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PREVIOUS YEAR QUESTIONS

CHAPTERWISE
(ENGLISH MEDIUM)

CLASS 12
CHEMISTRY
ALL LAST 10 YEAR QUESTION OF
RAJASTHAN BOARD

सभी प्रश्न CHAPTERWISE

Based on Rationalised NCERT 2023-24
ERRORLESS PDF
FOR RBSE EXAMINATION 2023-24

Maniesh Kr Sah
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CO-ORDINATION COMPOUND
CHAPTER-5
1. Taking an example of an ambidentate ligand, explain why it is called as ambidentate
ligand. [½+½=1M]
(RBSE 2013)

2. Give the oxidation number and coordination number of the central metal atom in the
complex compound K3[Fe(C2O4)3]. [½+½=1M]
(RBSE 2013)

3. Give the structures of cis-[CoCl2(en)2] and facial- [Co(NH3)3(NO2)3] isomers.[2M]

(RBSE 2013)

4. (a) Explain the applications of coordination compounds in the field of metal

purification giving an example.
(b) Write the IUPAC name of [Ag(NH3)2][Ag(CN)2] coordination compound.[2M]
(RBSE 2014)

5. Explain the difference between a double-salt and a complex, giving an example in

each case.[2M]
(RBSE 2014)

6. Write the formula of ionisation isomer of [Cr(H2O)4Br2]Cl.[1M]

(RBSE 2015)

7. Write the formula of coordination compound mercury tetrathiocyanato-cobaltate

(III).[1M]
(RBSE 2015)

8. Explain on the basis of valence bond theory that [Ni(CN)4]-2 is a low spin complex
ion. [2M] (RBSE 2015)

9. Classify the following into homoleptic & heteroleptic complexes?—[2M]

(i) K4[Fe(CN)6] (ii) [Co(NH3)5(CO3)]Cl

(iii) K2[Zn(OH)4] (iv) [Pt(NH3)2Cl(NO2)]

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 (RBSE 2016)

10. Explain the violet colour of [Ti(H2O)6]3+ complex on basis of the crystal field theory
(CFT).[2M] (RBSE 2016)

11. (a) Define primary and secondary valency of metal ionc proposed by werner theory.
(b) Write primary and secondary valency of co in [Co(NH3)6]cl3.
(c) Write structural formula of Ni(Co)4 and Cr(Co)6 .
(d) Draw the structure which shows Aynergic bonding interaction in a carbonyl
complex. [1+1+1+1=4M]
(RBSE 2017)

12. (i) Define linkage and ionisation isomerisum

(ii) Which isomerisum show by [Co(NH3)6] Write name.
(iii) Draw the diagram which show the transition of an electron in [Ti(H2O)6]+3 .
(iv) What impact takes place on metal comlex due to transition of an electron in
[Ti(H2O)6]+3. [1+1+1+1=4M]
(RBSE 2017)

13. Write IUPAC name of the following complex compound K3[Fe(C2O4)3].[1M]

(RBSE 2018)

14. On the basis of valence bond theory (VBT) explain the oxidation state, hybridization,
Geometry and magnetic nature of metal in complex[CoF6]3-.[2M]
(RBSE 2018)

15. Give any one example of bidentate ligand.[1M]

(RBSE 2019)

16. Give the oxidation state and coordination number of the central metal ion in the
following complexes-[2M]
(a) [Co(en)3]3+ (b) K4(Fe(CN)6]
(RBSE 2019)

17. Write oxidation state of Ni in [Ni(CO)4 ].[1M]

(RBSE 2020)

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18. Write definition of ambidentate ligand.[1M]
(RBSE 2020)

19. (a) Write IUPAC name of complex K3[Al(C2O4)3].

(b) Write the geometry and magnetic nature of the complex ion [NiCl4 ] 2– on the
basis of valence bond theory(VBT).[1+1=2M]
(RBSE 2020)

20. The co-ordination compound having tetrahedral geometry is-[1M]

(a) [Ni(CN)4]2- (b) [Ni(CO)4]

(c) [Fe(CO)5] (d) [Cr(CO)6]

(RBSE 2022)

21. Write IUPAC name of K3[Al(C2O4)3].[1M]

(RBSE 2022)

22. Define co-ordination polyhedron.[1M]

(RBSE 2022)

23. Write the type of isomerism exhibited by [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6]
[Co(CN)6]. [1M]
(RBSE 2022)

24. Didentate ligand is-[1M]

(a) C₂02- (b) SCN-

(c) NH3 (d) Cl-

(RBSE 2023)

25. Draw the geometries of geometrical isomers of [Pt(H2O)2Br2] and write their
configurations.[1.5M]
(RBSE 2023)
26. Write IUPAC names of following.[1.5M]
(a) [Cu(H2O)4]2+
(b) [Co(NH3)6]Br3
(c) [Fe(CN)6]3-
(RBSE 2023)

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