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PREVIOUS YEAR QUESTIONS

CHAPTERWISE
(ENGLISH MEDIUM)

CLASS 12
CHEMISTRY
ALL LAST 10 YEAR QUESTION OF
RAJASTHAN BOARD

सभी प्रश्न CHAPTERWISE

Based on Rationalised NCERT 2023-24
ERRORLESS PDF
FOR RBSE EXAMINATION 2023-24

Maniesh Kr Sah
7541948871
@boardzone
ALDEHYDES, KETONES AND CARBOXYLIC
ACIDS
CHAPTER-8
1. An organic compound having molecular formula C3H6O , gives orange-red
precipitate with 2, 4-dinitrophenyl hydrazine, but does not reduce Tollen's reagent.
Give IUPAC name and structural formula of the compound.[1M]
(RBSE 2013)

2. (a) How carboxylate ion get stabilised by resonance ? Explain by the structures.

(b) Carboxylic acids are more acidic than phenols. Explain [2M]
(RBSE 2013)

3. Explain the following with suitable example : [2M]

(a) Rosenmund reduction (RBSE 2022, RBSE 2023 , RBSE 2015)
(b) Gatterman-Koch reaction.
(RBSE 2014)

4. Explain the following with suitable example : [2M]

(a) Clemmensen reduction
(b) Stephen reaction.
(RBSE 2014)

5. (a) Write a note on Rosenmund reduction. (RBSE 2022, RBSE 2023 , RBSE 2014)
(b) Why is fluoroacetic acid more acidic than chloroacetic acid ?
(c) Draw the resonating structures of carboxylate ion. [2+1+1=4M]
(RBSE 2015)

6. (a) Write a note on Wolff-Kishner reduction.

(b) Boiling point of carboxylic acids are higher than aldehydes and ketones of
comparable molecular masses. Why ?
(c) Draw the dimer structure of ethanoic acid in vapour state.[2+1+1=4M]
(RBSE 2015)

7. (a) For which group identification Tollens test is used. Give chemical equation?
(b) Give one difference between Clemmensen reduction & Wolff Kishner reduction?
(c) Explain aldol reaction with chemical equation?

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 (d) Draw orbital diagram for the formation of carbonyl group?[4M]
(RBSE 2016)
8. (a) Give resonating structure of carboxylic group?
(b) Give chemical reaction to obtain the following.

(i) Carboxylic acid from Grignard reagent.

(ii) Benzoic acid from ethyl benzoate.
(iii) Benzamide from benzoic acid.

(c) Give resonating structures of propenoic acid?

(d) How will you distinguish aldehyde, ketone & carboxylic acid.[4M]
(RBSE 2016)

9. Chloroacetic acid is stronges acid than acetic acid give one reason.[1M]
(RBSE 2017)

10. Write the equation of chemical reaction and main of reaction obtained following
compounds (A) and (B) from CH3CHO
(A) But - 2 - enol
(B) Chloroform [2M]
(RBSE 2017)

11. Write the equation of chemical reaction and name of reaction to obtained following
compounds (A) and (B) from CH3COOH.
(A) Ethane
(B) Mono chloroacetic acid.

12. Write IUPAC name and chemical formula for Acetone.[1M]

(RBSE 2018)

13. (a) Arrange the following compounds in the descending order of their reactivity
towards nucleophilic substitution reaction.

CH3CHO, HCHO, CH3COCH3

(b) Alkanoic acid have highest boiling points. Explain[2M]

(RBSE 2018)

14. (a) Arrange the following carboxylic acid in ascending order of their acidity.
Benzoic acid, 4-methoxybenzoic acid, 4- nitrobenzoic acid.
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 (b) How will you distinguish between Aldehyde and ketone by chemical test.[2M]

(RBSE 2018)

15. (a) Write structural formula of oxalic acid.

(b) Explain mechanism of Aldol condensation. [3M]
(RBSE 2019)

16. (a) Write structural formula of Diethyl ketone.

(b) Explain mechanism of Kolbe electrolysis.[3M]
(RBSE 2019)

17. (a) Arrange the following haloacids in increasing order of their acidity.

(b) Why carboxylic acids are more acidic than phenol ? [2M]
(RBSE 2020)

18. (a) Arrange the following haloacids in increasing order of their acidity.

(b) Aldehydes are more reactive than ketones towards nucleophilic addition
reactions. Explain. [2M]
(RBSE 2020)

19. Write chemical formula of [A],[B] and [C] in above reaction sequence.[1.5M]

(RBSE 2022)

20. Explain reason:

(a) Acetic acid is weak acid as compared to formic acid.
(b) Boiling point of carboxylic acids is more than aldehydes having comparable
molecular masses.[2M]
(RBSE 2022)

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21. Draw the orbital diagram of carbonyl group.[1M]
(RBSE 2022)

dil.NaOH
22. (a) 𝟐𝐂𝐇𝟑 𝐂𝐇𝐎 −−⟶ 𝑿−−⟶ 𝒀 write chemical formula and IUPAC name of x and y in
−H2 O
above chemical sequence.
(b) write short note on Gattermann-Koch reaction.[2+2=4M]

(RBSE 2023)

dry ether + H3 O
23. (a) 𝐂𝐇𝟑 𝐌𝐠𝐁𝐫 + 𝐂𝐎𝟐 − − −−⟶ 𝑿−⟶ 𝒀 write chemical formula and name of x and y in
above chemical sequence.

(b)Write short note on Rosenmund reduction. .[2+2=4M]

(RBSE 2023)

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