aniline does not undergo Friedel-Crafts reaction. (21
SECTION-C

Q12. What are nucleic acids? Give the difference between nucleoside and nucleotide. 131
Q13. A first order reaction takes 30 minutes for 50% completion. Calculate the time required for 90% completion
of this reaction (log 2 = 0.3010).
31
Q14. A solution of [Ti(H2O)3* is violet in colour. Explain according to crystal field theory. Also calculate the
magnetic moment of this complex. [31
Q15. What are emulsions? What are their differenttypes? Give one example of each type. [31
ww.w
OR
Give reason for thé following 31
() high enthalpy of atomisation
Transition metals have
Fe/Fe redox couple has less positive electrode potentialthan Mn"/Mn couple
(ii) Copper (1) has dl configuration, while copper (1)hadd' configuration, still copper (1) is more stable in
aqueous solution than copper (1)
Q16. Predict the products of the following reactions. 131
() B,HTHF
(a) CH-CHECR () HOJOH
(6)CH,OHB,laq)
CH,CH,OH CUS73(K
Q17.The conductivity of 0.2M solution of KCI at 298 K is 0.0496 S cm1. Calculate its molar conductivity. 131
OR
How much charge is required for the reduction of 1 mole of MnO into Mn2t2 31
Q18. Draw the structures of major monohaloproducts formed in each of the following reactions
CH,CH Bra
(a) UV light 11
NO,
Et
(b) + HBr [11

OH

( (c) +SOClh [11

SazyastH
 Subjective Test-04_Code-B One Year Medical-2023

Q19. Write the structures of compounds A, B and C in each of the following. (31
Br

(a) Mg/dry ether Aa B C

(b)HO

(b) CH.CN (a)(b)H,0

SnCl,HC AdilNaoHB C
Q20. (a) State Raoult's law for a solution of volatile liquids. [11
(b) Under what conditions, a solution shows negative deviation from Raoult's law? 1
(c) Classifythe following solutions into positive and negative deviation from Raoult's law [11
(i) CHCls+CsHs
(i) CHCOCH3 +CaHsOH
Q21. (a) Write the mechanism of acid dehydration of ethanol to yield ethene.
(6) Give reason for the higher boiling point of ethanol in comparison to methoxymethane.
Q22. (a) Arrange the following amines in increasing order of basic strength in water
CaHsNH2, (CaHs)NH, (CaHs)»N, NH [11
(b) CHl+AgNO2 Maie A Sn/HC B
(Major product)
Identify A and B in the given reaction.
(c) Write the chemical equation for the conversion of nitrobenzene into chlorobenzene.
023. The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the
energy of activation of the reaction assuming that it does not change with temperature.
IR= 8.314JK mo, log 4 =
0.6020] [31
Q24. Differentiate between SN1 and SN2 mechanisms and give examples.
131
AAAAV ASECTION-D
Q25. (a) A solution of CuSO4 is electrolysed for 10 minutes with a current of 1.5 amperes. What is mass of copper
deposited at the cathode?
21
(6) The conductivity of 0.001028 moll aceticacidis4.95 10 S cmr, Calculate its dissociation constant
if 2 for acetic acid is 390.5 S cmmo

OR
(a) The standard electrode potential for Daniell cell is 1.1 V. Calculate the standard Gibbs energy for the
reaction.
[21
(b) Calculate the e.m.f. of the cell in which the following reaction takes place

Ni(s) + 2Ag (0.002 M) NP (0.160 M) +2Ag(s)

Given that Eel
cell
1.05 V
[31
Q26. (a) Carry out the following conversions:
[31
(i) 2-chloropropane to propanal
(ii) Benzaldehyde to benzophenone
(ii) Benzamide to toluene
(b) Give one example each of
(2
S a z i 0nl phthalimide synthesis
(ii) Clemmensen reduction
 Subjective Test-04 Code-B
One Year Medical-2023
OR
basic strength in gaseous phase
in the increasing order of
(a) Arrange the following [11
(CoHs)2NH, (C2Hs)3N, NH3, CeHsNH2, (CsHs)2NH
Give the structures of A, B and C in the following reactions [2
(b)
(i) CH,COOH A
A NaOBr- NaNO,/HCC
(i) CoH,CN A0di. NaOHB
(ii) A

(c) Give simple tests to distinguish between thelfollowing pair of compounds [21
() Benzoic acid and benzaldehyde
(i) Butanone and Butan-1-ol

Q27. (a) Complete the following reactions:

() C,O+ MnO +H*

(i) F+MnO +H,O (2]

(b) Answer the following [31
(i) Silver atom has completely filled d-orbitals (4d10) in its ground state. How can you say that it is a
transition element?
(i) Which first row transition metal exhibits the highest number of oxidation state and why?
ii) Which is a stronger reducing agent between Cr2 and Fe and why?
OR
(a) Complete the following reactions [21
() CrO +2H* YJU
Y
(Gi) Cr0 +20H
(b) () What is the common oxidation number of lanthanids elements
i) Actinoid contraction is greater from element to element as compared to Lanthanoid contraction.
Why?
(ii) Why the highest Mn fluoride is MnF4 whereas the highest oxide is Mn2O7
(3]

Sazyasachi