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Yashpatil TG~ @bohring_bot

Sri Chaitanya IIT Academy.,India.


 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60, Elite, Target & LIIT JEE-MAIN Date: 20-12-2023
Time: 09.00Am to 12.00Pm GTM-01 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the Test
Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having 30 questions
in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
(II) Section‐II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5 questions
attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less
than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is strictly
prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ______________________________
Yashpatil TG~ @bohrin
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
20‐12‐23_ Sr.Super60, Elite, Target & LIIT _ Jee‐Main_GTM‐01_Test Syllabus
PHYSICS : 2nd YEAR SYLLABUS
CHEMISTRY : 2nd YEAR SYLLABUS
MATHEMATICS : 2nd YEAR SYLLABUS

Sec: Sr.Super60, Elite, Target & LIIT Page 2


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A student is performing the experiment of resonance column. The diameter of the column
tube is 6 cm. The frequency of the tuning fork is 504Hz. Speed of the sound at the given
temperature is 336 m/s. The zero of the meter scale coincides with the top end of the
resonance column tube. The reading of the water level in the column when the first
resonance occurs is
1) 13 cm 2) 16.6 cm 3) 18.4 cm 4) 14.8 cm
2. If the source of light used in a Young’s double slit experiment is changed from red to violet
1) The fringes will become brighter
2) The central bright fringe will become a dark fringe
3) Consecutive fringe lines will come closer
4) The intensity of minima will increase
3. In Young’s double slit arrangement, slits are separated by a gap of 0.5 mm, and the screen is
placed at a distance of 0.5 m from them. The distance between the first and the third bright
fringe formed when the slits are illuminated by a monochromatic light of 5890 A0 is :-
1)1178  10 –9 m 2) 1178  10 –6 m

3)1178  10 –12 m 4) 5890  10 –7 m


4. Assertion (A): Formation of mirages in hot deserts is a phenomenon of total internal
reflection.
Reason (R): Air close to the land is hotter than the air far from the land in a hot desert. So
total internal reflection takes place
1) Assertion A is correct Reason R is wrong
2) Assertion A is wrong Reason R is correct
3) Assertion A and Reason R both are correct but Reason R is not explaining A
4) Assertion A and Reason R both are correct and Reason R is explaining A
Sec: Sr.Super60, Elite, Target & LIIT Page 3
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
5. The focal length of the objective of an astronomical telescope is 1 m and it is in normal
adjustment. Initially the telescope is focused to a heavenly body. If the same telescope is to
be focused to an object at a distance of 21 m from the objective, then identify the correct
choice
1) Eye piece should be displaced by 2 cm away from the objective
2) Eye piece should be displaced by 2 cm towards the objective
3) Eye piece should be displaced by 5 cm towards the objective
4) Eye piece should be displaced by 5 cm away from the objective
6. A Gaussian surface in the cylinder of cross section ‘  a 2 ’ and length ‘L’ is immersed in a

uniform electric field E with the cylinder axis parallel to the field. The flux ‘  ’ of the
electric field through the closed surface is
  
1) 2 a 2 E 2)  a 2 EL 3)  a 2 (2  L) E 4) Zero
7. Select correct statement for a capacitor having capacitance C, is connected to a source of
constant emf E
1) Almost whole of the energy supplied by the battery will be stored in the capacitor, if
resistance of connecting wire is negligibly small
2) Energy received by the capacitor will be half of energy supplied by the battery only when
the capacitor was initially uncharged
3) Strain energy in the capacitor must increases even if the capacitor had an initial charge
4) Energy stored depends on type of the source of emf
8. Match list - I with List - II
List - I List - II
a) Thermistor e) High positive ' '
b) Carbon f)  almost zero
c) Nichrome g) either positive or negative ' '
d) Constantan, and manganin h) Negative ' '

1) a-g, b-h, c-e, d-f 2) a-h, b-g, c-e, d-f


3) a-e, b-f, c-g, d-h 4) a-e, b-g, c-h, d-f
Sec: Sr.Super60, Elite, Target & LIIT Page 4
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
9. The four arms of a Wheatstone bridge have resistances as shown in the figure. A
galvanometer of 15 resistance is connected across BD. Calculate the current through the
galvanometer when a potential difference of 10 V is maintained across AC.

1) 2.44  A 2) 4.87  A 3) 2.44mA 4) 4.87mA


10. A long straight wire of resistance R, radius ‘a’ and length ‘ l ’ carries a constant current “I”.
The pointing vector for the wire is

IR IR 2 I 2R I 2R
1) 2) 3) 4)
2  al al al 2  al
11. A lamp (pure resistance) is connected in series with a capacitor
A) When a dc source is connected to the combination, the lamp will not glow in steady state
B) When ac source is connected to the combination, the brightness of glow of lamp
increases with increases of frequecncy of ac.
1) A is true B is false 2) A is false B is true
3) A & B are true 4) A & B are false

12. An electron revolving in an orbit of radius 0.5 A0 in a hydrogen atom executes 10 revolutions
per second. The magnetic moment of electron due to its orbital motion will be

1) 1256 1041 Am2 2) 653 1041 Am 2

3) zero 4) 256 1026 Am 2

Sec: Sr.Super60, Elite, Target & LIIT Page 5


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
13. Assertion: The induced emf and current will be same in two identical loops of copper and
aluminum, when rotated with same speed in the same magnetic field.
Reason: Mutual induction depends on the orientation of the coils
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true and R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true.
14. Two magnets A and B are identical and these are arranged as shown in the figure. Their
length is negligible in comparison with the separation between them. A magnetic needle is
placed between the magnets at point P which gets deflected through an angle under the
influence of magnets. The ratio of distances d1 and d2 will be

1 1 1 1
3
1) (2cot  ) 3 2) (2 tan  ) 3 3) (2cot  ) 4) (2 tan  ) 3
15. If in hydrogen atom, radius of nth Bohr orbit is rn , frequency of revolution of electron in nth
orbit is f n , choose the correct option

1) 2)

3) 4) Both (1) and (2)


Sec: Sr.Super60, Elite, Target & LIIT Page 6
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
16. A P-N junction diode can withstand currents up to 10 mA. Under forward bias, the diode has
a potential drop of 0.5 V across it which is assumed to be independent of current. The
maximum voltage of the battery used to forward bias the diode when a resistance 200  of
is connected in series with it is
1) 2.5V 2) 2.6V 3) 2.7V 4) 2.8V
17. A fission reaction is given by 236 140 94
92U  54 Xe  38 Sr  x  y , where x and y are two particles.
Considering 236
92U being at rest, the kinetic energies of the products are denoted by
K Xe , K Sr , K x  2MeV  and K y  2 MeV  , respectively. Let the binding energies per nucleon

of 236 140 94
92U , 54 Xe, 38 Sr be 7.5 MeV, 8.5 MeV and 8.5 MeV respectively. Considering different
conservation laws, the correct option is
1) x  n, y  n, K Sr  129 MeV , K Xe  86 MeV
2) x  p, y  e  , K Sr  129 MeV , K Xe  86 MeV
3) x  p, y  n, K Sr  129 MeV , K Xe  86 MeV
4) x  n, y  n, K Sr  86 MeV , K Xe  129 MeV
18. A symmetric star conducting wire loop is carrying a steady state current I as shown in figure.
The distance between the diametrically opposite vertices of the star is 4a. The magnitude of
the magnetic field at the center of the loop is

0 I  0 I 
1) 6 3  1 2) 6 3  1
4 a  4 a 
0 I  0 I 
3) 3 3  1 4) 3 2  3 
4 a  4 a 

Sec: Sr.Super60, Elite, Target & LIIT Page 7


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
19. The logic circuit shown below has the input waveforms ‘A’ and ‘B’ as shown. Pick out the
current output waveform.

Output is

1) 2)

3) 4)
20. The figure gives the magnetic field of an electromagnetic wave at a certain point and at a
certain instant. The wave transports energy in negative y-direction. Then the direction of
electric field at this point and instant is
Z'

y

B

x
1) z – axis 2) – z – axis 3) x – axis 4) – x – axis
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

Sec: Sr.Super60, Elite, Target & LIIT Page 8


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
21. A closed organ pipe of length L and an open organ pipe contain gases of densities 1 and  2
respectively. The compressibility of gases are equal in both the pipes. Both the pipes are
vibrating in their first overtone with same frequency. The length of the open pipe is
x 
L 1 where x is _____. (Round off to the Nearest Integer)
3 2
22. In the arrangement of capacitors shown in the figure, if each capacitor is 9 pF, then the
effective capacitance between the points A and B is (in pF)

23. A cylindrical wire of radius 0.5 mm and conductivity 5  107 S / m is subjected to an electric

field of 10 mV/m. The expected value of current in the wire will be x3 mA .The value of x
is __________.
24. In a series LCR circuit R = 200  and the voltage and the frequency of the main supply is
220 V and 50 Hz respectively. On taking out the capacitance from the circuit the current lags
behind the voltage by 300 . On taking out the inductor from the circuit the current leads the
voltage by 300 . The power dissipated in the LCR circuit is
25. A solenoid is of length 50 cm and has a radius of 2cm. It has 500 turns. Around its central
section a coil of 50 turns is wound. Calculate the mutual inductance of the system. (in  H )
(Round off to the Nearest Integer)
26. Consider the circuit shown in figure. With switch S1 closed and the other two switches open,
the circuit has a time constant 0.05sec. With switch S2 closed and the other two switches
open, the circuit has a time constant 2 sec. With switch S3 closed and the other two switches
open, the circuit oscillates with a period T. Find T (in sec). (Take  2  10 )
Sec: Sr.Super60, Elite, Target & LIIT Page 9
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P

27. Find the current measured by the ammeter in the circuit shown in figure ( in  10 1 A )

28. A certain metallic surface is illuminated by monochromatic radiation of wavelength  . The


stopping potential for photoelectric current for this radiation is 3V0 . If the same surface is
illuminated with a radiation of wavelength 2 , the stopping potential is V0 .The threshold
wavelength of this surface for photoelectric effect is____  .
29. Two plane mirrors A and B are aligned parallel to each other, as shown in the figure. A light
ray is incident at an angle 30° at a point just inside one end of A. The plane of incidence
coincides with the plane of the figure. The maximum number of times the ray undergoes
reflections (including the first one) before it emerges out is

30. One of the lines in the emission spectrum of Li2+ has the same wavelength as that of the 2nd
line of Balmer series in hydrogen spectrum. The electronic transition corresponding to this
line is n 12  n  .Find the value of x.

Sec: Sr.Super60, Elite, Target & LIIT Page 10


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. Plots showing the variation of the rate constant (k) with temperature (T) are given below.
The plot that follows Arrhenius equation is

1) 2)

3) 4)
32. For a first order homogeneous gaseous reaction, A  2 B  C if the total pressure after time t
was Pt and after long time ( t   ) was P then k in term of Pt , P and t, is
2.303  P  2.303  2 P 
1) k  log   2) k  log  
t  P  Pt  t  P  Pt 

2.303  2 P 
3) k  log   4) None of these
t  3( P  Pt ) 
33. Statement 1: Addition of HgI 2 to aqueous solution of KI increases the freezing point

Statement 2: A complex K 2  HgI 4  is formed

1) Statement 1 is True, Statement 2 is true; Statement 2 is a correct explanation for


Statement 1

Sec: Sr.Super60, Elite, Target & LIIT Page 11


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
2) Statement 1 is True, Statement 2 is true; Statement 2 is NOT a correct explanation for
Statement 1
3) Statement I is True, Statement 2 is False
4) Statement 1 is False, Statement is True
34. The molar volume of X  l  d  0.9 g / mL  increases by a factor of 3000 as it vaporizes at

27o C and the Y  l  d  0.88 g / mL  increases by a factor of 8000 at 27o C . A miscible

liquid solution of X and Y at 27o C has a vapour pressure of 50 torr. The mole fraction of Y
in solution is : (Given: R = 0.082 atm/L/mol/K; Molar mass of X = 75; Molar mass of
Y = 88)
1) 0.48 2) 0.52 3) 0.62 4) 0.247
35. A hydrogen electrode X was placed in a buffer solution of sodium acetate and acetic acid in
the ratio a : b and another hydrogen electrode Y was placed in a buffer solution of sodium
acetate and acetic acid in the ratio b : a. If reduction potential values for two cells are found
to be E1 and E2 respectively w.r.t. standard hydrogen electrode, the pK a value of the acid
can be given as
E1  E2  E  E2  E1 E2  E1
1) 2)   1 3)  0.118 4)
0.118  0.118  E2 0.118
36. How many electrons are delivered at the cathode during electrolysis by a current of 1amp in
60 seconds?
1) 3.74 1020 2) 6.0 1023 3) 7.48  1021 4) 6.0 1020
37. Statement 1: Oxygen is more electronegative than sulphur, yet H 2 S is more acidic than
H 2O .
Statement 2: H – S bond is weaker than O – H bond.

Sec: Sr.Super60, Elite, Target & LIIT Page 12


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
1) Statement 1 is True, Statement 2 is true; Statement 2 is a correct explanation for
Statement 1
2) Statement 1 is True, Statement 2 is true; Statement 2 is NOT a correct explanation for
Statement 1
3) Statement I is True, Statement 2 is False
4) Statement 1 is False, Statement is True
38.
Column I (Species) Column II (Colour in aq – solution)

a) Co3 , Co2 p) Yellow

b) Fe 2  q) Blue pink

c) Cu 2 r) Green

d) Mn3 s) Violet

e) Fe3 t) Blue

1) a – q, b – r, c – t, d – s, e – p 2) a – p, b – r, c – q, d – s, e – t
3) a – t, b – r, c – q, d – s, e – p 4) a – q, b – s, c – p, d – r, e – t

39. Statement 1: For the reaction 2 I   S 2O82   I 2  2 SO42  , Fe(III) catalyst is used
Statement 2: 2 Fe3  2 I   2 Fe 2   I 2
2 Fe2  S2O82  2 Fe3  2 SO42
1) Statement 1 is True, Statement 2 is true; Statement 2 is a correct explanation for
Statement 1
2) Statement 1 is True, Statement 2 is true; Statement 2 is NOT a correct explanation for
Statement 1
3) Statement I is True, Statement 2 is False
4) Statement 1 is False, Statement is True
Sec: Sr.Super60, Elite, Target & LIIT Page 13
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
40. Select the correct graphical representation

1) 2)

3) 4)
41. Consider the following staements
3
Statement 1: Cr  NH 3 6  is an inner orbital complex with crystal field stabilization
energy equal to 1.2 0
Statement 2: The octahedral complex formed by joining the CN  ligands to Fe3 ion has
theoretical value of spin only magnetic moment equal to 1.73 BM

Statement 3: Na2 S  Na2  Fe  CN 5 NO   Na4  Fe  CN 5 NOS  , In reactant and product

the oxidation states of iron are same and arrange in the order of true / false
1) FTF 2) TTF 3) TTT 4) FFF
42. The correct statement on the isomerism associated with the following complex ions
2 2 2
P)  Ni  H 2O 5 NH 3  Q)  Ni  H 2O 4 ( NH 3 ) 2  R)  Ni  H 2O 3 ( NH 3 )3  is

1) P and Q show geometrical and optical isomerism


2) Q and R show geometrical and optical isomerism
3) P and Q show only geometrical isomerism
4) Q and R show only geometrical isomerism
Sec: Sr.Super60, Elite, Target & LIIT Page 14
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P

43.
The major products P and Q are

1) and CH3CH 2CHO 2) and CH3COCH3

3) and CH3COCH3 4) and CH3CH 2CHO


OH

18 HBr
Major Product is
OH CCl4

44.
18
O O

1) 2)
OH Br

Br OH

3) 4)

Sec: Sr.Super60, Elite, Target & LIIT Page 15


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
H3C CH3
OH (1) Hg(OAc)2
Product formed is
(2) NaBH4

45. H3C
O CH3
CH3
CH3
O CH3

1) H3C 2) H3C
CH3
O
CH3

3) 4)
O O
18 A
R  C  O  H  R ' OH  R  C  O  R ' H 2O
46. Fischer esterification is represented as follows
here  R  CH 3 , R '  C2 H 5  in the above reaction A/2 is equal to
1) 8 2) 9 3) 6 4) 12
Ph

CH 3  C  CH 2 
H
CH3OH
C

47. O , C will be
Ph
Ph Ph OH Ph OCH3
CH 3  C  CH 2
O+ CH 3  C  CH 2 CH 3  C  CH 2 CH 3  C  CH 2

1) H 2) OH 3) OCH3 4) OCH3

Sec: Sr.Super60, Elite, Target & LIIT Page 16


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
48. Which of the following plots is (are) correct for the given reaction? (  P0 is the initial
concentration of P)
CH3 CH3
H3C Br + NaOH H 3C OH +NaBr
CH3 CH3
(P) (Q)
P Q

Initial rate
t1/ 2

 P 0  P 0
1) 2)

  P 
Q  
  P 

 P0   0 

3) Time 4) Time

Br / P HOH / H 
49. CH 3  COOH      B  
2  A    C  . The product (C) will be
NaCN

COOH
CH2 COOH
CH2

1)
COOH 2) CH2 COOH

CH2 CO CO
O CH2 CH O
3) CH2 CO 4) CO

Sec: Sr.Super60, Elite, Target & LIIT Page 17


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
50. Which of the following azodyes cannot be prepared by combining benzene diazonium
chloride with corresponding compounds?
CH3
CH3
N
CH3

N N CH3
N N

1) 2)
OH

N N
N N
OH

3) 4)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

51. The vapour pressure of fluorobenzene at t oC is given by the equation


1250
log p  mm Hg   7.0 
t  220
Calculate the boiling point of the liquid in o C if the external (applied) pressure is 5.26%
more than required for normal boiling point (log 2 = 0.3)
52. Given the equivalent conductance of sodium butyrate, sodium chloride and hydrogen

chloride are 83, 127 and 426 mho cm 2 eq 1 at 25o C respectively. Calculate the equivalent
conductance of butyric acid at infinite dilution in same units.

Sec: Sr.Super60, Elite, Target & LIIT Page 18


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
53. How many of the following statement(s) is (are) correct when a mixture of NaCl and
K 2Cr2O7 is gently warmed with conc. H2SO4?
1) A deep red vapour is evolved
2) The vapours when passed into NaOH solution gives a yellow solution of Na2CrO4
3) Chlorine gas is evolved
4) Chromyl chloride is formed
54. How many of the following compounds will decolourize the colour of acidified KMnO4 ?
H 2S FeSO4 NaNO2 Na2 SO3
PbS Na2 S NaNO3 Na2 SO4
CO2 SO3 P2O5
55. Please help Santa and Banta to decode the lock of their car XYZT
Given:
XeF2 XeF4 XeF6 XeO3 XeOF4 XeO2 F2

Code 1 2 3 4 5 6
1) No. of planar compounds = T
2) Code of the compound which is linear = Z
3) Code of the compound which has distorted octahedral shape = X
4) Code of the compound which is pyramidal = Y
56. How many species do not exist?

PH 3 , PH 5 , PCl5 , PBr5 , SiF62 , SF6 , Al2 F6 , PbI 4 , NCl5 , AlCl3 , OF2 , OH 2 , OF4 ,
HFO4 , FeI3 , B2 F6
57. If 3-chloro 3 – methyl hexane is treated with C2 H 5ONa / C2 H 5OH , E2 Elimination
reaction takes place predominantly. How many isomeric alkenes would be formed?

Sec: Sr.Super60, Elite, Target & LIIT Page 19


Yashpatil TG~ @bohrin
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
58. Among the following how many compounds are showing both reactivity with “ LiAlH 4 ” &
Aldol condensation & I 2 / NaOH ?
CHO

O O
CH 3  C  H CH 3  CH 2  C  CH 2  CH 3
1) 2) CH 2  CH 2 3) 4)
O
CHO C Cl

C CH3 C H O O

O O CH 3  C  CH 2  C  CH 3
5) 6) 7)

59. Specific rotation for  -anomer of a given mono saccharide is 100o for  -anomer is 20o .

Specific rotation of equilibrium mixture is 68o , if % of  anomer is x  10% then x is


60. How many of the following is / are true about vitamins?
1) Vitamins in the human body are needed in large amounts
2) Water soluble vitamins must be supplied regularly in diet.
3) Vitamins of the B group and vitamic C are water soluble
4) Vitamins A, D, E and K are fat soluble.

Sec: Sr.Super60, Elite, Target & LIIT Page 20


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. If vertex of a parabola is (2,-1) and the equation of its directrix is 4 x  3 y  21 , then the
length of its latus rectum is
1) 2 2)8 3)12 4)16

62. PN is an ordinate of the parabola y 2  4ax (P on y 2  4ax and N on x-axis). A straight line
is drawn parallel to the axis to bisect NP and meets the curve in Q. NQ meets the tangent at
the vertex A in a point T such that AT=kNP, then the value of k is (where A is the vertex)
3 2 1
1) 2) 3) 1 4)
2 3 3
63. Let  n ,  n be the distinct roots of the equation x 2   n  1 x  n 2  0. If
2021
1
 a
can be expressed in the form , where a and b are positive integers
n2  n
  1  n  1 b
relatively prime to each other, then value of  b  a  , is :
1)1 2) 3 3) 6 4) 9

64. The solution of the differential equation y 2dx  x 2  xy  y 2 dy  0, is : 


x x
1) tan 1    ln y  C  0 2) 2 tan 1    ln y  C  0
 y  y

3) ln  y  x 2  y 2   ln y  C  0 4) ln  y  x 2  y 2   C  0
   
a x y
65. If A   x b z  where a, b, c, x, y, z1,2,3,4,5,6 and also a , b, c, x, y , z are distinct. Then
 y z c 

the number of matrices as A with trace equal to 10 is :


2 2 2 3
1) 3 3! 2) 2  3! 3)  3! 4)  3!

Sec: Sr.Super60, Elite, Target & LIIT Page 21


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
18
20  9 10 
 1 3
66. If terms independent of x in the expansion of  3x   and  x   are A and B
 x  x 
 
 9 
respectively then  A  B  equals :
 38 

1) 310. 19C8 2) 310. 19C9 3) 39. 20C8 4) 39. 19C18

67. Statement -1 : The equation x 2   2 m  1 x   2 n  1  0, where m, n  I, cannot have any

rational roots.
2
Statement- 2: The quantity  2m  1  4  2n  1 , where m, n  I , can never be perfect
square.
Have to select the correct choice as given below .
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for Statement
-1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true
25
 1 
68. Statement -1 : The term independent of x in the expansion of  x 2   2 is 50C25.
 x2 
Statement-2 : In a binomial expansion middle term is independent of x.
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for
Statement -1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true
Sec: Sr.Super60, Elite, Target & LIIT Page 22
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
69. Statement-1 : If f : a1, a2 , a3 , a4 , a5  a1, a2 , a3 , a4 , a5 , f is onto and f  x   x for each
x a1, a2 , a3 , a4 , a5 , then number of such functions is equal to 44.

Statement-2: The number of derangement for n distinct objects is n! 


n
 1r
r 0
r!
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for Statement
-1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true

70. Statement –1 : The only circle having radius 10 and a diameter along line 2 x  y  5 is
x2  y 2  6 x  2 y  0 .
Statement-2: 2 x  y  5 is a normal to the circle x 2  y 2  6 x  2 y  0
1) Statement -1 is false, Statement-2 is true;
2) Statement -1 is true, Statement-2 is true; Statement-2 is a correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is true, Statement -2 is true, Statement 2 is not a correct explanation for .
statement-1.
71. The first of two groups of samples has 100 observations with mean 15 and Standard
deviation(S.D) = 3, if the two groups together have 250 observations with mean 15.6 and
S.D = 13.44 then S.D of second group is
1) 4 2) 5 3) 6 4) 3.52
72. Mean and standard deviation of 100 observations were found to be 40 and 10, respectively.
If at the time of calculation two observations were wrongly taken as 30 and 70 in place of 3
and 27 respectively, then the correct standard deviation is .
1)10.24 2)8.24 3)6.24 4) 12.24

Sec: Sr.Super60, Elite, Target & LIIT Page 23


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
73. A circle has the same centre as an ellipse and passes through the foci F1 and F2 of the
ellipse, such that the two curves intersect in 4 points. Let ‘P’ be any one of their point of
intersection. If the major axis of the ellipse is 17 and the area of the triangle PF1F2 is 30,
then the distance between the foci is :
1)11 2) 12 3) 13 4) 14
z i 5
74. Let z be a complex number such that  1 and z  . Then the value of z  3i is :
z  2i 2
7 15
1) 10 2) 3) 4) 2 3
2 4
75. If ax 2  by 2  2 x  cy  11  a , b, c  R  is the locus of centre of circles whose radius is 5 and
bisect the circumference of circle x 2  y 2  2 x  4 y  4 then the value of  a  b  c  is equal
to
1) -2 2)-4 3) 4 4) 6
18
17 x 27  x  1
76. If  x 26
 x  1  5 x  3 dx   C , where C is constant of integration, then the
k
value of k is :
1)3 2) 6 3)9 4)12
77. The 1st , 2nd and 3rd terms of an arithmetic series are a,b and a2 , where a is negative then

sum of an infinite geometric series whose first three terms are a, a2 and b respectively, is:
1 3 1 1
1) 2) 3) 4)
2 2 3 4
 x ,  2  x  1

78. Let a function f  x  be defined in  2,2 as f  x    sgn x ,  1  x  1 , where x

 x , 1 x  2
denotes fractional part, then area bounded by graph of f  x  and x-axis is :
1) 2 2) 3 3) 4 4) 5

Sec: Sr.Super60, Elite, Target & LIIT Page 24


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
5  9  13  .........   4 y  1
79. Let y  1og 2 x  log 4 x  log16 x  .........   and 4log 4 x  , then
1  3  5  ........   2 y  1
the value of x 2 y equals :
1) 20 2) 22 3) 24 4) 28
80. Consider the cuves on the Argand plane as

C1 : arg  z  
4
3
C2 : arg  z   and C3 : arg  z  5  5i    , where i  1 .
4
25
Statement- 1: Area of the region bounded by the curves C1, C2 and C3 is
2
Statement-2 : The boundaries of C1, C2 and C3 constitute a right isosceless triangle.
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for Statement
-1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. Point ‘O’ is the centre of the ellipse with major axis AB and minor axis CD. Point F is one
focus of the ellipse. If OF=6 and the diameter of the inscribed circle of triangle OCF is 2,
then the product of (AB) (CD) =

f t 
x
 
82. If f : R  R be a differentiable function satisfying f  x   x ln x  x   t.nt dt x  R ,
1

1
then the value of f '  e   f "  
4

Sec: Sr.Super60, Elite, Target & LIIT Page 25


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
83. Mr. A either walks to school or take bus to school everyday. The probability that he takes a
bus to school is 1/ 4 . If he takes a bus, the probability that he will be late is 2 / 3 . If he walks
to school, the probability that he will be late is 1/ 3 . The probability that Mr. A will be on
p
time for at least one out of two consecutive days is , where p and q are co-prime, the value
q
of  q  p  is
84. The contents of three urns are 1white, 2 red, 3 green balls; 2white, 1red and 1 green balls; 4
white, 5 red and 3 green balls. Two balls are drawn from an urn chosen at random and are
found to be one white and one green. If the probability that the balls so drawn came from the
a
third urn can be expressed as , where a and b are co-prime positive integers, then the value
b
of (a + b)=

cos ec 2 x  2019  cot  x 


85. If  dx   C , then the value of g  0   ___(Where C is constant
 cos x  2019
 g  x  2019

of integration)
3
86.  
Let I1   x 2  x  3 f x3  2 x 2  5 x  2020 dx and 
1
3
  
I 2   4 x 2  3 x  2 f x3  2 x 2  5 x  2020 dx . If the value of
2 I1 a
 where a and b are
3I 2 b
1

co-prime , then the value of  a  b  .


87. Let S be a circle with centre C(3,5) and PA and PB are pair of tangents drawn from an
external point P  9,11 to the circle S. The distance between the origin and the point inside
the quadrilateral ACBP which is equidistant from its four vertices is.

Sec: Sr.Super60, Elite, Target & LIIT Page 26


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P
88. Let S be a circle of radius 1 with centre at A. Two circles with radius r and R and centre at C

and D are externally tangent to each other and internally tangent to S. If DAC  120o . The
value of Rr  3R  3r is
a
89. Let f be a continuous and even function such that  f  x  dx  10. If g(x) is a continuous
0
a
positive function such that g  x  g   x   1 and  g  x  dx  5 , then the value of
0

f  x
a
 1  g  x
dx is ______
a

90. If area of the triangle formed by latus recturm and tangents at the end points of latus rectum

x2 y2
of   1 is A, then 80 A is
16 9

Sec: Sr.Super60, Elite, Target & LIIT Page 27


Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 20‐12‐23_ Sr.Super60, Elite, Target & LIIT _Jee‐Main_GTM‐01_Q.P

Sec: Sr.Super60, Elite, Target & LIIT Page 28

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