He Aspire NBER EAU This time isto be spent in roadliis fl NN at the head of this paper is the time pany four ques tions at wm Section B. _ Section an compulsory. Aten The intencte, ques d marks for questions oF SECTIONA rom this Section ) westions fre Question 4, (Attempt all que Choose the Correct answers to the questions from the given options (Ponet copy the questions, write the correct answers.oniy) () The structural isomer of butane contains carbon ato ae 3 Hof vend bromide vt (®) The following informations are regarding the electrolysis of !ea at cathode and anode respectively, | Solid, bromine vapour lead IL Solid, lead, bromine vapour lI molten, bromine vapour and lead IV. molten, lead, bromine vapour (d) 2 Which is the true information? | and IV (@) only (2) only iv (b) only It 7 ae em (iii) The trend in which periodic property decreases ied 7 one character (b) Non . (2) Electronegativity (@) Electron affinity (c) Atomtic radii dergoes are : 7 hat a metal under ) During an ionic bonding the changes (b) looses electrons and gets oxidised (@) looses electrons and gets reduced s and gets oxidised (c) accepts electrons and gets reduced (d) accepts electron gcua ber of acid salts formed by nitric acid are The nul es (2 41 Pr 5 10 h silver nitrate solution andfotiowed ide salt reacted will 0d by excess of ammonium hydra: hows f) Aerio! the following observations F saints: fay white prerptate Insoluble In excess ©) white precipitate sotubie in excuse (@) yellow precipitate insoluble In excess (6) bluish white precipitate. sone = Vapour densiy of 2 gas relates which of the two physical properion rere diag bileririabecees gas and hydrogen unin {a) Volume of the unknown gas and mass of hydrogen (b) Mass of the hydrogen and mass of the unknown gas {c) Mass of the unknown gas and mass of hydrogen {¢) Mass of unknown gas and the volume of hydrogen The molecule C3H, belongs to the family of (2) alkynes (b) alkanes (©) alcoho! )) Sugar charcoal is produced when conc. sulphuric aci sulphuric acid is seen here? (a) drying agent {c) dehydrating property ) The correct arrangement of ions accordin; few drops and then excess ammonium Observations 1. blue precipitate that turns to deep blue solution 2. white precipitate that becomes soluble 3. white precipitate that remains insoluble 4. no formation of the precipitate (a) Cu®*, Pb, Zn?*, Cae (b) Feo, pp2> Fez (@) athenes reacts with sugar crystals Which property of (0) oxidizing agent (@) as non volatile acid 9 {0 their observation in the colour of the precipitate when hydroxide is added to some of their solutions cut () Fe’, Cu?*, Zn2*, Mig? (@) Cur, Zn2*, Pb, Care Hydrogen chloride gas is ______ to moist litmus suggesting that t has a pH value of (@) acidic, less than 7 (b} neutral, equal to 7 (c) neutral, less than 7 (d) acidic, more than 7 ‘Ammonia reacts with copper oxide to form copper. The colour of the solid reactant here is (a) Red (©) Yellow (6) Brown () Black The V.D. of the third member of the alcohol family is (a) 30 (b) 60 (c) 40 (@ 45 Which of the following conditions are appropriate for electroplating an object? (2) Direct current, more time (b) Direct current, less time (c) Alternating current, more time (@) Alternating current, less time The colourless gas is formed when copper reacts with nitric acid that is (a) cold and concentrated (b) hot and diluted (0) cold and dilute (@) hot and concentratedCHEMISTRY 1st =X: 2078 He with silver Answer ing of an artic EF the Question 2. id answer the following ce ati () The diagram given below shows the bas = based on the process. Study the diagr i Battery Ammeter Block of silver Article to be plated “Electrolyte (@) Name the electrolyte used in the process (b) Why is the article made the cathode? (©) Wate down the electrode reactions (@) Why AQNOs is not used as the electrolyte? (0) Match the following Cotumn 1 with Column 1 Column 1 Column 11 (@ Hol (Cron (b) Silver nitrate (i) Pyrosulphunie acid (6) _HySO, (ii) Non polar molecule (oN, (w) Polar molecule (e)_H,8,0, () _Dehydrating agent (c) The colourless gas that becomes feddish brown, when it comes (nitrogen / nitric oxidey "P contact with oxygen is (@ Duralumin is an alloy of the base metal (e) Electronegativity of an element refers to the (attraction t 5 te a towards iself when bonded in a compourg SeePtENC8) of & pair of elec Identity the followingCOTY aa te nergy that is released when the chlorine atom by, ee comes a chi 4a) TH nin excess during the Ostwald's proces. {e) The gas taker ructural formulae of (a) Draw the st 4, 2— methyl propan ~ 2 ~ of 2. Ethanal 3, But-2-ene (0) Name the following organic compounds according to pag i ie 1 OH 2 cH $-0 is—CH,, SECTION B (Attempt any four questions) yestion 3 ©) How is the electronegativity of A likely to compare with 89 (6) State whether A is likely to be placed to th (W) (@) State whether the following statements are 1. In the cathode the cations gains ele a e left oF to the right compared to that of B ttue or false. Justify your answer etrons and are oxidised Finely divided iron is used in the Habers’ Process ©) Calculate the number of moles in 51 9 of ammonia a juestion 4. () The following question refers to the extraction of aluminium by electrolysis - @ {@) Why are the carbon rods replaced from time to time at the anode? (0) Give balanced equation for the reaction at the cathode? (ii) Three solutions P. Q and R have pH values 35, 5.2 and 122 Tespectively. Which one of this is 2 R (a) Weak acid? (©) Strong alkali? . : SECIS Fanaa () A chemical salt gave the following percentage composition Na = ai $= 40.51%, O= 30 ae Calculate the empirical formula of the salt (Na = 23, $ = 32, 0 = 16] ys‘HUIS ) Give balanced equation for the preparation of the following if {a) Ethane from Sodium propionate {b) Ethene from ethanol (6) Ethyne from calcium carbide ostion ; : {a) Sarita wanls {0 prove ‘hal cone. Sulphuric has dehydrating property. To deme O eh acid to the viol crystals tekon in c Ton oe opal (b) Write @ balanced equation for the above + (i) Identity the cations present in the given salt solution dropwise and then in excess to them. The observations Noted down are Solution P White ppt observed that becomes solule ta Solution @ : No characteristics observation noticed (#9 (@) When nitric acid is prepared by the action of cone Sulphuric acid on potassium nitrate, wha the special feature of the apparatus used? (b) Write balanced equation for the (c) What is the preferable te (w) Acidulated water is ele Nstrate thig observe? Dn P and Q when ammonium hydroxiay above reaction, MPerature for the reaction Clrolyzed in Hoftmans’ Voltameter In this context answer the following questions (2) Name the gas evolved at the anode. (0) What is the material used for electrodes () What is the ratio of gases evol Question 6 ¥ lo liberate two gases ved by volume? aining carbon and chlorine, (2) (i) Name the following : re (2) The ore of iron containing its oxide (0) The solvent over which hydrogen chiorid le cannot be collected (il) Acid “Pp has the molecular formula where it contains one H® ion and ionizes to a small extent 13} Acid “Q" has the molecular formula where is Contains two H® ions and ionizes almost completely (a) is a dibasic acid (>) —____ is a weak acid (c) Both P and Q liberates the gas when reacted with an active metal Dufespect to the gas ammonia, answer the following Pressure required during its industrial manufacture. ype of compounds that reacts with warm water to form the gas. Md product formed when excess of chlorine reacts with amrGunite giving reasons a ts with both acid and afkah oe ce ims a wate compound with oxygen rte sceotiall ielclin. ers cen ebservation of Ri wy swnte il following with respect to the Contact Process - nswer the i) Peres eee en lie ge compound forme 0 ae ne the catalyst used. (o) Nar jon the temperature of the oxidation chamber at (w) An elect tS ¥lence shell enters into a chemical bonding tom of an element “D" having seven elections in ie xt shot, m with ie i type of bonding is formed between © and D7 @ Draw the electron dot diagram to show its formation (0) Dre ion 8 ee is denatured alcohol? The atomic number of an element is 13. To which positon 4 iy The ; ) From the given equation ANHy +50, -+ 4NO + 6H4,0 i Calculate the volume of oxygen required to oxidis ted. Also calculate tha volume Of nitric oxide for (w) With reference to the electropiatin (@) the electrolyte used (0) the reaction at the electrodes. © ammonia completely it 100 cm? of ammonia is MmMed. Which law is used here? 3) 9 Of a key chain by Pratap, using nickel State > 5S.