LESSON 9: COMPLEXATION

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Complexes (coordination compounds) result from a donor-acceptable mechanism
-Metal ion complexes
-Organic molecular complexes classifcation of complexes
-Inclusion compounds
metal ion complexes belong to the same class of complexes
-Inorganic type
-Chelates
metal ion complexes
-Olefin
-Aromatic type
Hexamminecobalt (III) example of metal ion complexes
donates a pair of electron to form a coordinate covalent between
Ligand
itself
Chlorophyll and Hemoglobin naturally occuring chelates
Chelates places stringent steric requirement to both ligand and metal
-used to tie up and sequester iron or copper iron
EDTA
-used to sequester and remove calcium ions from hard water
-Quinhydrone type
-Picric acid type
Organic Molecular complexes
-Caffeine and other drug complexes
-Polymer type
-Channel lattice type
-Layer Type
-Clatharates Inclusion/ Occlusion compounds
-Monomolecular type
-Macromolecular type
reuslt from architecture of molecules than from their chemical
Inclusion compounds
affinity
packed in an orderly manner and held together by hydrogen bonds
Channel lattic Type
between nitrogen and oxygen atoms
Starch-iodine solution example of channel lattic type
channel-type complex consisting of iodine molecules entrapped
Starch-iodine solution
with spirals of glucose residues
clatharates example of layer type
formmof a cagelike lattice in whih the coordinating compound is
clatharates
entrapped
Warfarin sodium example of clatharates
involve in the entrapment of a single guest molecule in the capac-
Monomolecular Inclusion Compounds
ity of one host molecule
Cyclodextrins exampl of Monomolecular Inclusion Compounds
cyclic oligomer of glucose that form water soluble inclusion com-
Cyclodextrins
pounds with small molecules and portion of large compounds
atoms are arranged in three dimension to produce cage and
Macromolecular Inclusion Compound
channels
Molecular Seive Macromolecular Inclusion Compound is also called
-Zeolites
-Dextrins example of Molecular Seive
-Silica Gel

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